Hostname: page-component-78c5997874-94fs2 Total loading time: 0 Render date: 2024-11-11T03:37:11.525Z Has data issue: false hasContentIssue false
  • English
  • Français

Caesium desorption from layer silicate minerals using quaternary ammonium salts

Published online by Cambridge University Press:  03 September 2018

T. Miura ,
A. Sasaki ,
N. Suzuki  and
M. Endo
T. Miura*
Affiliation:
Yamagata University, Graduate School of Science and Engineering, 4-3-16 Jonan, Yonezawa, Yamagata, Japan
A. Sasaki
Affiliation:
Yamagata University, Faculty of Engineering, 4-3-16 Jonan, Yonezawa, Yamagata, Japan
N. Suzuki
Affiliation:
Showa Pharmaceutical University, 3-3165 Higashi-tamagawa Gakuen, Machida, Tokyo, Japan
M. Endo
Affiliation:
Yamagata University, Graduate School of Science and Engineering, 4-3-16 Jonan, Yonezawa, Yamagata, Japan
*
*E-mail: t.miura1230@gmail.com
Get access Rights & Permissions [Opens in a new window]

Abstract

The adsorption and desorption of cesium onto layered minerals, zeolite and geochemical reference samples were studied. 0.5 g of bentonite and mica were able to adsorb 71.2 and 51.5 mg of cesium, respectively, from 50 mL of deionized water containing 200 mg/L of cesium under neutral pH condition. These amounts of cesium adsorption were greater than those reported for vermiculites (8.9 and 5.6 mg, respectively). Additionally, the cesium adsorption on mica and vermiculite remained essentially unchanged under seawater conditions, but it decreased drastically on zeolite. The cesium desorption from the layered minerals was promoted by the addition of ammonium ions, namely trioctylmethylammonium chloride and zephiramine. These ammonium ions desorb cesium from the interlayers of the minerals without destroying the mineral structure. The cesium desorption procedure using quaternary ammonium ions would be extremely useful for decontamination of soil containing the layered minerals with adsorbed radioactive cesium.

Keywords

layer silicate mineralsadsorption/desorption of Csinterlayer swellingquaternary ammonium saltsseawaterheat treatment
Type
Article
Information
Clay Minerals , Volume 53 , Issue 3 , September 2018 , pp. 487 - 496
Copyright
Copyright © Mineralogical Society of Great Britain and Ireland 2018 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Footnotes

Guest Associate Editor: M. Elsayed

This paper was originally presented during the session: ‘ES-02 Environmental applications of clay minerals’ of the International Clay Conference 2017.

References

REFERENCES

Abdel-Karim, A.M., Zaki, A.A., Elwan, W., El-Naggar, M.R. & Gouda, M.M. (2016) Experimental and modeling investigations of cesium and strontium adsorption onto clay of radioactive waste disposal. Applied Clay Science, 132–133, 391–401.Google Scholar
Benedicto, A., Missana, T. & Fernández, A.M. (2014) Interlayer collapse affects on cesium adsorption onto illite. Environmental Science & Technology, 48, 4909–4915.Google Scholar
Bostick, B.C., Vairavamurthy, M.A., Karthikeyan, K.G. & Chorover, J. (2002) Caesium adsorption on clay minerals: an EXAFS spectroscopic investigation. Environmental Science & Technology, 36, 2670–2676.Google Scholar
Chiang, P.N., Wang, M.K., Huang, P.M. & Wang, J.J. (2011) Effects of low molecular weight organic acids on 137Cs release from contaminated soils. Applied Radiation and Isotopes, 69, 844–851.Google Scholar
Delvaux, B., Kruyts, N. & Cremers, A. (2000) Rhizospheric mobilization of radiocesium in soils. Environmental Science & Technology, 34, 1489–1493.Google Scholar
Dzene, L., Ferrage, E., Viennet, J.C., Tertre, E. & Hubert, F. (2017) Crystal structure control of aluminized clay minerals on the mobility of caesium in contaminated soil environments. Scientific Report, 7, 43187.Google Scholar
Dzene, L., Tertre, E., Hubert, F. & Ferrage, E. (2015) Nature of the sites involved in the process of cesium desorption from vermiculite. Journal of Colloid and Interface Science, 455, 254–260.Google Scholar
Endo, M., Yoshikawa, E., Muramatsu, N., Takizawa, N., Kawai, T., Unuma, H., Sasaki, A., Masano, A., Takeyama, Y. & Kahara, T. (2013) The removal of cesium ion with natural Itaya zeolite and the ion exchange characteristics. Journal of Chemical Technology & Biotechnology, 88, 1597–1602.Google Scholar
Kahr, G., Kraehenbuehl, F., Müller-Vonmoos, M. & Stoeckli, H.F. (1986) Wasseraufnahmeund Wasserbewegung in Hochverdichtetem Bentonit. Nagra, Baden, Switzerland.Google Scholar
Kikuchi, R., Mukai, H., Kuramata, C. & Kogure, T. (2015) Cs-sorption in weathered biotite from Fukushima granitic soil. Journal of Mineralogical and Petrological Sciences, 110, 126–134.Google Scholar
Kogure, T., Morimoto, K., Tamura, K., Sato, H. & Yamagishi, A. (2012) XRD and HRTEM evidence for fixation of cesium ions in vermiculite clay. Chemistry Letters, 41, 380–382.Google Scholar
Komy, Z.R., Shaker, A.M., Heggy, S.E.M. & El-Sayed, M.E.A. (2014) Kinetic study for copper adsorption onto soil minerals in the absence and presence of humic acid. Chemosphere, 99, 117–124.Google Scholar
Matsumoto, K. (2002) Decomposition methods of sparingly soluble materials. BUNSEKI, 2, 60–66 (in Japanese).Google Scholar
McKinley, J.P., Zachara, J.M., Heald, S.M., Dohnalkova, A., Newville, M.G. & Sutton, S.R. (2004) Microscale distribution of cesium sorbed to biotite and muscovite. Environmental Science & Technology, 38, 1017–1023.Google Scholar
Michael, E.E. (2004) Soil and Water Chemistry: An Integrative Approach. CRC Press, Boca Raton, FL, USA.Google Scholar
Mimura, H. & Kanno, T. (1985) Distribution and fixation of cesium and strontium in zeolite A and chabazite. Journal of Nuclear Science and Technology, 22, 284–291.Google Scholar
Mishra, S., Sahoo, S.K., Bossew, P., Sorimachi, A. & Tokonami, S. (2018) Reprint of ‘Vertical migration of radio-caesium derived from the Fukushima Dai-ichi Nuclear Power Plant accident in undisturbed soils of grassland and forest’. Journal of Geochemical Exploration, 184B, 271–295.Google Scholar
Miura, T., Takizawa, N., Togashi, K., Sasaki, A. & Endo, M. (2018) Adsorption/desorption characteristics of cesium ions on natural and synthetic minerals. Journal of Ion Exchange, 29, 9–15.Google Scholar
Mukai, H., Hirose, A., Motai, S., Kikuchi, R., Tanoi, K., Nakanishi, T., Yaita, T. & Kogure, T. (2016) Caesium adsorption/desorption behavior of clay minerals considering actual contamination conditions in Fukushima. Scientific Reports, 6, 21543.Google Scholar
Murota, K., Saito, T. & Tanaka, S. (2016) Desorption kinetics of cesium from Fukushima soils. Journal of Environmental Radioactive, 153, 134–140.Google Scholar
Nakao, A., Ogasawara, S., Sano, O., Ito, T. & Yanai, J. (2014) Radiocesium sorption in relation to clay mineralogy of paddy soils in Fukushima, Japan. Science of the Total Environment, 468, 523–529.Google Scholar
Onikata, M., Kondo, M., Hayashi, N. & Yamanaka, S. (1999) Complex formation of cation-exchanged montmorillonites with propylene carbonate: osmotic swelling in aqueous electrolyte solutions. Clays and Clay Minerals, 47, 672–677.Google Scholar
Onodera, M., Kirishima, A., Nagao, S., Takamiya, K., Ohtsuki, T., Akiyama, D. & Sato, N. (2017) Desorption of radioactive cesium by seawater from the suspended particle in river water. Chemosphere, 185, 806–815.Google Scholar
Parajuli, D., Takahashi, A., Tanaka, H., Sato, M., Fukuda, S., Kamimura, R. & Kawamoto, T. (2015) Variation in available cesium concentration with parameters during temperature induced extraction of cesium from soil. Journal of Environmental Radioactivity, 140, 78–83.Google Scholar
Peeterbroeck, S., Alexandre, M., Jérôme, R. & Dubois, Ph. (2005) Poly (ethylene-co-vinyl cetate) /clay nanocomposites: effect of clay nature and organic modifiers on morphology, mechanical and thermal properties. Polymer Degradation and Stability, 90, 288–294.Google Scholar
Royer, B., Cardoso, N.F., Lima, E.C., Macedo, T.R. & Airoldi, C. (2010) A useful organofunctionalized layered silicate for textile dye removal. Journal of Hazardous Materials, 181, 366–374.Google Scholar
Sawhney, B.L. (1972) Selective sorption and fixation of cations by clay minerals: a review. Clays and Clay Minerals, 20, 93–100.Google Scholar
Stagnaro, S.Y.M., Rueda, M.L., Volzone, C. & Ortiga, J. (2012) Structural modification lamellar solid by thermal treatment. Effect on the Cd and Pb adsorptions from aqueous solution. Procedia Materials Science, 1, 180–184.Google Scholar
Staunton, S. & Roubaud, M. (1997) Adsorption of 137Cs on montmorillonite and illite: effect of charge compensating cation, ionic strength, concentration of Cs, K, and fluvic acid. Clays and Clay Minerals, 45, 251–260.Google Scholar
Tamura, K., Sato, H. & Yamagishi, A. (2015) Desorption of Cs+ ions from a vermiculite by exchanging with Mg2+ ions: effects of Cs+-capturing ligand. Journal of Radioanalytical and Nuclear Chemistry, 303, 2205–2210.Google Scholar
Wu, J., Li, B., Liao, J., Feng, Y., Zhang, D., Zhao, J., Wen, W., Yang, Y. & Liu, N. (2009) Behavior and analysis of cesium adsorption on montmorillonite mineral. Journal of Environmental Radioactivity, 100, 914–920.Google Scholar
Zachara, J.M., Smith, S.C., Liu, C., McKinley, J.P., Serne, R.J. & Gassman, P.L. (2002) Sorption of Cs+ to micaceous subsurface sediments from the Hanford site, USA. Geochemica et Cosmochimica Acta, 66, 193–211.Google Scholar
Zaunbrecher, L.K., Cygan, R.T. & Elliott, W.C. (2015) Molecular models of cesium and rubidium adsorption on weathered micaceous minerals. The Journal of Physical Chemistry A, 119, 5691–5700.Google Scholar