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Halloysite nanotubes with fluorinated cavity: an innovative consolidant for paper treatment

Published online by Cambridge University Press:  02 January 2018

Giuseppe Cavallaro ,
Giuseppe Lazzara ,
Stefana Milioto  and
Filippo Parisi
Giuseppe Cavallaro
Affiliation:
Department of Physics and Chemistry, Università degli Studi di Palermo, Viale delle Scienze, pad. 17, Palermo 90128, Italy
Giuseppe Lazzara*
Affiliation:
Department of Physics and Chemistry, Università degli Studi di Palermo, Viale delle Scienze, pad. 17, Palermo 90128, Italy
Stefana Milioto
Affiliation:
Department of Physics and Chemistry, Università degli Studi di Palermo, Viale delle Scienze, pad. 17, Palermo 90128, Italy
Filippo Parisi
Affiliation:
Department of Physics and Chemistry, Università degli Studi di Palermo, Viale delle Scienze, pad. 17, Palermo 90128, Italy
*
*E-mail: giuseppe.lazzara@unipa.it
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Abstract

Hybrid material based on halloysite nanotubes (HNTs) and sodium perfluorooctanoate (NaPF8) was used as a consolidant for paper treatment. The consolidation efficiency was determined by thermogravimetry as well as by paper grammage determination. Morphological analysis of the treated paper was performed by means of scanning electron microscopy while the effect of modified HNTs on the thermal behaviour of the cellulose fibres was investigated by differential scanning calorimetry which determined the combustion enthalpy of the paper.Water contact angle measurements were performed to study the paper wettability. The physico-chemical properties investigated (mesoscopic structure, thermal stability and wettability) of the treated paper were correlated successfully with the consolidation loading and, consequently, to the affinity between the fluorinated modified HNTs and the fibrous cellulose structure. This study proposes a new green protocol for paper consolidation based on natural tubular nanoparticles with a flame retardant effect.

Keywords

thermogravimetrydifferential scanning calorimetryhalloysitewettabilitypaper
Type
Research Article
Information
Clay Minerals , Volume 51 , Issue 3 , June 2016 , pp. 445 - 455
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2016

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