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Effect of Sonication on Particle-Size Distribution in Natural Muscovite and Biotite

Published online by Cambridge University Press:  01 January 2024

Luis A. Pérez-Maqueda ,
Francisco Franco ,
Miguel A. Avilés ,
Juan Poyato  and
José L. Pérez-Rodríguez
Luis A. Pérez-Maqueda*
Affiliation:
Instituto de Ciencia de Materiales de Sevilla, CSIC-Universidad de Sevilla, C. Américo Vespucio s/n, 41092 Sevilla, Spain
Francisco Franco
Affiliation:
Departamento de Química Inorgánica, Cristalografía y Mineralogía, Facultad de Ciencias, Campus de Teatinos, Universidad de Málaga, 29071 Málaga, Spain
Miguel A. Avilés
Affiliation:
Instituto de Ciencia de Materiales de Sevilla, CSIC-Universidad de Sevilla, C. Américo Vespucio s/n, 41092 Sevilla, Spain
Juan Poyato
Affiliation:
Instituto de Ciencia de Materiales de Sevilla, CSIC-Universidad de Sevilla, C. Américo Vespucio s/n, 41092 Sevilla, Spain
José L. Pérez-Rodríguez
Affiliation:
Instituto de Ciencia de Materiales de Sevilla, CSIC-Universidad de Sevilla, C. Américo Vespucio s/n, 41092 Sevilla, Spain
*
*E-mail address of corresponding author: maqueda@cica.es
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Abstract

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The effects of ultrasound treatment on the mean particle size, crystal structure, crystallite dimensions and specific surface area of natural muscovite and biotite samples have been investigated. Sonication of macroscopic flakes of muscovite and biotite produced a drastic particle-size reduction. The conditions for the preparation of micron and submicron-sized muscovite and biotite particles of narrow particle-size distribution by sonochemistry are described. The effect of sonication on particle-size reduction is more significant for muscovite than for biotite. Thus, for long sonication times (100 h), submicron and micron particles are predominant in muscovite and biotite, respectively. The resulting materials are crystalline, as assayed by X-ray diffraction, only broadening of the diffraction lines due to size-reduction was observed. Nuclear magnetic resonance studies revealed that the coordination of Al and Si was not modified by the treatment. Chemical analysis showed that the composition of the sample was not affected by the sonication except for a small contamination by Ti from the tip cup of the sonication instrument.

Keywords

BiotiteMicaMuscoviteNMRParticle SizeSonicationUltrasoundXRD
Type
Research Article
Information
Clays and Clay Minerals , Volume 51 , Issue 6 , December 2003 , pp. 701 - 708
Copyright
Copyright © 2003, The Clay Minerals Society

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