Hostname: page-component-78c5997874-94fs2 Total loading time: 0 Render date: 2024-11-10T10:09:47.523Z Has data issue: false hasContentIssue false
  • English
  • Français

Enhanced Second-Order Optical Nonlinearity of Dye Molecules Adsorbed onto Laponite Particles

Published online by Cambridge University Press:  28 February 2024

Carlo Boutton ,
Martti Kauranen ,
André Persoons ,
Michael P. Keung ,
Katrien Y. Jacobs  and
Robert A. Schoonheydt
Carlo Boutton
Affiliation:
Laboratory of Chemical and Biological Dynamics and Center for Research on Molecular Electronics and Photonics, Katholieke Universiteit Leuven, B-3001 Heverlee, Belgium
Martti Kauranen
Affiliation:
Laboratory of Chemical and Biological Dynamics and Center for Research on Molecular Electronics and Photonics, Katholieke Universiteit Leuven, B-3001 Heverlee, Belgium
André Persoons
Affiliation:
Laboratory of Chemical and Biological Dynamics and Center for Research on Molecular Electronics and Photonics, Katholieke Universiteit Leuven, B-3001 Heverlee, Belgium
Michael P. Keung
Affiliation:
Center for Surface Chemistry and Catalysis, Department of Interphase Chemistry, Katholieke Universiteit Leuven, B-3001 Heverlee, Belgium
Katrien Y. Jacobs
Affiliation:
Center for Surface Chemistry and Catalysis, Department of Interphase Chemistry, Katholieke Universiteit Leuven, B-3001 Heverlee, Belgium
Robert A. Schoonheydt
Affiliation:
Center for Surface Chemistry and Catalysis, Department of Interphase Chemistry, Katholieke Universiteit Leuven, B-3001 Heverlee, Belgium
Rights & Permissions [Opens in a new window]

Extract

Core share and HTML view are not available for this content. However, as you have access to this content, a full PDF is available via the ‘Save PDF’ action button.

Nonlinear-optical investigations of new materials are important for 2 complementary reasons. first, the requirements for materials to be used in device applications that utilize nonlinear interactions are very demanding. New approaches to materials research can yield materials with favorable properties compared to traditional nonlinear materials, as shown recently in several supramolecular systems (Cox et a1. 1990; Stucky and MacDougall 1990; Clays et a1. 1993; Kelderman et a1. 1993; Kauranen et a1. 1995; Lehn 1995). This is particularly true for 2nd-order nonlinear optics that require noncentrosymmetric materials (Prasad and Williams 1991). On the other hand. nonlinear-optical processes can provide new techniques to study the properties of new materials. The nonlinear techniques have the potential of being more sensitive than the existing techniques or providing information that is not accessible at all using the existing techniques (Shen 1984). Here again, 2nd-order processes are particularly important because they provide an extremely sensitive tool to study symmetry properties of materials.

Keywords

Clay-Dye CompositesLaponiteMethylene BlueNonlinear Optics
Type
Research Article
Information
Clays and Clay Minerals , Volume 45 , Issue 3 , June 1997 , pp. 483 - 485
Copyright
Copyright © 1997, The Clay Minerals Society

References

Bleam, W.F., (1990) Electrostatic potential at the basal (001) surface of talc and pyrophyllite as related to tetrahedral sheet distortions Clays Clay Miner 38 38–526.CrossRefGoogle Scholar
Cenens, J. and Schoonheydt, R.A., (1988) Visible spectroscopy of methylene blue on hectorite, laponite B, and barasym in aqueous suspension Clays Clay Miner 36 214–224 10.1346/CCMN.1988.0360302.CrossRefGoogle Scholar
Clays, K. Hendrickx, E. Triest, M. Verbiest, T. Persoons, A. Dehu, C. and Brédas, J.L., (1993) Nonlinear optical properties of proteins measured by hyper-Rayleigh scattering in solution Science 262 262–1422 10.1126/science.262.5138.1419.CrossRefGoogle ScholarPubMed
Clays, K. and Persoons, A., (1991) Hyper-Rayleigh scattering in solution Phys Rev Lett 66 66–2983 10.1103/PhysRevLett.66.2980.CrossRefGoogle ScholarPubMed
Cox, S.D. Gier, T.E. and Stucky, G.D., (1990) Second-harmonic generation by the self-aggregation of organic guests in molecular sieve hosts Chem Mater 2 2–619 10.1021/cm00011a600.CrossRefGoogle Scholar
Garfunkel-Shweky, D. Yariv, S., Elsen, A. Grobet, P. Keung, M. Leeman, H. Schoonheydt, R. and Toufar, H., (1995) Electronic and IR spectroscopy study of the basicity of the oxygen plane of Nasmectites treated with acridine orange Leuven, Belgium. Univ. of Leuven. 170.Google Scholar
Heesink, G.J.T. Ruiter, A.G.T. van Hulst, N.F. and Bölger, B., (1993) Determination of hyperpolarizability tensor components by depolarized hyper-Rayleigh scattering Phys Rev Lett 71 71–1002 10.1103/PhysRevLett.71.999.CrossRefGoogle ScholarPubMed
Heinz, T.F. Chen, C.K. Ricard, D. and Shen, Y.R., (1981) Optical second-harmonic generation from a monolayer of centrosymmetric molecules adsorbed on silver Chem Phys Lett 83 83–182 10.1016/0009-2614(81)80315-6.CrossRefGoogle Scholar
Heinz, T.F. Chen, C.K. Ricard, D. and Shen, Y.R., (1982) Spectroscopy of molecular monolayers by resonant second-harmonic generation Phys Rev Lett 48 48–481 10.1103/PhysRevLett.48.478.CrossRefGoogle Scholar
Kauranen, M. Verbiest, T. Boutton, C. Teerenstra, M.N. Clays, K. Schouten, A.J. Nolte, R.J.M. and Persoons, A., (1995) Supramolecular second-order nonlinearity of polymers with orientationally correlated chromophores Science 270 270–969 10.1126/science.270.5238.966.CrossRefGoogle Scholar
Kelderman, E. Heesink, G.J.T. Derhaeg, L. Verbiest, T. Klaase, P.T.A. Verboom, W. Engbersen, J. v. Hulst, N.F. Clays, K. Persoons, A. and Reinhoudt, D.N., (1993) Highly ordered films of neat calix[4]arenes for second order nonlinear optics Adv Mater 5 5–930 10.1002/adma.19930051211.CrossRefGoogle Scholar
Lehn, J.M., (1995) Supramolecular chemistry Weinheim VCH 10.1002/3527607439.CrossRefGoogle Scholar
Munn, R.W., (1995) Microscopic theory of molecular crystal surface second-harmonic generation J Chem Phys 103 103–859 10.1063/1.470066.CrossRefGoogle Scholar
Prasad, P.N. and Williams, D.J., (1991) Introduction to nonlinear optical effects in molecules and polymers New York J Wiley.Google Scholar
S’heeren, G. Derhaeg, L. Verbiest, T. Samyn, C. and Persoons, A., (1993) Nonlinear optical properties of polymers and thin polymer films Makromol Chem, Makromol Symp 69 193–203 10.1002/masy.19930690121.CrossRefGoogle Scholar
Shen, Y.R., (1984) The principles of nonlinear optics New York J Wiley.Google Scholar
Stucky, G.D. and MacDougall, J.E., (1990) Quantum confinement and host/guest chemistry: Probing a new dimension Science 247 247–678 10.1126/science.247.4943.669.CrossRefGoogle ScholarPubMed
Terhune, R.W. Maker, P.D. and Savage, C.M., (1965) Measurements of nonlinear light scattering Phys Rev Lett 14 14–684.CrossRefGoogle Scholar
Theng, B.K.G., (1974) The chemistry of clay-organic reactions London Adam Hilger.Google Scholar