Hostname: page-component-78c5997874-mlc7c Total loading time: 0 Render date: 2024-11-10T06:11:04.921Z Has data issue: false hasContentIssue false
  • English
  • Français

High-Temperature Transformation of Asbestos Tailings by Carbothermal Reduction

Published online by Cambridge University Press:  01 January 2024

Zhao-Hui Huang ,
Wen-Juan Li ,
Zi-He Pan ,
Yan-Gai Liu  and
Ming-Hao Fang
Zhao-Hui Huang
Affiliation:
School of Materials Science and Technology, China University of Geosciences (Beijing), Beijing 100083, P.R. China
Wen-Juan Li
Affiliation:
School of Materials Science and Technology, China University of Geosciences (Beijing), Beijing 100083, P.R. China
Zi-He Pan
Affiliation:
School of Materials Science and Technology, China University of Geosciences (Beijing), Beijing 100083, P.R. China
Yan-Gai Liu
Affiliation:
School of Materials Science and Technology, China University of Geosciences (Beijing), Beijing 100083, P.R. China
Ming-Hao Fang*
Affiliation:
School of Materials Science and Technology, China University of Geosciences (Beijing), Beijing 100083, P.R. China
*
*E-mail address of corresponding author: fmh@cugb.edu.cn
Rights & Permissions [Opens in a new window]

Abstract

Core share and HTML view are not available for this content. However, as you have access to this content, a full PDF is available via the ‘Save PDF’ action button.

The production and industrial use of asbestos cement and other asbestos-containing materials have been restricted in most countries because of the potential detrimental effects on human health and the environment. Chrysotile is the most common form of asbestos and investigations into how to recycle this serpentine phyllosilicate mineral have attracted extensive attention. Chrysotile asbestos tailings can be transformed thermally, at high temperature, by in situ carbothermal reduction (CR). The CR method aims to maximize use of the chrysotile available and uses high temperatures and carbon to change the mineral form and structure of the chrysotile asbestos tailings. When chrysotile asbestos is employed as the raw material and coke (carbon) powder is used as the reducing agent for CR transformation, stable, high-temperature composites consisting of forsterite, stishovite, and silicon carbide are formed. Forsterite (Mg2SiO4) was the most abundant crystalline phase formed in samples heat treated below 1500ºC. At 1600ºC, forsterite was exhausted through decomposition and β-SiC formed by reduction of stishovite. A larger proportion of β-SiC was generated as the carbon content was increased. This research revealed that both temperature and carbon addition play key roles in the transformation of chrysotile asbestos tailings.

Keywords

Asbestos TailingsCarbothermal ReductionChrysotileForsteriteThermal TransformationSilicon Carbide
Type
Research Article
Information
Clays and Clay Minerals , Volume 61 , Issue 1 , February 2013 , pp. 75 - 82
Copyright
Copyright © The Clay Minerals Society 2013

References

Auzende, A.L. Daniel, I. Reynard, B. Lemaire, C. and Guyot, F., 2004 High-pressure behavior of serpentine minerals: a Raman spectroscopic study Physics and Chemistry of Minerals 31 269–277.CrossRefGoogle Scholar
Berkheiser, V.E., 1982 Adsorption of stearic acid by chrysotile Clays and Clay Minerals 30 91–96.CrossRefGoogle Scholar
Brindley, G.W. and Brown, G., 1984 Crystal Structure of Clay Minerals and their X-ray Identification London Mineralogical Society.Google Scholar
Brindley, G.W. and Zussman, J., 1957 A structure study of the thermal transformation of serpentine minerals to forsterite American Mineralogist 42 461–474.Google Scholar
Bowen, N.L. and Anderson, O., 1914 The binary system MgO-SiO2 phase diagram American Journal of Science 37 487–500.CrossRefGoogle Scholar
Cheng, T.-W. and Hsu, C.-W., 2006 A study of silicon carbide synthesis from waste serpentine Chemosphere 64 510–514.CrossRefGoogle ScholarPubMed
Colangelo, F. Cioffi, R. Lavorgna, M. Verdolotti, L. and De Stefano, L., 2011 Treatment and recycling of asbestos-cement containing waste Journal of Hazardous Materials 195 391–397.CrossRefGoogle ScholarPubMed
Foresti, E. Gazzano, M. Gualtieri, A.F. Lesci, I.G. Lunelli, B. Pecchini, G. Renna, E. and Roveri, N., 2003 Determination of low levels of free fibres of chrysotile in contaminated soils by X-ray diffraction and FTIR spectroscopy Analytical and Bioanalytical Chemistry 376 653–658.CrossRefGoogle ScholarPubMed
Gidarakos, E. Anastasiadou, K. Koumantakis, E. and Nikolaos, S., 2008 Investigative studies for the use of an inactive asbestos mine as a disposal site for asbestos wastes Journal of Hazardous Materials 153 955–965.CrossRefGoogle ScholarPubMed
Gualtieri, A.F. Cavenati, C. Zanatto, I. Meloni, M. Elmi, G. and Gualtieri, M.L., 2008 The transformation sequence of cement-asbestos slates up to 1200 degrees C and safe recycling of the reaction product in stoneware tile mixtures Journal of Hazardous Materials 152 563–570.CrossRefGoogle Scholar
Gualtieri, A.F. Gualtieri, M.L. and Tonelli, M., 2008 In situ ESEM study of the thermal decomposition of chrysotile asbestos in view of safe recycling of the transformation product Journal of Hazardous Materials 156 260–266.CrossRefGoogle ScholarPubMed
Gualtieri, A.F. Giacobbe, C. and Viti, C., 2012 The dehydroxylation of serpentine group minerals American Mineralogist 97 666–680.CrossRefGoogle Scholar
Huang, T.-H., 1953 Serpentine-fused phosphate, citric solubility and glass content correlation Journal of Agricultural and Food Chemistry 1 62–67.CrossRefGoogle Scholar
Kim, D.-J. and Chung, H.-S., 2003 Synthesis and characterization of ZSM-5 zeolite from serpentine Applied Clay Science 24 69–77.CrossRefGoogle Scholar
Li, W.-J. Huang, Z.-H. Liu, Y.-G. Fang, M.-H. Ouyang, X. and Huang, S.-F., 2012 Phase behavior of serpentine mineral by carbothermal reduction nitridation Applied Clay Science 57 86–90.CrossRefGoogle Scholar
Li, Z.-H. Dai, Y.-N. and Xue, H.-S., 2005 Thermodynamical analysis and experimental test of magnesia by vacuum carbothermic reduction Nonferrous Metals 57 56–59.Google Scholar
Lin, P.-C. Huang, C.-W. Hsiao, C.-T. and Teng, H., 2008 Magnesium hydroxide extracted from a magnesium-rich mineral for CO2 sequestration in a gas-solid system Environmental Science & Technology 42 2748–2752.CrossRefGoogle Scholar
Lou, V.L.K. Mitchell, T.E. and Heuer, A.H., 1985 Review-graphical displays of the thermodynamics of high-temperature gas-solid reactions and their application to oxidation of metals and evaporation of oxides Journal of the American Ceramic Society 68 49–58.CrossRefGoogle Scholar
Lyubimov, D.N. Dolgopolov, K.N. Kozakov, A.T. and Nikolskii, A.V., 2011 Improvement of performance of lubricating materials with additives of clayey minerals Journal of Friction and Wear 32 442–451.CrossRefGoogle Scholar
Mazzoni, A.D. and Aglietti, E.F., 1998 SiC-Si3N4 bonded materials by the nitridation of SiC and talc Ceramics International 24 327–332.CrossRefGoogle Scholar
Mendelovici, E. Frost, R.L. and Kloprogge, J.T., 2001 Modification of chrysotile surface by organosilanes: An IR-photoacoustic spectroscopy study Journal of Colloid and Interface Science 238 273–278.CrossRefGoogle ScholarPubMed
Murphy, W.J. and Ross, R.A., 1977 A comparative study of thermal effects on surface and structural parameters of natural Californian and Quebec chrysotile asbestos up to 700 degrees C Clays and Clay Minerals 25 78–89.CrossRefGoogle Scholar
Nishikawa, K. Takahashi, K. Karjalainen, A. Wen, C.-P. Furuya, S. Hoshuyama, T. Todoroki, M. Kiyomoto, Y. Wilson, D. Higashi, T. Ohtaki, M. Pan, G. W. and Wagner, G., 2008 Recent mortality from pleural mesothelioma, historical patterns of asbestos use, and adoption of bans: A global assessment Environmental Health Perspectives 116 1675–1680.CrossRefGoogle Scholar
Papirer, J.H. Dovergne, G. Siffert, B. and Leroy, P., 1976 Surface modification of chrysotile asbestos under the influence of aluminium trichlorid Clays and Clay Minerals 24 101–102.CrossRefGoogle Scholar
Porcu, M. Orr, R. Cincotti, A. and Cao, G., 2005 Self-propagating reactions for environmental protection: Treatment of wastes containing asbestos Industrial & Engineering Chemistry Research 44 85–91.CrossRefGoogle Scholar
Pronost, J. Beaudoin, G. Lemieux, J.M. Hebert, R. Constantin, M. Marcouiller, S. Klein, M. Duchesne, J. Molson, J.W. Larachi, F. and Maldague, X., 2012 CO2-depleted warm air venting from chrysotile milling waste (Thetford Mines, Canada): Evidence for in-situ carbon capture from the atmosphere Geology 40 275–278.CrossRefGoogle Scholar
Qi, X.-W. Lu, L. Jia, Z.-N. Yang, Y.-L. and Liu, H.-R., 2012 Comparative tribological properties of magnesium hexasilicate and serpentine powder as lubricating oil additives under high temperature Tribology International 49 53–57.CrossRefGoogle Scholar
Schulze, R.K. Hill, M.A. Field, R.D. Papin, P.A. Hanrahan, R.J. and Byler, D.D., 2004 Characterization of carbonated serpentine using XPS and TEM Energy Conversion and Management 45 3169–3179.CrossRefGoogle Scholar
Valentine, R. Chang, M.J. Hart, R.W. Finch, G.L. and Fisher, G.L., 1983 Thermal modification of chrysotile asbestos: evidence for decreased cytotoxicity Environmental Health Perspectives 51 357–368.CrossRefGoogle ScholarPubMed
Wang, L.-J. Lu, A.-H. Wang, C.-Q. Zheng, X.-S. Zhao, D.-J. and Liu, R., 2006 Nano-fibriform production of silica from natural chrysotile Journal of Colloid and Interface Science 295 436–439.CrossRefGoogle ScholarPubMed
Wypych, F. Adad, L.B. Mattoso, N. Marangon, A.A.S. and Schreiner, W.H., 2005 Synthesis and characterization of disordered layered silica obtained by selective leaching of octahedral sheets from chrysotile and phlogopite structures Journal of Colloid and Interface Science 283 107–112.CrossRefGoogle ScholarPubMed
Zaremba, T. and Peszko, M., 2008 Investigation of the thermal modification of asbestos wastes for potential use in ceramic formulation Journal of Thermal Analysis and Calorimetry 92 873–877.CrossRefGoogle Scholar
Zaremba, T. Krzakała, A. Piotrowski, J. and Garczorz, D., 2010 Study on the thermal decomposition of chrysotile asbestos Journal of Thermal Analysis and Calorimetry 101 479–485.CrossRefGoogle Scholar