Hostname: page-component-78c5997874-m6dg7 Total loading time: 0 Render date: 2024-11-10T16:07:09.319Z Has data issue: false hasContentIssue false

Morphology and properties of polymer matrixnanocomposites

Published online by Cambridge University Press:  19 April 2010

Salah H.R. Ali*
Affiliation:
Engineering and Surface Metrology, National Institute for Standards (NIS), Giza, Egypt
M.K. Bedewy*
Affiliation:
Dean of Engineering, Misr Univ. for Science and Technology, 6th of October, Egypt
M.A. Etman
Affiliation:
Mechanical Eng. Dept, Al-Ahram Higher Institute for Eng. and Tech., Egypt
H.A. Khalil
Affiliation:
Chemistry Lab, National Research Centre (NRC), Dokki, Giza, Egypt
B.S. Azzam
Affiliation:
Design & Production Eng., Faculty of Eng., Cairo Univ., Egypt
*
* Correspondence:SalahAli20@yahoo.com
** Correspondence:KBedewy@yahoo.com
Get access

Abstract

Carbon nanotubes (CNTs) have become strongly promising nano-particles for developingnovel smart polymer matrix nanocomposites to satisfy the ever increasing designrequirements of the recent avenues of space industry and other special structuralapplications. The objective of this paper is to investigate the influence of doped anddispersed CNTs in polymer matrix on its intrinsic properties. Three different types ofpolymers; polyvinylchloride (PVC), polymethylemethacrylate (PMMA), and polystyrene (PS)were subjected to this experimental investigation. CNTs/polymer matrix composites with acontent ratio of CNTs up to 5% by weight were synthesized in lab. The nanocomposites werethen characterized by measuring their mechanical, electrical, and thermal properties. Inaddition, thermo gravimetric analysis (TGA), Fourier transform infra red spectroscopy(FTIR), and scanning electron microscopy (SEM) were applied, and the results are presentedand discussed. It can be generally concluded that both PMMA and PS polymers disclosed muchbetter matching ability and cross linking ability with the interweaving CNTs than the PVC.Both PMMA and PS polymers may thus be nominated for further extension of the investigationto cover a wider range of CNTs content ratios in an endeavour towards searching formaximum specific performance properties of such nanocomposites.

Type
Research Article
Copyright
© EDP Sciences 2010

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

M. Eijiro, Carbon Nanotube-Polymer Composite for Light-Driven Microthermal Control (Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, 2008), Vol. 47, pp. 3610–3613
Martel, R., Schmidt, T., Shea, H.R., Hertel, T., Single and multi-wall carbon nanotube field-effect transistors, Appl. Phys. Lett. 3, 2447 (1998) CrossRefGoogle Scholar
B. Sundaray, Preparation and Electrical Characterization of Electrospun Fibers of Carbon Nanotube-Polymer Nanocomposites, Ph.D. thesis, Dept of Physics, Indian Institute of Technology, Madras Chennai, India, 2006, www.physics.iitm.ac.in/research_files/synopsis/bibek.pdf
Salah H.R. Ali, M.A. Etman, B.S. Azam, M.K. Bedewy, Parametric study of CNTs production using submerged arc-discharge technique, in Proceeding of the CON008 Conference, Saudi Arabia (2008)
M.A. Etman, Synthesis and evaluation of carbon nano-tubes and its applications in nanocomposites, Ph.D. thesis, Mech. Design & Prod. Eng. Dept., Cairo Univ., 2008
H. Xu, S. Zhang, S.M. Anlage, L. Hu, G. Grüner, Frequency- and electric-field-dependent conductivity of single-walled carbon nanotube networks of varying density, The American Physical Society, Phys. Rev. B 77, 075418 (2008)
Endo, S.A., Hikosaka, M.J., Conditions for melt crystallization without thermal degradation and equilibrium melting temperature of atactic poly (vinyl alcohol), Macromol, Sci. Phys. Part B 42, 793 (2003) CrossRefGoogle Scholar
J.W. Gillman, D.L. VanderHart, T. Kashiwagi, Thermal decomposition chemistry of poly (vinyl alcohol)’, Fire and Polymers II: Materials and Test for Hazard Prevention ACS (1994), Vol. 599, p. 161
M.N. Ibrahim, Comparative studies of polymerization techniques for polymer nanocomposites synthesis for industrial applications, MSc thesis, Helwan University, Cairo, Egypt, 2007
Ali, Salah H.R., Etman, M.A., Azam, B.S., Rashed, R.M., Bedewy, M.K., Advanced Nanometrology Techniques for Carbon Nanotubes Characterization, J. Metrol. Meas. Syst. 15, 551 (2008) Google Scholar