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Air-stable, unoxidized, hydrocarbon-dispersible boron nanoparticles

Published online by Cambridge University Press:  31 January 2011

Brian Van Devener ,
Jesus Paulo L. Perez  and
Scott L. Anderson
Brian Van Devener
Affiliation:
Department of Chemistry, University of Utah, Salt Lake City, Utah 84112
Jesus Paulo L. Perez
Affiliation:
Department of Chemistry, University of Utah, Salt Lake City, Utah 84112
Scott L. Anderson*
Affiliation:
Department of Chemistry, University of Utah, Salt Lake City, Utah 84112
*
a) Address all correspondence to this author. e-mail: anderson@chem.utah.edu
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Abstract

Here we describe a simple method to produce boron nanoparticles with control over surface chemistry and dispersiblity in different solvents, with potential applications ranging from high energy density fuels to neutron capture therapy. The methodology should be adaptable to many hard materials; indeed, we have produced hydrocarbon-dispersible silicon nanoparticles using a procedure similar to that described below. The method, based on high-energy milling, with subsequent sedimentation to separate aggregates, produces gram quantities of nanoparticles in a narrow distribution of particle sizes centered around 50 nm, and should be readily scalable to industrial scale production.

Keywords

BNanoscalePassivation
Type
Rapid Communications
Information
Journal of Materials Research , Volume 24 , Issue 11 , November 2009 , pp. 3462 - 3464
Copyright
Copyright © Materials Research Society 2009

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References

1.Risha, G.A., Evans, B.J., Boyer, E., and Kuo, K.K.: Metals energetic additives, and special binders used in solid fuels for hybrid rockets. Prog. Astronaut. Aeronaut. 218, 413 (2007).Google Scholar
2.Slutsky, V.G., Tsyganov, S.A., Severin, E.S., and Polenov, L.A.: Synthesis of small-scale boron-rich nano size particles. Propellants, Explosives, Pyrotechnics 30, 303 (2005).CrossRefGoogle Scholar
3.Risha, G.A., Boyer, E., Evans, B., Kuo, K.K., and Malek, R.: Characterization of nano-sized particles for propulsion applications (Mater. Res. Soc. Symp. Proc. 800, Warrendale, PA, 2003), p. 243.Google Scholar
4.Kuo, K.K., Risha, G.A., Evans, B.J., and Boyer, E.: Potential usage of energetic nano-sized powders for combustion and rocket propulsion (Mater. Res. Soc. Symp. Proc. 800, 2003), p. 3.Google Scholar
5.Petersen, M.S., Petersen, C.C., Agger, R., Sutmuller, M., Jensen, M.R., Soerensen, P.G., Mortensen, M.W., Hansen, T., Bjoerholm, T., Gundersen, H.J., Huiskamp, R., and Hokland, M.: Boron nanoparticles inhibit tumor growth by boron neutron capture therapy in the murine B16-OVA model. Anticancer Res. 28, 571 (2008).Google ScholarPubMed
6.Zhu, Y., Koh, Y.C., Maguire, J.A., and Hosmane, N.S.: Boronbased nanostructures: Precursors to modern materials. Polym. Preprints 49, 857 (2008).Google Scholar
7.Pickering, L., Mitterbauer, C., Browning, N.D., Kauzlarich, S.M., and Power, P.P.: Room temperature synthesis of surface-functionalised boron nanoparticles. Chem. Commun. 6, 580 (2007).CrossRefGoogle Scholar
8.Xu, T.T., Zheng, J-G., Wu, N., Nicholls, A.W., and Roth, J.R.: Crystalline boron nanoribbons: Synthesis and characterisation. Nano Lett. 4, 963 (2004).CrossRefGoogle Scholar
9.Chiu, Y.S., Shaw, P.W., and Ho, S.Y.: Bond analysis of coated boron powder, in Combustion of Boron-Based Solid Propellants Solid Fuels, edited by Kuo, K.K. (CRC, Boca Raton, FL, 1993), p. 181.Google Scholar
10.Shyu, I-M. and Liu, T-K.: Combustion characteristics of GAPcoated boron particles and the fuel-rich solid propellant. Combust. Flame 100, 634 (1995).CrossRefGoogle Scholar
11.Fink, L.E.: The Boeing Company: Slurry fuels and associated methods. U.S. Patent No. 2007/0056212 A1, 2007.Google Scholar
12.Bunker, C.E. and Karnes, J.J.: Low-temperature stability and hightemperature reactivity of iron-based core-shell nanoparticles. J. Am. Chem. Soc. 126, 10852 (2004).CrossRefGoogle ScholarPubMed
13.Powell, C.J.: Elemental binding energies for x-ray photoelectron spectroscopy. Appl. Surf. Sci. 89, 141 (1995).CrossRefGoogle Scholar
14.Wagner, C.D., Naumkin, A.V., Kraut-Vass, A., Allison, J.W., Powell, C.J., and Rumble, J.R. Jr.: NIST X-ray photoelectron spectroscopy database, 2003.Google Scholar