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Synthesis of magnesium hydroxide nanoneedles and short nanorods on polymer dispersant template

Published online by Cambridge University Press:  31 January 2011

Hong Yan
Affiliation:
Key Laboratory of Interface Science and Engineering in Advanced Materials of Taiyuan University of Technology, Ministry of Education, Taiyuan, Shanxi 030024, People’s Republic of China; and College of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan, Shanxi 030024, People’s Republic of China
Jianming Wu
Affiliation:
Key Laboratory of Interface Science and Engineering in Advanced Materials of Taiyuan University of Technology, Ministry of Education, Taiyuan, Shanxi 030024, People’s Republic of China; and College of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan, Shanxi 030024, People’s Republic of China
Xuehu Zhang
Affiliation:
Key Laboratory of Interface Science and Engineering in Advanced Materials of Taiyuan University of Technology, Ministry of Education, Taiyuan, Shanxi 030024, People’s Republic of China; and College of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan, Shanxi 030024, People’s Republic of China
Yan Zhang
Affiliation:
Key Laboratory of Interface Science and Engineering in Advanced Materials of Taiyuan University of Technology, Ministry of Education, Taiyuan, Shanxi 030024, People’s Republic of China; and College of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan, Shanxi 030024, People’s Republic of China
Liqiao Wei
Affiliation:
Key Laboratory of Interface Science and Engineering in Advanced Materials of Taiyuan University of Technology, Ministry of Education, Taiyuan, Shanxi 030024, People’s Republic of China; and College of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan, Shanxi 030024, People’s Republic of China
Xuguang Liu
Affiliation:
College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan, Shanxi 030024, People’s Republic of China
Bingshe Xu*
Affiliation:
Key Laboratory of Interface Science and Engineering in Advanced Materials of Taiyuan University of Technology, Ministry of Education, Taiyuan, Shanxi 030024, People’s Republic of China; and College of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan, Shanxi 030024, People’s Republic of China
*
a)Address all correspondence to this author.e-mail: xubs@public.ty.sx.cn
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Abstract

Magnesium hydroxide nanoneedles and nanorods were synthesized by reverse precipitation in the presence of polyethylene glycol (MW 1000) at ambient temperature. The obtained magnesium hydroxide crystals were characterized in terms of morphology, particle size, crystal structure, and thermal stability by high-resolution transmission electron microscopy, x-ray diffraction, infrared spectroscopy, and thermogravimetric and differential thermal analysis. The experimental results show that the growth of magnesium hydroxide crystals and the dispersivity of the nanostructures were greatly influenced by polymer dispersant. The mechanism of the formation of magnesium hydroxide nanorods and nanoneedles was also proposed.

Type
Articles
Copyright
Copyright © Materials Research Society 2007

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References

REFERENCES

1Rosei, F.: Nanostructrued surfaces: Challenges and frontiers in nanotechnology. J. Phys.: Condens. Matter 16, S1373 2004Google Scholar
2Barth, J.V., Costantini, G.Kern, K.: Engineering atomic and molecular nanostructures at surfaces. Nature 437, 671 2005CrossRefGoogle ScholarPubMed
3Li, Y-D., Sui, M., Ding, Y., Zhang, G-H., Zhuang, J.Wang, C.: Preparation of Mg(OH)2 nanorods. Adv. Mater. 12, 818 20003.0.CO;2-L>CrossRefGoogle Scholar
4Lv, J-P., Qiu, L-Z.Qu, B-J.: Controlled growth of three morphological structures of magnesium hydroxide nanoparticles by wet precipitation method. J. Cryst. Growth 267, 676 2004CrossRefGoogle Scholar
5Guo, L., Ji, Y-L.Xu, H-B.: Regularly shaped, single-crystalline ZnO nanorods with Wurtzite Structure. J. Am. Chem. Soc. 124, 14864 2002CrossRefGoogle ScholarPubMed
6Sun, Y-G.Xia, Y-N.: Large-scale synthesis of uniform silver nanowires through a soft, self-seeding, polyol process. Adv. Mater. 14, 833 20023.0.CO;2-K>CrossRefGoogle Scholar
7Yan, L., Zhuang, J., Sun, X-M., Deng, Z-X.Li, Y-D.: Formation of rod-like Mg(OH)2 nanocrystallites under hydrothermal conditions and the conversion to MgO nanorods by thermal dehydration. Mater. Chem. Phys. 76, 119 2001CrossRefGoogle Scholar
8Fan, W-L., Sun, S-X., Song, X-Y., Zhang, W-M., Yu, H-Y., Tan, X-J.Cao, G-X.: Controlled synthesis of single-crystalline Mg(OH)2 nanotubes and nanorods via a solvothermal process. J. Solid State Chem. 177, 2329 2004CrossRefGoogle Scholar
9Fan, W-L., Sun, S-X., You, L-P., Cao, G-X., Song, X-Y., Zhang, W-M.Yu, H.Y.: Solvothermal synthesis of Mg(OH)2 nanotubes using Mg10(OH)18Cl2·5H2O nanowires as precursors. J. Mater. Chem. 13, 3062 2003CrossRefGoogle Scholar
10Wu, H-Q., Shao, M-W., Gu, J-S.Wei, X-W.: Microwave-assisted synthesis of fibre-like Mg(OH)2 nanoparticles in aqueous solution at room temperature. Mater. Lett. 58, 2166 2004CrossRefGoogle Scholar
11Hsu, J-P.Nacu, A.: Prepatation of submicron-sized Mg(OH)2 particles through precipitation. Colliods Surf. A 262, 220 2005CrossRefGoogle Scholar
12Henrist, C., Mathieu, J.P., Vogels, C., Rulmont, A.Cloots, R.J.: Morphological study of magnesium hydroxide nanoparticles precipitated in dilute aqueous solution. J. Cryst. Growth 249, 321 2003CrossRefGoogle Scholar
13Xu, B-Q., Wei, J-M., Wang, H-Y., Sun, K-Q.Zhu, Q-M.: Nano-MgO: Novel preparation and application as support of Ni catalyst for CO2 reforming of methane. Catal. Today 68, 217 2001CrossRefGoogle Scholar
14Sharifi, F.Azaiez, J.: Vortex dynamics of fiber-laden free shear flows. J. Non-Newtonian Fluid Mech. 127, 73 2005CrossRefGoogle Scholar
15Göschel, U., Lutz, W.Davidson, N.C.: The influence of a polymeric nucleating additive on the crystallisation in glass fibre reinforced polyamide 6 composites. Compos. Sci. Technol. 2007CrossRefGoogle Scholar
16Phillips, V.A., Kolbe, J.L.Opperhauser, H.: Effect of pH on the growth of Mg(OH)2 crystals in an aqueous environment at 60 °C. J. Cryst. Growth 41, 228 1977CrossRefGoogle Scholar
17Du, J-M., Liu, Z-M., Wu, W-Z., Li, Z-H., Han, B-X.Huang, Y.: Preparation of single-crystal copper ferrite nanorods and nanodisks. Mater. Res. Bull. 40, 928 2005CrossRefGoogle Scholar
18Zhang, M., Wang, Z-H., Xi, G-C.Ma, D-K.: Large-scale synthesis of antimony nanobelt bundles. J. Cryst. Growth 268, 215 2004CrossRefGoogle Scholar
19Yates, M.Z., Ott, K.C., Birnbaum, E.R.McCleskey, T.M.: Hydrothermal synthesis of molecular sieve fibers: Using microemulsions to control crystal morphology. Angew. Chem., Int. Ed. Engl. 41, 476 20023.0.CO;2-S>CrossRefGoogle ScholarPubMed
20 JCPDS No. 7-239. International Center for Diffraction Data: Swarthmore, PA, 1982.Google Scholar
21Yan, H.Xu, B-S.: Preparation of α-Al2O3/W nanocomposite powder. J. Inorg. Mater. 18, 1127 2003Google Scholar
22Saravanan, L.Subramanian, S.: Surface chemical studies on the competitive adsorption of poly(ethylene glycol) and ammonium poly(methacrylate) onto alumina. J. Colloid Interface Sci. 284, 363 2005CrossRefGoogle ScholarPubMed
23Qiu, L-Z., Xie, R-C., Ding, P.Qu, B-J.: Preparation and characterization of Mg(OH)2 nanoparticles and flame-retardant property of its nanocomposites with EVA. Compos. Struct. 62, 391 2003CrossRefGoogle Scholar