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Vacuum-ultraviolet–vis luminescence of dibarium magnesium orthoborate Ba2Mg(BO3)2 doped with Ce3+ and Eu2+ ions

Published online by Cambridge University Press:  01 April 2006

Huihong Lin ,
Hongbin Liang ,
Zifeng Tian ,
Qiang Su ,
Hanyu Xie ,
Jinfu Ding ,
Guobin Zhang  and
Yibing Fu
Huihong Lin
Affiliation:
State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, People's Republic of China
Hongbin Liang*
Affiliation:
State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, People's Republic of China
Zifeng Tian
Affiliation:
State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, People's Republic of China
Qiang Su
Affiliation:
State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, People's Republic of China
Hanyu Xie
Affiliation:
State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, People's Republic of China
Jinfu Ding
Affiliation:
State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, People's Republic of China
Guobin Zhang
Affiliation:
National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei 230026, People's Republic of China
Yibing Fu
Affiliation:
National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei 230026, People's Republic of China
*
a) Address all correspondence to this author. e-mail: cesbin@mail.sysu.edu.cn
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Abstract

The spectroscopic properties of Ba2Mg(BO3)2:Ce3+ and Ba2Mg(BO3)2:Eu2+ in vacuum-ultraviolet-vis range were investigated. The 5d crystal-field splitting components and the barycenter of Ce3+, the lowest 5d levels, the emission and the Stokes shifts of Eu2+ and Ce3+ in the host lattices, as well as the host-related absorption are identified and discussed in terms of the crystal structure of the host lattice.

Keywords

FiringLuminescencePowder
Type
Articles
Information
Journal of Materials Research , Volume 21 , Issue 4 , April 2006 , pp. 864 - 869
Copyright
Copyright © Materials Research Society 2006

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References

REFERENCES

1.Verstegen, J.M.P.J.: The luminescence of Tb3+ in borates of the composition X2Z(BO3)2 (X = Ba, Sr, Ca; Z = Ca, Mg). J. Electrochem. Soc. 121, 1631 (1974).CrossRefGoogle Scholar
2.Akella, A., Keszler, D.A.: Structure and Eu2+ luminescence of dibarium magnesium orthoborate. Mater. Res. Bull. 30, 105 (1995).CrossRefGoogle Scholar
3.Diaz, A., Keszler, D.A.: Red, green, and blue Eu2+ luminescence in solid-state borates: A structure-property relationship. Mater. Res. Bull. 31, 147 (1996).CrossRefGoogle Scholar
4.Poort, S.H.M., Meijerink, A., Blasse, G.: Lifetime measurements in Eu2+-doped host lattices. J. Phys. Chem. Solids 58, 1451 (1997).CrossRefGoogle Scholar
5.Diaz, A., Keszler, D.A.: Eu2+ luminescence in the borates X2Z(BO3)2 (X = Ba, Sr; Z = Mg, Ca). Chem. Mater. 9, 2071 (1997).CrossRefGoogle Scholar
6.Blasse, G., Grabmaier, B.C.: Luminescent Materials (Springer-Verlag Press, Berlin, 1994).CrossRefGoogle Scholar
7.Shionoga, S., Yen, W.M.: Phosphor Handbook (CRC Press, Boca Raton, FL, 1999).Google Scholar
8.Yokosawa, N., Sato, G., Nakazawa, E.: Improvement of luminescence degradation of PDP blue phosphor with new UV phosphor. J. Electrochem. Soc. 150, H197 (2003).CrossRefGoogle Scholar
9.Koike, J., Kojima, T., Toyonaga, R., Kagami, A., Hase, T., Inaho, S.: New tricolor phosphors for gas discharge display. J. Electrochem. Soc. 126, 1008 (1979).CrossRefGoogle Scholar
10.Srivastava, A.M., Doughty, D.A., Beers, W.W.: Photon cascade luminescence of Pr3+ in LaMgB5O10. J. Electrochem. Soc. 143, 4113 (1996).CrossRefGoogle Scholar
11.Srivastava, A.M., Doughty, D.A., Beers, W.W.: On the vacuumultraviolet excited luminescence of Pr3+ in LaB3O6. J. Electrochem. Soc. 144, L190 (1997).CrossRefGoogle Scholar
12.Kwon, I-E., Yu, B-Y., Bae, H., Hwang, Y-J., Kwon, T-W., Kim, C-H., Pyun, C-H., Kim, S-J.: Luminescence properties of borate phosphors in the UV/VUV region. J. Lumin. 87–89, 1039 (2000).CrossRefGoogle Scholar
13.Jüstel, T., Krupa, J-C., Wiechert, D.U.: VUV spectroscopy of luminescent materials for plasma display panels and Xe discharge lamps. J. Lumin. 93, 179 (2001).CrossRefGoogle Scholar
14.Dominiak-Dzika, G., Ryba-Romanowski, W., Kovács, L., Beregi, E.: Effect of temperature on luminescence and VUV to visible conversion in the YAl3(BO3)4:Dy3+ (YAB:Dy) crystal. Radiat. Meas. 38, 557 (2004).CrossRefGoogle Scholar
15.Liang, H.B., Shi, J.S., Su, Q., Zhang, S.Y., Tao, Y.: Spectroscopic properties of Ce3+-doped MBPO5 (M = Ca, Sr, Ba) under VUV excitation. Mater. Chem. Phys. 92, 180 (2005).CrossRefGoogle Scholar
16.Liang, H.B., Tao, Y., Xu, J.H., He, H., Wu, H., Chen, W.X., Wang, S.B., Su, Q.: Photoluminescence of Ce3+-, Pr3+-, and Tb3+-activated Sr3Ln(PO4)3 under VUV-UV excitation. J. Solid State Chem. 177, 901 (2004).CrossRefGoogle Scholar
17.Dorenbos, P.: 5d-level energies of Ce3+ and the crystalline environment. I. Fluoide compounds. Phys. Rev. B 62, 15640 (2000).CrossRefGoogle Scholar
18.Dorenbos, P.: 5d-level energies of Ce3+ and the crystalline environment. III. Oxides containing ionic complexes. Phys. Rev. B 64, 125117 (2001).CrossRefGoogle Scholar
19.Nag, A., Kutty, T.R.N.: Photoluminescence due to efficient energy transfer from Ce3+ to Tb3+ and Mn2+ in Sr3Al10SiO20. Mater. Chem. Phys. 91, 524 (2005).CrossRefGoogle Scholar
20.Dorenbos, P.: f→d transition energies of divalent lanthanides in inorganic compounds. J. Phys.: Condens. Matter 15, 575 (2003).Google Scholar
21.Dorenbos, P.: Relation between Eu2+ and Ce3+ f-d transition energies in inorganic compounds. J. Phys.: Condens. Matter 15, 4797 (2003).Google Scholar