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Fabrication of zeolite MFI membranes supported by α-Al2O3 hollow ceramic fifibers for CO2 separation

Published online by Cambridge University Press:  06 June 2013

Songjie Fan ,
Jia Liu ,
Feng Zhang ,
Shuyuan Zhou  and
Fuxing Sun
Songjie Fan
Affiliation:
Department of Chemistry, State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130012, People’s Republic of China
Jia Liu
Affiliation:
Department of Chemistry, State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130012, People’s Republic of China
Feng Zhang
Affiliation:
Department of Chemistry, State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130012, People’s Republic of China
Shuyuan Zhou
Affiliation:
Department of Chemistry, State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130012, People’s Republic of China
Fuxing Sun*
Affiliation:
Department of Chemistry, State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130012, People’s Republic of China
*
a)Address all correspondence to this author. e-mail: fxsun@jlu.edu.cn
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Abstract

High-performance and continuous zeolite MFI membranes have been successfully fabricated, using in situ hydrothermal synthetic method, on α-Al2O3 hollow ceramic fifibers (HCFs). The CO2 separation properties of the as-prepared MFI membrane are studied by single gas permeation and binary gas permeation of CO2/N2 and CO2/CH4. The separation results show that the membrane exhibits high CO2 selectivity with separation factors of 9.2 and 6.0 for CO2/N2 and CO2/CH4, respectively. A preferred permeance for CO2 in the binary gas mixtures is about 3 × 10−7mol/(m2 s Pa). Furthermore, the supported MFI membrane possesses high mechanical strength, strong thermal stability, and high reproducibility, which are expected to have potential applications in industrial CO2 recycling.

Type
Articles
Information
Journal of Materials Research , Volume 28 , Issue 13: FOCUS ISSUE: Frontiers in Thin-Film Epitaxy and Nanostructured Materials , 14 July 2013 , pp. 1870 - 1876
Copyright
Copyright © Materials Research Society 2013 

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