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Newly designed organic/inorganic film for optical second-harmonic generation

Published online by Cambridge University Press:  31 January 2011

Tomokatsu Hayakawa ,
Dai Imaizumi  and
Masayuki Nogami
Tomokatsu Hayakawa
Affiliation:
Department of Materials Science and Engineering, Nagoya Institute of Technology, Gokiso, Showa, Nagoya, Aichi 466-8555, Japan
Dai Imaizumi
Affiliation:
Department of Materials Science and Engineering, Nagoya Institute of Technology, Gokiso, Showa, Nagoya, Aichi 466-8555, Japan
Masayuki Nogami
Affiliation:
Department of Materials Science and Engineering, Nagoya Institute of Technology, Gokiso, Showa, Nagoya, Aichi 466-8555, Japan
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Abstract

In this paper we report the fabrication of organic/inorganic film for optical secondharmonic generation by a sol-gel method for the purpose of the improvement of thermal stability and chemical resistance. The film contains the azo dye Disperse Orange 3 protected by poly(vinylpyrrolidone) in a reticulation of silica gel, whose structure was developed by the spinodal decomposition and the gel-forming process as temperature increased. Corona-poling at elevated temperature could successively induce the optical second-harmonic nonlinearities. The dependence of temperature and field strength on the second-harmonic intensity was also investigated.

Type
Articles
Information
Journal of Materials Research , Volume 15 , Issue 2 , February 2000 , pp. 530 - 535
Copyright
Copyright © Materials Research Society 2000

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