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Noncontact thermophysical property measurement of liquid cerium by electrostatic levitation

Published online by Cambridge University Press:  31 January 2011

Jianqiang Li ,
Takehiko Ishikawa ,
Junpei T. Okada ,
Yuki Watanabe ,
Jianding Yu ,
Shinichi Yoda  and
Zhangfu Yuan
Jianqiang Li*
Affiliation:
Japan Aerospace Exploration Agency, Tsukuba, Ibaraki 305-8505, Japan; and State Key Laboratory of Multiphase Complex System, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China
Junpei T. Okada
Affiliation:
Japan Aerospace Exploration Agency, Tsukuba, Ibaraki 305-8505, Japan
Yuki Watanabe
Affiliation:
Advanced Engineering Services Co. Ltd., Tsukuba, Ibaraki 305-0032, Japan
Shinichi Yoda
Affiliation:
Japan Aerospace Exploration Agency, Tsukuba, Ibaraki 305-8505, Japan
Zhangfu Yuan
Affiliation:
State Key Laboratory of Multiphase Complex System, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China
*
a) Address all correspondence to this author. e-mail: jqli@home.ipe.ac.cn
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Abstract

The knowledge of thermophysical properties of active metals is critical to understand their metallurgical processes and further industrial applications. However, due to high reactivity and melt contamination from a crucible and gaseous environment, accurate values of the properties are hard to obtain using conventional methods such as the sessile-drop method. In the present study, a vacuum electrostatic levitator was used to circumvent these difficulties and enabled the noncontact determination of thermophysical properties of liquid cerium even in an undercooled state. The data of density, surface tension, and viscosity of molten cerium were reported, as well as their temperature dependence.

Keywords

CeLiquidMetal
Type
Rapid Communications
Information
Journal of Materials Research , Volume 24 , Issue 7 , July 2009 , pp. 2449 - 2452
Copyright
Copyright © Materials Research Society 2009

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References

1Lide, D.R. and Frederikse, H.P.R.: CRC Handbook of Chemistry and Physics, 78th ed. (CRC, Boca Raton, FL, 1997), pp. 112–123.Google Scholar
2Rhim, W-K., Chung, S-K., Barber, D., Man, K-F., Gutt, G., Rulison, A.A., and Spjut, R.E.: An electrostatic levitator for hightemperature containerless materials processing in l-g. Rev. Sci. Instrum. 64, 2961 (1993).Google Scholar
3Paradis, P-F., Ishikawa, T., and Yoda, S.: Electrostatic levitation research and development at JAXA: Past and present activities in thermophysics. Int. J. Thermophys. 26, 1031 (2005).CrossRefGoogle Scholar
4Paradis, P-F. and Rhim, W-K.: Thermophysical properties of zirconium at high temperature. J. Mater. Res. 14, 3713 (1999).Google Scholar
5Yu, J., Paradis, P-F., Ishikawa, T., Yoda, S., Saita, Y., Itoh, M., and Kano, F.: Giant dielectric constant of hexagonal BaTiO3 crystal grown by containerless processing. Chem. Mater. 16, 3973 (2004).Google Scholar
6Paradis, P-F., Ishikawa, T., Fujii, R., and Yoda, S.: Physical properties of liquid and undercooled tungsten by levitation techniques. Appl. Phys. Lett. 86, 041901 (2005).Google Scholar
7Paradis, P-F., Ishikawa, T., and Yoda, S.: Noncontact density measurements of tantalum and rhenium in the liquid and undercooled states. Appl. Phys. Lett. 83, 4047 (2003).Google Scholar
8Paradis, P-F., Ishikawa, T., and Yoda, S.: Thermophysical properties of liquid and supercooled ruthenium measured by noncontact methods. J. Mater. Res. 19, 590 (2004).Google Scholar
9Ishikawa, T., Paradis, P-F., Itami, T., and Yoda, S.: Non-contact thermophysical property measurements of refractory metals using an electrostatic levitator. Meas. Sci. Technol. 16, 443 (2005).Google Scholar
10Ishikawa, T., Paradis, P-F., Watanabe, Y., and Yoda, S.: Development of non-contact electrical resistivity measurement technique using an electrostatic levitator. J. Jpn. Soc. Microgravity Appl. 25, 399 (2008).Google Scholar
11Deluga, G.A., Salge, J.R., Schmidt, L.D., and Verykios, X.E.: Renewable hydrogen from ethanol by autothermal reforming. Science 303, 993 (2004).Google Scholar
12Esch, F., Fabris, S., Zhou, L., Montini, T., Africh, C., Fornasiero, P., Comelli, G., and Rosei, R.: Electron localization determines defect formation on ceria substrates. Science 309, 752 (2005).Google Scholar
13Lambertin, D., Homme, S.C., Bourges, G., and Sanchez, S.: Activity coefficients of plutonium and cerium in liquid gallium at 1073 K: Application to a molten salt/solvent metal separation concept. J. Nucl. Mater. 341, 131 (2005).Google Scholar
14Wu, C.M.L., Yu, D.Q., Law, C.M.T., and Wang, L.: Properties of lead-free solder alloys with rare earth element additions. Mater. Sci. Eng., R 44, 1 (2004).Google Scholar
15Kononenko, V.I., Sukhman, A.L., Gruverman, S.L., and Torokin, V.V.: Density and surface tension of liquid rare earth metals, scandium, and yttrium. Phys. Status Solidi A 84, 423 (1984).Google Scholar
16Chung, S-K., Thiessen, D.B., and Rhim, W-K.: A noncontact measurement technique for the density and thermal expansion coefficient of solid and liquid materials. Rev. Sci. Instrum. 67, 3175 (1996).Google Scholar
17Rhim, W-K., Ohsaka, K., and Paradis, P-F.: Noncontact technique for measuring surface tension and viscosity of molten materials using high temperature electrostatic levitation. Rev. Sci. Instrum. 70, 2796 (1999).Google Scholar
18Ishiakwa, T., Paradis, P-F., Fujii, R., Saita, Y., and Yoda, S.: Thermophysical property measurements of liquid and supercooled irijium by containerless methods. Int. J. Thermophys. 26, 893 (2005).Google Scholar
19Rohr, W.G.: The liquid densities of cerium and neodymium metals. J. Less-Common Met. 10, 389 (1966).Google Scholar
20Bezuklandnikova, L.L., Kononenko, V.I., and Torokin, V.V.: Teplofiz. Vys. Temp. 27, 478 (1989).Google Scholar
21Pulliam, G.R. and Fitzsimmons, E.S.: Reactions of Cerium and Lanthanum with Ceramic Oxides (U.S., Atom. Energy Comm., Ames Lab. Rep. No. ISC-659-1955, 1955).Google Scholar
22Sukhman, A.L., Konenko, V.I., Gruverman, S.L., and Torokiv, V.V.: Surface Properties of Melts (Naukova Dumka, Kiev, 1982), pp. 107–117.Google Scholar
23Allen, B.C.: Liquid metals, in Chemistry and Physics (Dekker, New York, 1972).Google Scholar
24Keene, B.J.: Review of data for the surface tension of pure metals. Int. Mater. Rev. 38, 157 (1993).Google Scholar
25Mills, K.C. and Su, Y.C.: Review of surface tension data for metallic elements and alloys: Part 1–Pure metals. Int. Mater. Rev. 51, 329 (2006).Google Scholar
26Wittenberg, L.G. and Dewitt, R.: Prop. liquid metals, in Proc. Int. Conf., 2nd ed. (Takeuchi-Sakae Taylor and Francis, London, 1973).Google Scholar