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Development of Functional Surfaces on High-Density Polyethylene (HDPE) via Gas-Assisted Etching (GAE) Using Focused Ion Beams

Published online by Cambridge University Press:  09 December 2015

Meltem Sezen  and
Feray Bakan
Meltem Sezen
Affiliation:
Sabancı University Nanotechnology Research and Application Center (SUNUM), 34956 Orhanlı, Istanbul, Turkey
Feray Bakan*
Affiliation:
Sabancı University Nanotechnology Research and Application Center (SUNUM), 34956 Orhanlı, Istanbul, Turkey
*
*Corresponding author. feraybakan@sabanciuniv.edu
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Abstract

Irradiation damage, caused by the use of beams in electron and ion microscopes, leads to undesired physical/chemical material property changes or uncontrollable modification of structures. Particularly, soft matter such as polymers or biological materials is highly susceptible and very much prone to react on electron/ion beam irradiation. Nevertheless, it is possible to turn degradation-dependent physical/chemical changes from negative to positive use when materials are intentionally exposed to beams. Especially, controllable surface modification allows tuning of surface properties for targeted purposes and thus provides the use of ultimate materials and their systems at the micro/nanoscale for creating functional surfaces. In this work, XeF2 and I2 gases were used in the focused ion beam scanning electron microscope instrument in combination with gallium ion etching of high-density polyethylene surfaces with different beam currents and accordingly different gas exposure times resulting at the same ion dose to optimize and develop new polymer surface properties and to create functional polymer surfaces. Alterations in the surface morphologies and surface chemistry due to gas-assisted etching-based nanostructuring with various processing parameters were tracked using high-resolution SEM imaging, complementary energy-dispersive spectroscopic analyses, and atomic force microscopic investigations.

Keywords

focused ion beamgas-assisted etchingsurface modificationfunctionalized polymer surfacesnanostructuring
Type
Materials Applications and Techniques
Information
Microscopy and Microanalysis , Volume 21 , Issue 6 , December 2015 , pp. 1379 - 1386
Copyright
© Microscopy Society of America 2015 

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References

Al-Shamery, K.H., Rubahn, H.G. & Sitter, H. (2008). Organic Nanostructures for Next Generation Devices. Berlin Heidelberg: Springer.CrossRefGoogle Scholar
Brostow, W. (2000). Performance of Plastics. Munich: Hanser-Gardner Publications.Google Scholar
Brown, N. & Tipping, G. (2001). Polymers in Mass Transit Conference. Shropshire: Rapra Technology.Google Scholar
Buckley, R.W. (2003). Polymer Enhancement of Technical Textiles, vol. 14, Shropsire: Rapra Technology.Google Scholar
Cademartiri, L. & Ozin, G. (2009). Concepts of Nanochemistry. Weinheim: Wiley.Google Scholar
Campbell-Platt, G. (2009). Food Science and Technology. New Jersey: Wiley, John & Sons, Inc.Google Scholar
Chan, C.M., Koand, T.M. & Hiraoka, H. (1996). Polymer surface modification by plasmas and photons. Surf Sci Rep 24(1–2), 1–54.CrossRefGoogle Scholar
Chanda, M. & Roy, S.K. (2008). Industrial Polymers, Specialty Polymers, and Their Applications, vol. 73, Plastics Engineering. Florida: Taylor & Francis, Inc.CrossRefGoogle Scholar
Drobny, J.G. (2003). Radiation Technology for Polymers. Florida: CRC Press.Google Scholar
Egerton, R.F., Li, P. & Malac, M. (2004). Radiation damage in TEM and SEM. Micron 35, 399–409.CrossRefGoogle ScholarPubMed
FEI Company (2010). App. Note: Using beam chemistries with SEM, FIB and DualBeam™ for surface modification.Google Scholar
Frey, L., Lehrer, C. & Ryssel, H. (2003). Nanoscale effects in focused ion beam processing. Appl Phys A 3(76), 1017–1023.CrossRefGoogle Scholar
Giannuzzi, L.A. & Stevie, F.A. (2004). Introduction to Focused Ion Beams: Instrumentation, Theory, Techniques, and Practice. New York, USA: Springer.Google Scholar
Goodman, T.D. (2005). Advancements in polymer optics design, fabrication, and materials, Society of Photo-Optical Instrumentation Engineers, SPIE Proceeding Series. California, USA.Google Scholar
Grubb, D.T. (1974). Radiation damage and electron microscopy of organic polymers. J Mater Sci 9, 1715–1736.CrossRefGoogle Scholar
Huzzayin, A., Boggs, S. & Ramprasad, R. (2009). Computational quantum mechanics-based study of conduction in iodine doped polyethylene. In Annual Report Conference on Electrical Insulation and Dielectric Phenomena, CEIDP ’09, pp. 138–141.Virginia: IEEE.CrossRefGoogle Scholar
Jones, D. (2004). Pharmaceutical Applications of Polymers for Drug Delivery. UK: Rapra Technology.Google Scholar
Kharitonov, A.P. (2004). Improvement of performance characteristics of polymer materials by direct fluorination. Chem Sust Dev 12, 624–630.Google Scholar
Klauk, H. (2006). Organic Electronics: Materials, Manufacturing and Applications. Weinheim: Wiley, John & Sons, Inc.CrossRefGoogle Scholar
Knystautas, E.J. (2005). Engineering Thin Films and Nanostructures with Ion Beams. Florida, USA: CRC.Google Scholar
Köhler, J.M. & Fritzsche, W. (2004). Nanotechnology: An Introduction to Nanostructuring Techniques. Weinheim, Germany: Wiley, John & Sons, Inc.CrossRefGoogle Scholar
Mark, J.E. (2006). Physical Properties of Polymers Handbook. New York: Springer.Google Scholar
Mayer, J., Giannuzzi, L.A., Kamino, T. & Michael, J. (2007). TEM sample preparation and FIB-induced damage. MRS Bull 32, 400–407.CrossRefGoogle Scholar
Moberly, W.J., Chan, W.J., Adams, D.P., Aziz, M.J., Hobler, G. & Schenkel, T. (2007). Fundementals of focused ion beam nanostructural processing: below, at and above the surface. MRS Bull 32, 424–432.CrossRefGoogle Scholar
Moon, M.W., Lee, S.H., Sun, J.Y., Oh, K.H., Vaziri, A. & Hutchinson, J.W. (2007). Wrinkled hard skins on polymers created by focused ion beam. Proc Natl Acad Sci USA 104(4), 1130–1133.CrossRefGoogle ScholarPubMed
Morawetz, H. (1985). Polymers: The Origin and Growth of a Science. New York: John Wiley & Sons.Google Scholar
Narlikar, A.V. & Fu, Y.Y. (2010). Oxford Handbook of Nanoscience and Technology. New York: Oxford University Press.Google Scholar
Pagliaro, M. & Ciriminna, R. (2005). New fluorinated functional materials. J Mater Chem 15, 4981–4991.CrossRefGoogle Scholar
Petty, M.C. (2008). Molecular Electronics: From Principles to Practice. Chichester: Wiley, John & Sons, Inc.Google Scholar
Ratner, M.A. & Ratner, D. (2002). Nanotechnology: A Gentle Introduction to the Next Big Idea. New Jersey: Prentice Hall.Google Scholar
Svorcik, V., Proskova, K., Hnatowicz, V. & Rybka, V. (1999). Iodine penetration and doping of ion modi-fied polyethylene. Nucl Instrum Methods Phys Res B 149, 312–318.CrossRefGoogle Scholar
Thomas, D.W. (2004). Advanced Biomaterials for Medical Applications. Massachusetts, USA: Springer.CrossRefGoogle Scholar
Wool, R.P. & Sun, X.S. (2005). Bio-Based Polymers and Composites. California: Elsevier Academic Press.Google Scholar
Yao, N. & Wang, Y.L. (2005). Handbook of Microscopy for Nanotechnology. New York: Springer.CrossRefGoogle Scholar
Zhou, W. & Wang, Z.L. (2007). Scanning Microscopy for Nanotechnology: Techniques and Applications. New York: Springer.CrossRefGoogle Scholar
Zhu, Q. & Han, C.C. (2007). Synthesis and crystallization behaviors of highly fluorinated aromatic polyesters. Polymer 48, 3624–3631.CrossRefGoogle Scholar