Electron-microscopic observation of BaTiO3 prepared by additive assisted aqueous synthesis

Abstract

Bulk barium titanate (BaTiO3) has found widespread applications especially in multi-layered ceramic capacitors (MLCCs) and embedded decoupling capacitors (EDC). In the last years, the interest in one-dimensional (1D) nanostructured ferroelectric systems (nanotubes, nanowires, nanorods, nanobelts, nanofibers) is increasing. Recently theoretical studies reported an enhancement of ferroelectricity in 1D systems. Although the hydrothermal and aqueous synthesis of equiaxed barium titanate powders have been thoroughly investigated the growth of barium titanate anisotropic nanoparticles still less known. Indeed it is particularly dificult to modify the crystal habit by hydrothermal and related methods. However it is expected that the presence of some additives during the synthesis will change the growth kinetics.