Hostname: page-component-78c5997874-lj6df Total loading time: 0 Render date: 2024-11-10T15:59:05.121Z Has data issue: false hasContentIssue false

Microstructural Characterization of High Indium-Composition InXGa1−XN Epilayers Grown on c-Plane Sapphire Substrates

Published online by Cambridge University Press:  06 August 2013

Myoungho Jeong
Affiliation:
Department of Materials Science and Engineering, Korea Advanced Institute of Science and Technology, Daejeon 305-701, Republic of Korea
Hyo Sung Lee
Affiliation:
Department of Advanced Materials Engineering, Chungnam National University, Daejeon 305-764, Republic of Korea
Seok Kyu Han
Affiliation:
Department of Advanced Materials Engineering, Chungnam National University, Daejeon 305-764, Republic of Korea
Eun-Jung-Shin
Affiliation:
Graduate School of Green Energy Technology, Chungnam National University, Daejeon 305-764, Republic of Korea
Soon-Ku Hong*
Affiliation:
Department of Advanced Materials Engineering, Chungnam National University, Daejeon 305-764, Republic of Korea Graduate School of Green Energy Technology, Chungnam National University, Daejeon 305-764, Republic of Korea
Jeong Yong Lee
Affiliation:
Department of Materials Science and Engineering, Korea Advanced Institute of Science and Technology, Daejeon 305-701, Republic of Korea
Yun Chang Park
Affiliation:
Measurement & Analysis Division, National NanoFab Center (NNFC), Daejeon 305-806, Republic of Korea
Jun-Mo Yang
Affiliation:
Measurement & Analysis Division, National NanoFab Center (NNFC), Daejeon 305-806, Republic of Korea
Takafumi Yao
Affiliation:
Center for Interdisciplinary Research, Tohoku University, Sendai 980-8578, Japan
*
*Corresponding author. E-mail: soonku@cnu.ac.kr
Get access

Abstract

The growth of high-quality indium (In)-rich InXGa1−XN alloys is technologically important for applications to attain highly efficient green light-emitting diodes and solar cells. However, phase separation and composition modulation in In-rich InXGa1−XN alloys are inevitable phenomena that degrade the crystal quality of In-rich InXGa1−XN layers. Composition modulations were observed in the In-rich InXGa1−XN layers with various In compositions. The In composition modulation in the InXGa1−XN alloys formed in samples with In compositions exceeding 47%. The misfit strain between the InGaN layer and the GaN buffer retarded the composition modulation, which resulted in the formation of modulated regions 100 nm above the In0.67Ga0.33N/GaN interface. The composition modulations were formed on the specific crystallographic planes of both the {0001} and {0114} planes of InGaN.

Type
Research Article
Copyright
Copyright © Microscopy Society of America 2013 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Doppalapudi, D., Basu, S.N., Ludwig, K.F. & Moustakas, T.D. (1998). Phase separation and ordering in InGaN alloys grown by molecular beam epitaxy. J Appl Phys 84, 13891395.10.1063/1.368251Google Scholar
El-Masry, N.A., Piner, E.L., Liu, S.X. & Bedair, S.M. (1998). Phase separation in InGaN grown by metalorganic chemical vapor deposition. Appl Phys Lett 72, 4042.Google Scholar
Henoc, P., Izrael, A., Quillec, M. & Launois, H. (1982). Composition modulation in liquid phase epitaxial InxGa1−xAsyP1−y layers lattice matched to InP substrates. Appl Phys Lett 40, 963965.Google Scholar
Ho, I.-H. & Stringfellow, G.B. (1996). Solid phase immiscibility in GaInN. Appl Phys Lett 69, 27012703.Google Scholar
Jani, O., Ferguson, I., Honsberg, C. & Kurtz, S. (2007). Design and characterization of GaN/InGaN solar cells. Appl Phys Lett 91, 132117.Google Scholar
Jun, S.W., Seong, T.-Y., Lee, J.H. & Lee, B. (1996). Naturally formed InxAl1−xAs/InyAl1−yAs vertical superlattices. Appl Phys Lett 68, 34433445.Google Scholar
Lee, J.W., Kim, J.-H., Han, S.K., Hong, S.-K., Lee, J.Y., Hong, S.I. & Yao, T. (2010). Interface and defect structures in ZnO films on m-plane sapphire substrates. J Crystal Growth 312, 238244.Google Scholar
Moram, M.A. & Vickers, M.E. (2009). X-ray diffraction of III-nitrides. Rep Prog Phys 72, 036502.Google Scholar
Moustakas, T.D. & Molnar, R.J. (1993). Growth of GaN by ECR-assisted MBE. Physica B 185, 3649.Google Scholar
Singh, R., Doppalapudi, D., Moustakas, T.D. & Romano, L.T. (1997). Phase separation in InGaN thick films and formation of InGaN/GaN double heterostructures in the entire alloy composition. Appl Phys Lett 70, 10891091.Google Scholar
Ueda, O., Isozumi, S. & Komiya, S. (1984). Composition-modulated structures in InGaAsP and InGaP liquid phase epitaxial layers grown on (001) GaAs substrates. Jpn J Appl Phys 23, L241L243.Google Scholar
Wu, J., Walukiewicz, W., Yu, K.M., Ager, J.W. III, Haller, E.E., Lu, H., Schaff, W.J., Saito, Y. & Nanishi, Y. (2002). Unusual properties of the fundamental band gap of InN. Appl Phys Lett 80, 39673969.Google Scholar
Yodo, T., Yona, H., Ando, H., Nosei, D. & Harada, Y. (2002). Strong band edge luminescence from InN films grown on Si substrates by electron cyclotron resonance-assisted molecular beam epitaxy. Appl Phys Lett 80, 968970.Google Scholar
Zhu, X.L., Guo, L.W., Ge, B.H., Peng, M.Z., Yu, N.S., Yan, J.F., Zhang, J., Jia, H.Q., Chen, H. & Zhou, J.M. (2007). Observation of metallic indium clusters in thick InGaN layer grown by metal organic vapor deposition. Appl Phys Lett 91, 172110.Google Scholar