Hostname: page-component-78c5997874-j824f Total loading time: 0 Render date: 2024-11-14T06:28:09.506Z Has data issue: false hasContentIssue false
  • English
  • Français

The importance of cation–cation repulsion in the zircon–reidite phase transition and radiation-damaged zircon

Published online by Cambridge University Press:  22 May 2019

Makoto Tokuda Open the ORCID record for Makoto Tokuda [Opens in a new window] ,
Akira Yoshiasa ,
Hiroshi Kojitani ,
Saki Hashimoto ,
Seiichiro Uehara ,
Tsutomu Mashimo ,
Tsubasa Tobase  and
Masaki Akaogi
Makoto Tokuda*
Affiliation:
Institute of Pulsed Power Science, Kumamoto University, Kurokami 2-39-1, Kumamoto, 860-8555, Japan Graduate School of Science and Technology, Kumamoto University, Kurokami 2-39-1, Kumamoto, 860-8555, Japan
Akira Yoshiasa
Affiliation:
Institute of Pulsed Power Science, Kumamoto University, Kurokami 2-39-1, Kumamoto, 860-8555, Japan Graduate School of Science and Technology, Kumamoto University, Kurokami 2-39-1, Kumamoto, 860-8555, Japan
Hiroshi Kojitani
Affiliation:
Department of Chemistry, Gakushuin University, Mejiro, Toshima-ku, Tokyo, 171-8588, Japan
Saki Hashimoto
Affiliation:
Department of Chemistry, Gakushuin University, Mejiro, Toshima-ku, Tokyo, 171-8588, Japan
Seiichiro Uehara
Affiliation:
Department of Earth and Planetary Sciences, Faculty of Science, Kyushu University, Hakozaki, Fukuoka, 812, Japan
Tsutomu Mashimo
Affiliation:
Institute of Pulsed Power Science, Kumamoto University, Kurokami 2-39-1, Kumamoto, 860-8555, Japan
Tsubasa Tobase
Affiliation:
Graduate School of Science and Technology, Kumamoto University, Kurokami 2-39-1, Kumamoto, 860-8555, Japan
Masaki Akaogi
Affiliation:
Department of Chemistry, Gakushuin University, Mejiro, Toshima-ku, Tokyo, 171-8588, Japan
*
*Author for correspondence: Makoto Tokuda, Email: tokuda@imr.tohoku.ac.jp
Get access Rights & Permissions [Opens in a new window]

Abstract

Single crystals of synthetic reidite and natural radiation-damaged zircon from Okueyama, Japan were investigated using X-ray diffraction. The pressure-induced zircon–reidite transition is described by the twisting and translations of SiO4 tetrahedra with disappearance of the SiO4–ZrO8 shared edges. The lattice of radiation-damaged zircons expands mainly from α-decays of radioactive elements such as U and Th. Although old radiation-damaged zircons show anomolous lattice distortion, young radiation-damaged zircons do not show such distortions. These distortions are caused by thermal recovery that suppresses the Si4+–Zr4+ repulsion between the SiO4 tetrahedron and ZrO8 dodecahedron. These changes in structure can be understood by considering the cation–cation repulsion between the SiO4–ZrO8 shared edges.

Keywords

reiditezirconphase transitionradiation damagecation-cation repulsion
Type
Article
Information
Mineralogical Magazine , Volume 83 , Issue 4 , August 2019 , pp. 561 - 567
Copyright
Copyright © Mineralogical Society of Great Britain and Ireland 2019 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Footnotes

Associate Editor: Michael Rumsey

References

Akaogi, M., Hashimoto, S. and Kojitani, H. (2018) Thermodynamic properties of ZrSiO4 zircon and reidite and of cotunnite-type ZrO2 with application to high-pressure high-temperature phase relations in ZrSiO4. Physics of the Earth and Planetary Interior, 281, 1–7.Google Scholar
Brøgger, W.C. (1893) Amorf. Pp. 742–743 in: Salmonsens Illustre de Konverssationslexikon, 1. Copenhagen.Google Scholar
Errandonea, D. and Manjón, F.J. (2008). Pressure effects on the structural and electronic properties of ABX4 scintillating crystals. Progress in Materials Science, 53, 711–773.Google Scholar
Fukunaga, O. and Yamaoka, S. (1979) Phase transformation in ABO4 type compounds under high pressure. Physical Chemistry of Minerals, 5, 167–177.Google Scholar
Glass, B.P. and Liu, S. (2001) Discovery of high-pressure ZrSiO4 polymorph in naturally occurring shock-metamorphosed zircons. Geology, 29, 371–373.Google Scholar
Hamberg, A. (1914) Die radioaktiven Substanzen und die geologische Forschung. Geologiska Föreningens Stockholm Förhandlingar, 36, 31–96.Google Scholar
Hazen, R.M., and Finger, L.W. (1979) Crystal structure and compressibility of zircon at high pressure. American Mineralogist, 64, 196–201.Google Scholar
Kolesov, B.A., Geiger, C.A. and Armbruster, T. (2001) The dynamic properties of zircon studied by single-crystal X-ray diffraction and Raman spectroscopy. European Journal of Mineralogy, 13, 939–948.Google Scholar
Kusaba, K., Syono, Y., Kikuchi, M. and Fukuoka, K. (1985) Shock behavior of zircon: phase transition to scheelite structure and decomposition. Earth and Planetary Science Letters, 72, 433–439.Google Scholar
Kusaba, K., Yagi, T., Kikuchi, M. and Syono, Y. (1986) Structural considerations on the mechanism of the shock-induced zircon-scheelite transition in ZrSiO4. Journal of Physics and Chemistry of Solids, 47, 675–679.Google Scholar
Liu, L.G. (1979) High-pressure phase transformations in baddeleyite and zircon, with geophysical implications. Earth and Planetary Science Letters, 44, 390–396.Google Scholar
Mashimo, T., Nagayama, K., and Sawaoka, A. (1983) Shock compression of zirconia ZrO2 and zircon ZrSiO4 in the pressure range up to 150 GPa. Physics and Chemistry of Minerals, 9, 237–247.Google Scholar
Momma, K. and Izumi, F. (2008) VESTA: a three-dimensional visualization system for electronic and structural analysis. Journal of Applied Crystallography, 41, 653–658.Google Scholar
Murakami, T., Chakoumakos, B.C., Ewing, R.C., Lumpkin, G.R. and Weber, W.J. (1991) Alpha-decay event damage in zircon. American Mineralogist, 76, 1510–1532.Google Scholar
Nakatsuka, A., Yoshiasa, A. and Takeno, S. (1995) Site preference of cations and structural variation in Y3Fe5–xGaxO12 (0 ≤ x ≤ 5) solid solutions with garnet structure. Acta Crystallographica, B51, 737–745.Google Scholar
Nakatsuka, A., Yoshiasa, A. and Yamanaka, T. (1999) Cation distribution and crystal chemistry of Y3Al5–xGaxO12 (0 < x < 5) garnet solid solutions. Acta Crystallographica, B55, 266–272.Google Scholar
Ono, S., Funakoshi, K., Nakajima, Y., Tange, Y. and Katsura, T. (2004) Phase transition of zircon at high P-T conditions. Contributions to Mineralogy and Petrology, 147, 505–509.Google Scholar
Pauling, L. (1929) Pauling rules for ionic structures. Journal of the American Chemical Society, 51, 1010–1026.Google Scholar
Pauling, L. (1960) The Nature of the Chemical Bond, 3rd edition, p. 93. Cornell University Press, Ithaca, USA.Google Scholar
Reid, A.F. and Ringwood, A.E. (1969) Newly observed high pressure transformations in Mn2O3, GaAl2O4, and ZrSiO4. Earth and Planetary Science Letters, 6, 205–208.Google Scholar
Ríos, S., Malcherek, T., Salje, E.K.H. and Domeneghetti, C. (2000) Localized defects in radiation-damaged zircon. Acta Crystallographica, B56, 947–952.Google Scholar
Robinson, K., Gibbs, G.V. and Ribbe, P.H. (1971) The Structure of zircon: A comparison with garnet. American Mineralogist, 56, 782–790.Google Scholar
Sheldrick, G.M. (2015) SHELXT – Integrated space-group and crystal-structure determination. Acta Crystallographica, A71, 3–8.Google Scholar
Shibata, K. (1978) Contemporaneity of Tertiary granites in the outer zone of Southwest Japan. Chishitsu Chosajo Geppo, 29, 551–554.Google Scholar
Stubican, V.S. and Roy, R. (1959) High-pressure scheelite-structure polymorphs of rare-earth vanadates and arsenates. Zeitschrift für Kristallographie, 101, 451–456.Google Scholar
Takahashi, M. (1986) Anatomy of a middle Miocene Valles-type caldera cluster: geology of the Okueyama volcano-plutonic complex, southwest Japan. Journal of Volcanology and Geothermal Research, 29, 33–70.Google Scholar
Tange, Y. and Takahashi, E. (2004) Stability of the high-pressure polymorphs of zircon (ZrSiO4) in the deep mantle. Physics of the Earth Planetary Interiors, 143, 233–229.Google Scholar
Tokuda, M., Yoshiasa, A., Mashimo, T. and Iishi, K. and Nakatsuka, A. (2018) The vanadate garnet Ca2NaCd2V3O12: a single-crystal X-ray diffraction study. Acta Crystallographica, C74, 460–464.Google Scholar
Weber, W.J, Ewing, R.C., Catlow, C.R.A., Díaz de la Rubia, T., Hobbs, L.W., Kinoshita, C., Matzke, H., Motta, A.T., Nastasi, M., Salje, E.K.H., Vance, E.R. and Zinkle, S.J. (1998) Radiation effects in crystalline ceramics for the immobilization of high-level nuclear waste and plutonium. Journal of Materials Research, 13, 1434–1484.Google Scholar
Supplementary material: File

Tokuda et al. supplementary material

Tokuda et al. supplementary material 1

Download Tokuda et al. supplementary material(File)
File 57.4 KB