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Lead-antimony sulfosalts from Tuscany (Italy). XVII. Meerschautite, (Ag,Cu)5.5Pb42.4(Sb,As)45.1S112O0.8, a new expanded derivative of owyheeite from the Pollone mine, Valdicastello Carducci: occurrence and crystal structure

Published online by Cambridge University Press:  02 January 2018

Cristian Biagioni ,
Yves Moëlo ,
Paolo Orlandi  and
Chris J. Stanley
Cristian Biagioni*
Affiliation:
Dipartimento di Scienze della Terra, Università di Pisa, Via S. Maria 53, I-56126 Pisa, Italy
Yves Moëlo
Affiliation:
Institut des Matériaux Jean Rouxel, UMR6502, CNRS, Université de Nantes, 2, rue de la Houssinière, 44 322 Nantes Cedex 3, France
Paolo Orlandi
Affiliation:
Dipartimento di Scienze della Terra, Università di Pisa, Via S. Maria 53, I-56126 Pisa, Italy
Chris J. Stanley
Affiliation:
Department of Earth Sciences, The Natural History Museum, Cromwell Road, London SW7 5BD, UK
*
*E-mail: biagioni@dst.unipi.it
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Abstract

The new mineral species meerschautite, ideally (Ag,Cu)5.5Pb42.4(Sb,As)45.1S112O0.8, has been discovered in the baryte + pyrite ± (Pb-Zn-Ag) deposit of the Pollone mine, near Valdicastello Carducci, Apuan Alps, Tuscany, Italy. It occurs as black prismatic crystals, striated along [100], up to 2 mm long and 0.5 mm thick, associated with baryte, boulangerite, pyrite, quartz and sphalerite. Meerschautite is opaque with a metallic lustre and shows a black streak. In reflected light, meerschautite is white in colour, weakly bireflectant and non pleochroic. With crossed polars, it is distinctly anisotropic with grey to dark grey rotation tints with brownish and greenish shades. Reflectance percentages for COM wavelengths [λ (nm), Rair (%)] are: 470: 39.7/41.4; 546: 38.3/39.9; 589: 37.4/39.0; 650: 35.8/37.2. Electron-microprobe data collected on two different samples gave (wt.%): Cu 0.22, Ag 3.15, Tl 0.07, Pb 48.54, Sb 25.41, As 2.82, S 19.74, Se 0.14, Cl 0.03, sum 100.12 (# 1) and Cu 0.22, Ag 3.04, Tl 0.13, Pb 48.53, Sb 25.40, As 2.93, Bi 0.06, S 19.82, Se 0.13, Cl 0.05, sum 100.31 (# 2). On the basis of 112 anions (S+Se+Cl) per formula unit, the empirical formulae are (Ag5.29Cu0.63)∑5.92(Pb42.43Tl0.06)∑42.49(Sb37.80As6.82)∑44.62(S111.53Se0.32Cl0.15)∑112 (# 1) and (Ag5.08Cu0.62)∑5.70(Pb42.22Tl0.12)∑42.34(Sb37.61As7.07Bi0.05)∑44.73(S111.45Se0.30Cl0.25)∑112 (# 2). Main diffraction lines, corresponding to multiple hkl indices, are [d in Å (relative visual intensity)]: 3.762 (m), 3.663 (s), 3.334 (vs), 3.244 (s), 3.016 (m), 2.968 (m), 2.902 (m), 2.072 (ms). The crystal structure study gave a monoclinic unit cell, space group P21, with a = 8.2393(1), b = 43.6015(13), c = 28.3688(8) Å, β = 94.128(2)°, V = 10164.93(2) Å3, Z = 2. The crystal structure has been solved and refined to a final R1 = 0.122 on the basis of 49,037 observed reflections. The structure is based on two building blocks, both formed by a complex column with a pseudotrigonal Pb6S12 core and two arms of unequal lengths (short and long arms, respectively). Two different kinds of short arms occur in meerschautite. One is an Ag-rich arm, whereas the other shows localized Sb–O–Sb bonds. Meerschautite is an expanded derivative of owyheeite and has quasi-homeotypic relationships with sterryite and parasterryite.

Keywords

meerschautitenew mineral speciessulfosaltleadsilverantimonyarsenicoxygencrystal structurePollone mineApuan ALPSTuscanyItaly
Type
Research Article
Information
Mineralogical Magazine , Volume 80 , Issue 4 , June 2016 , pp. 675 - 690
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2016

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