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Speciation of adsorbed arsenic(V) on red mud using a sequential extraction procedure

Published online by Cambridge University Press:  05 July 2018

D. A. Rubinos ,
M. Arias ,
F. Díaz-Fierros  and
M. T. Barral
D. A. Rubinos*
Affiliation:
Departamento de Edafoloxía e Química Agrícola, Facultade de Farmacia, Universidade de Santiago de Compostela, 15782 Santiago de Compostela, Spain
M. Arias
Affiliation:
Área de Edafoloxía e Química Agrícola, Facultade de Ciencias de Ourense, Universidade de Vigo, 32004 Ourense, Spain
F. Díaz-Fierros
Affiliation:
Departamento de Edafoloxía e Química Agrícola, Facultade de Farmacia, Universidade de Santiago de Compostela, 15782 Santiago de Compostela, Spain
M. T. Barral
Affiliation:
Departamento de Edafoloxía e Química Agrícola, Facultade de Farmacia, Universidade de Santiago de Compostela, 15782 Santiago de Compostela, Spain
*
*E-mail: edrubi@usc.es
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Abstract

The distribution of sorbed arsenic(V) among different geochemical fractions for arsenic(V)-loaded red mud, an oxide-rich residue from bauxite refining that has been proposed as an adsorbent for arsenic, was studied as a function of sorbed arsenic(V) concentration using a sequential extraction procedure. The release of previously sorbed arsenic(V) was also studied as a function of pH and arsenic(V) concentration. Most sorbed arsenic(V) (0.39–7.86 mmol kg–1) was associated with amorphous and crystalline Al and Fe oxides (24.1–43.8% and 24.7–59.0% of total sorbed arsenic, respectively). Exchangeable arsenic was the smallest fraction (0.4–5.2% of total sorbed arsenic). The distribution of sorbed arsenic(V) was related to the arsenic surface coverage. For arsenic surface coverages >∼30% the percentage of arsenic(V) associated with the amorphous Al oxide fraction increased and that associated with the crystalline oxide fraction decreased. The arsenic(V) exchangeable fraction increased from 1.4 to 756 μmol kg–1 as surface coverage increased from 388 to 7855 μmol kg–1. The release of sorbed arsenic(V) from red mud was greater at alkaline pH values (maximum release of ∼33% of previously sorbed arsenic at pH = 12), but for high arsenic(V) initial concentration (0.2 mM arsenic) considerable amounts of arsenic (6.5% of previously sorbed arsenic) were released at pH 4, in accordance with the dissolution of amorphous Al oxides in the red mud. The results obtained suggest a greater mobility of sorbed arsenic(V) as its surface concentration approaches saturation.

Keywords

red mudarsenicsorptionspeciationsequential extraction
Type
Research Article
Information
Mineralogical Magazine , Volume 69 , Issue 5 , October 2005 , pp. 591 - 600
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2005

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References

Altundoğan, H.S., Altundogan, S., Tumen, F. and Bildik, M. (2000) Arsenic removal from aqueous solutions by adsorption on red mud. Waste Management, 20, 761–767.CrossRefGoogle Scholar
Anawar, H.M., Akai, J. and Sakugawa, H. (2004) Mobilization of arsenic from subsurface sediments by effect of bicarbonate ions in groundwater. Chemosphere, 54, 753–762.CrossRefGoogle ScholarPubMed
Anderson, M.A., Ferguson, J.F. and Gavis, J. (1976) Arsenate adsorption on amorphous aluminum hydroxide. Journal of Colloid and Interface Science, 54, 391–399.CrossRefGoogle Scholar
Apak, R., Tütem, E., Mehmet, H. and Hizal, J. (1998) Heavy metal cation retention by unconventional sorbents (red muds and fly ashes). Water Research, 32, 430–440.CrossRefGoogle Scholar
Arias, M., López, E., Núñez, A., Rubinos, D., Soto, B., Barral, M.T. and Díaz-Fierros, F. (1999) Adsorption of methylene blue by red mud, an oxide-rich byproduct of bauxite refining. Pp. 361–365 in: Effect of Mineral-Organic-Microorganism Interactions on Soil and Freshwater Environments (Berthelin, J. et al., editors). Kluwer Academic/ Plenum Publishers, New York.CrossRefGoogle Scholar
Cappuyns, V., Van Herreweghe, S., Swennen, R., Ottenburgh, R. and Deckers, J. (2002) Arsenic pollution at the industrial site of Reppel-Bocholt (north Belgium). Science of the Total Environment, 295, 217–240.CrossRefGoogle Scholar
Daus, B., Wennrich, R. and Weiss, H. (2004) Sorption materials for arsenic removal from water: a comparative study. Water Research, 38, 2948–2954.CrossRefGoogle ScholarPubMed
Driehaus, W., Jekel, M. and Hildebrandt, J. (1998) Granular ferric hydroxide — a new adsorbent for the removal of arsenic from natural water. Journal of Water SRT - Aqua, 47, 30–35.Google Scholar
Fordham, A.W. and Norris, K. (1979) Arsenate-73 uptake by components of several acidic soils and its implications for phosphate retention. Australian Journal of Soil Research, 17, 307–316.CrossRefGoogle Scholar
Frost, R.R. and Griffin, A. (1977) Effect of pH on adsorption of arsenic and selenium from landfill leachate by clay minerals. Soil Science Society of America Journal, 41, 53—56.CrossRefGoogle Scholar
García-Sánchez, A., Álvarez-Ayuso, E. and Rodríguez-Martin, F. (2002) Sorption of As(V) by some oxyhydroxides and clay minerals. Application to its immobilization in two polluted mining soils. Clay Minerals, 37, 187–194.CrossRefGoogle Scholar
Genç, H., Tjell, J.C., McConchie, D. and Schuiling, O. (2003) Adsorption of arsenate from water using neutralized red mud. Journal of Colloid and Interface Science, 264, 327–334.CrossRefGoogle ScholarPubMed
Genç-Fuhrman, H., Tjell, J.C. and McConchie, D. (2004a) Adsorption of arsenic from water using activated neutralized red mud. Environmental Science and Technology, 38, 2428–2434.CrossRefGoogle ScholarPubMed
Genç-Fuhrman, H., Tjell, J.C. and McConchie, D. (2004b) Increasing the arsenate adsorption capacity of neutralized red mud (Bauxsol). Journal of Colloid and Interface Science, 271, 313–320.CrossRefGoogle Scholar
Glenister, D.J. (1987) Alcoa's experiences with alternative techniques for bauxite residue disposal and the rehabilitation of old residue areas. Pp. 50–70 in: Tailings Disposal and Management Symposium (Stockon, N. editor). Murdoch University, Western Australia.Google Scholar
Glenister, D.J. and Thornber, M.R. (1985) Alkalinity of red mud and its application for the management of acid wastes. Pp. 109–113 in: Chemeca 85 Symposium Proceedings, Paper A8c.Google Scholar
Goldberg, S. and Johnston, C.T. (2001) Mechanisms of arsenic adsorption on amorphous oxides evaluated using macroscopic measurements, vibrational spectroscopy, and surface complexation modeling. Journal of Colloid and Interface Science, 234, 204–216.CrossRefGoogle ScholarPubMed
Gupta, S.K. and Chen, K.Y. (1978) Arsenic removal by adsorption. Journal of Water Pollution Control Federation, 50, 493–506.Google Scholar
Gupta, V.K. and Sharma, S. (2002) Removal of cadmium and zinc from aqueous solution using red mud. Environmental Science and Technology, 36, 3612–3617.CrossRefGoogle ScholarPubMed
International Agency for Research on Cancer (1980) IARC Monographs on the Evaluation of Carcinogenic Risks to Humans, Vol. 23, IARC, Lyon, France.Google Scholar
Jackson, B.P. and Miller, W.P. (2000) Effectiveness of phosphate and hydroxide for desorption of arsenic and selenium species from iron oxides. Soil Science Society of America Journal, 64, 1616—1622.CrossRefGoogle Scholar
Lin, T.F. and Wu, J.K. (2001) Adsorption of arsenite and arsenate within activated alumina grains: Equilibrium and kinetics. Water Research, 35, 2049–2057.CrossRefGoogle ScholarPubMed
Livesey, N.T. and Huang, P.M. (1981) Adsorption of arsenate by soils and its relation to selected chemical properties and anions. Soil Science, 131, 88—94.CrossRefGoogle Scholar
Lombi, E., Wenzel, W.W. and Sletten, R.S. (1999) Arsenic adsorption by soils and iron-oxide-coated sand: kinetics and reversibility. Journal of Plant Nutrition and Soil Science, 162, 451–456.3.0.CO;2-B>CrossRefGoogle Scholar
Lombi, E., Sletten, R.S. and Wenzel, W.W. (2000) Sequentially extracted arsenic from different size fractions of contaminated soils. Water, Air and Soil Pollution, 124, 319–332.CrossRefGoogle Scholar
Lombi, E., Zhao, F.J., Zhang, G., Sun, B., Fitz, W., Zhang, H. and McGrath, S.P. (2002) In situ fixation of metals in soils using bauxite residue: chemical assessment. Environmental Pollution, 118, 435–443.CrossRefGoogle ScholarPubMed
López, E., Soto, B., Arias, M., Núñez, A., Rubinos, D. and Barral, M.T. (1998) Adsorbent properties of red mud and its use for wastewater treatment. Water Research, 32, 1314–1322.CrossRefGoogle Scholar
Mehra, O.P. and Jackson, M.L. (1960) Iron oxide removal from soils and clays by a dithionite-citrate system buffered with sodium bicarbonate. Clays and Clay Minerals, 7, 317–327.CrossRefGoogle Scholar
Nickson, R., McArthur, J., Burgess, W., Ahmed, K.M., Ravenscroft, P. and Rahman, M. (1998) Arsenic poisoning of Bangladesh groundwater. Nature, 395, 338.CrossRefGoogle ScholarPubMed
Nirel, P.M.V. and Morel, F.M.M. (1990) Pitfalls of sequential extractions. Water Resources, 24, 1055–1056.Google Scholar
Pierce, M.L. and Moore, C.B. (1980) Adsorption of arsenite and arsenate on amorphous iron hydroxide from dilute aqueous solutions. Environmental Science and Technology, 14, 214–216.CrossRefGoogle Scholar
Prasad, G. (1994) Removal of arsenic(V) from aqueous systems by adsorption onto some geological materials. Pp. 133–152 in: Arsenic in The Environment. Part I: Cycling and Characterization (Nriagu, J.O., editor). John Wiley & Sons, Inc., New York, USA.Google Scholar
Rubinos, D., Soto, B., Arias, M. and Barral, M.T. (1998a) Adsorción de As(V) por lodos rojos de bauxita (As(V) adsorption by bauxite red mud). V Congreso Intemacional de Quίmica de la ANQUE. Tenerife, Spain. Abstract.Google Scholar
Rubinos, D., Vilaboy, K. and Barral, M.T. (1998b) Quantitative determination of zeolites in red mud by a cation-exchange capacity method. In: Analytical methodology in the environmental field (Prada, D. et al., editors). Diputacion de La Coruña, La Coruña, Spain.Google Scholar
Rubinos, D., Arias, M., Barral, M.T. and Diaz-Fierros, F. (2002) Surface properties of red mud as influenced by arsenate adsorption. XIII Spanish-Italian Congress on the thermodynamics of metal complexes. Santiago de Compostela, Spain. Abstract.Google Scholar
Schwertmann, U. (1964) Differenzierung der Eisenoxide der Bodens durch extraktion mit ammonium oxalat-Lösung. Zeitschrift für Pflanzenernährung und Bodenkunde, 105, 194–202.CrossRefGoogle Scholar
Shevade, S. and Ford, R.F. (2004) Use of synthetic zeolites for arsenate removal from pollutant water. Water Research, 38, 3197–3204.CrossRefGoogle ScholarPubMed
Sun, X. and Doner, H.E. (1996) An investigation of arsenate and arsenite bonding structures on goethite by FTIR. Soil Science, 161, 865–872.CrossRefGoogle Scholar
Wauchope, R.D. (1975) Fixation of arsenical herbicides, phosphate and arsenate in alluvial soils. Journal of Environmental Quality, 4, 355–358.CrossRefGoogle Scholar
World Health Organization, WHO (1993) WHO Guidelines for drinking water quality, 2nd edition. Geneva, Switzerland.Google Scholar
World Health Organization, WHO (2001) Arsenic and arsenic compounds. Environmental Health Criteria, 2nd edition. Geneva, Switzerland.Google Scholar