Hostname: page-component-cd9895bd7-p9bg8 Total loading time: 0 Render date: 2024-12-28T20:15:31.424Z Has data issue: false hasContentIssue false
  • English
  • Français

Porosity distribution in a heterogeneous clay-rich fault core by image processing of 14C-PMMA autoradiographs and Scanning Electron Microscopy

Published online by Cambridge University Press:  17 December 2017

Ville Nenonen ,
Juuso Sammaljärvi ,
Bo Johanson ,
Mikko Voutilainen ,
Emilie L’Hôpital ,
Pierre Dick  and
Marja Siitari-Kauppi
Ville Nenonen*
Affiliation:
Laboratory of Radiochemistry, University of Helsinki, Helsinki, Finland
Juuso Sammaljärvi
Affiliation:
Laboratory of Radiochemistry, University of Helsinki, Helsinki, Finland
Bo Johanson
Affiliation:
Geological Survey of Finland (GTK), Espoo, Finland
Mikko Voutilainen
Affiliation:
Laboratory of Radiochemistry, University of Helsinki, Helsinki, Finland
Emilie L’Hôpital
Affiliation:
Institut de Radioprotection et de Sûreté Nucléaire (IRSN), Fontenay-aux-Roses, France
Pierre Dick
Affiliation:
Institut de Radioprotection et de Sûreté Nucléaire (IRSN), Fontenay-aux-Roses, France
Marja Siitari-Kauppi
Affiliation:
Laboratory of Radiochemistry, University of Helsinki, Helsinki, Finland
*
*(Email: ville.nenonen@helsinki.fi)
Get access

Abstract

Shale formations are considered by a number of countries as the most suitable media to dispose of high-level radioactive waste. This is mainly due to the impermeable, self-sealing, chemical reducing, and sorption properties that tend to retard radionuclide migration. However, shale formations can also contain highly connected fault zones with permeabilities that can differ of several orders of magnitudes with respect to the undeformed host rock. The objective of this work is to use the 14C-PMMA autoradiography method combined with SEM-EDS measurements to understand the porosity variations in and around fault gouges and to define their relationship to mechano-chemical processes. The studied samples were taken from a low permeability shale in a small-scale vertical strike-slip fault at the Tournemire underground research laboratory. Results display significant variations in porosity and mineralogy along the studied gouge zone due to polyphased tectonics and paleo-fluid circulations.

Keywords

porositygeologicscanning electron microscopy (SEM)waste management
Type
Articles
Information
MRS Advances , Volume 3 , Issue 21: Scientific Basis for Nuclear Waste Management XLI , 2018 , pp. 1167 - 1173
Check for updates
Copyright
Copyright © Materials Research Society 2017 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Wibberley, C.A.J., Yeilding, G., and Di Toro, G., Special Publications, 299, Geological Society, London (2008).Google Scholar
Faulkner, D.R., Jackson, C.A.L., Lunn, R.J., Schlische, R.W., Shipton, Z.K., Wibberley, C.A.J. and Withjack, M.O. Journal of Structural Geology, 32, 1557–1575 (2010).Google Scholar
Constanin, J., Peyaud, J.P, Vergely, P., Pagel, M. and Cabrera, J., Physics and Chemistry of the Earth, 29, 25–41 (2004).CrossRefGoogle Scholar
Lefevre, M., Guglielmi, Y., Henry, P., Dick, P. and Gout, C. Journal of Structural Geology, 83, 73–84 (2016).Google Scholar
Dick, P., Wittebroodt, C., Courbet, C., Sammaljärvi, J., Esteve, I., Matray, J.M., Siitari- Kauppi, M., Voutilainen, M. and Dauzeres, A. The Clay Minerals Society Workshop Lectures Series, 21, 219–229 (2016).Google Scholar
Hellmuth, K-H., Lukkarinen, S. and Siitari-Kauppi, M. Isotopenpraxis. Isotopes in Environmental and Health Studies 30, 47–60 (1994).Google Scholar
Siitari-Kauppi, M. Academic Dissertation, Report Series in Radiochemistry, 17, University of Helsinki (2002).Google Scholar
Sammaljärvi, J., Shoff Rama, M., Ikonen, J., Muuri, E., Hellmuth, K.H. and Siitari-Kauppi, M. Engineering Geology, 210, 70–83 (2016).CrossRefGoogle Scholar
Voutilainen, M., Siitari-Kauppi, M., Sardini, P., Lindberg, A. and Timonen, J. Journal of Geophysical Research, 117, B01201 (2012).Google Scholar