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Identification of Defect Levels in Copper Indium Diselenide (CuInSe2) Thin Films via Photoluminescence Studies

Published online by Cambridge University Press:  06 August 2018

Niraj Shrestha ,
Dhurba R. Sapkota ,
Kamala K. Subedi ,
Puja Pradhan ,
Prakash Koirala ,
Adam B. Phillips ,
Robert W. Collins ,
Michael J. Heben  and
Randy J. Ellingson
Niraj Shrestha*
Affiliation:
Department of Physics and Astronomy, Wright Center for Photovoltaics Innovation and Commercialization, University of Toledo, Toledo, OH, USA43606
Dhurba R. Sapkota
Affiliation:
Department of Physics and Astronomy, Wright Center for Photovoltaics Innovation and Commercialization, University of Toledo, Toledo, OH, USA43606
Kamala K. Subedi
Affiliation:
Department of Physics and Astronomy, Wright Center for Photovoltaics Innovation and Commercialization, University of Toledo, Toledo, OH, USA43606
Puja Pradhan
Affiliation:
Department of Physics and Astronomy, Wright Center for Photovoltaics Innovation and Commercialization, University of Toledo, Toledo, OH, USA43606
Prakash Koirala
Affiliation:
Department of Physics and Astronomy, Wright Center for Photovoltaics Innovation and Commercialization, University of Toledo, Toledo, OH, USA43606
Adam B. Phillips
Affiliation:
Department of Physics and Astronomy, Wright Center for Photovoltaics Innovation and Commercialization, University of Toledo, Toledo, OH, USA43606
Robert W. Collins
Affiliation:
Department of Physics and Astronomy, Wright Center for Photovoltaics Innovation and Commercialization, University of Toledo, Toledo, OH, USA43606
Michael J. Heben
Affiliation:
Department of Physics and Astronomy, Wright Center for Photovoltaics Innovation and Commercialization, University of Toledo, Toledo, OH, USA43606
Randy J. Ellingson
Affiliation:
Department of Physics and Astronomy, Wright Center for Photovoltaics Innovation and Commercialization, University of Toledo, Toledo, OH, USA43606
*
*(Email: Niraj.Shrestha@rockets.utoledo.edu)
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Abstract

Photoluminescence (PL) spectroscopy has been used to study the defect levels in thin film copper indium diselenide (CuInSe2, CIS) which we are developing as the absorber layer for the bottom cell of a monolithically grown perovskite/CuInSe2 tandem solar cell. Temperature and laser power dependent PL measurements of thin film CIS for two different Cu/In ratios (0.66 and 0.80) have been performed. The CIS film with Cu/In = 0.80 shows a prominent donor-to-acceptor peak (DAP) involving a shallow acceptor of binding energy ∼22 meV, with phonon replica at ∼32 meV spacing. In contrast, PL measurement of CIS film for Cu/In = 0.66 taken at 20 K exhibited an asymmetric and broad PL spectrum with peaks at 0.845 eV and 0.787 eV. Laser intensity dependent PL revealed that the observed peaks 0.845 eV and 0.787 eV shift towards higher energy (aka j-shift) at ∼11.7 meV/decade and ∼ 8 meV/decade with increase in laser intensity respectively. The asymmetric and broad spectrum together with large j-shift suggests that the observed peaks at 0.845 eV and 0.787 eV were related to band-to-tail (BT) and band-to-impurity (BI) transition, respectively. Such a band-tail-related transition originates from the potential fluctuation of defect states at low temperature. The appearance of band related transition in CIS film with Cu/In = 0.66 is the indicator of the presence of large number of charged defect states.

Keywords

defectsoptoelectronicCu
Type
Articles
Information
MRS Advances , Volume 3 , Issue 52: Energy Materials and Technologies , 2018 , pp. 3135 - 3141
Copyright
Copyright © Materials Research Society 2018 

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