Hostname: page-component-78c5997874-94fs2 Total loading time: 0 Render date: 2024-11-10T10:19:35.472Z Has data issue: false hasContentIssue false
  • English
  • Français

Controlled synthesis of anganese (oxihydr)oxides in queous olution by hermolysis

Published online by Cambridge University Press:  03 September 2012

S. Cassaignon ,
M. Koelsch  and
J-P. Jolivet
S. Cassaignon
Affiliation:
Laboratoire de Chimie de la matière condensée, CNRS UMR7574 Université Pierre et Marie Curie - Tour 54 - 4, place jussieu - 75252 Paris Cedex 05
M. Koelsch
Affiliation:
Laboratoire de Chimie de la matière condensée, CNRS UMR7574 Université Pierre et Marie Curie - Tour 54 - 4, place jussieu - 75252 Paris Cedex 05
J-P. Jolivet
Affiliation:
Laboratoire de Chimie de la matière condensée, CNRS UMR7574 Université Pierre et Marie Curie - Tour 54 - 4, place jussieu - 75252 Paris Cedex 05
Get access

Abstract

Nanometric particles of manganese (oxihydr)oxides (Hausmannite, Manganite, Nsutite, Pyrolusite and Vernadite) have been synthesized by thermohydrolysis of MnCl2 and/or KMnO4in aqueous medium. The modification of various chemical parameters (pH and precursors concentration, nature of the reducer or oxidizer, temperature and duration of the thermolysis) allow the control of the nature, the size and the morphology of the obtained particles.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 822: Symposium S – Nanostructured Materials in Alternative Energy Devices , 2004 , S3.8
Copyright
Copyright © Materials Research Society 2004

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1 Post, J.E., Proc. Natl. Acad. Sci. 96, 3447 (1999)Google Scholar
2 Kucza, W., Electr. Communications. 4(9), 669 (2002)Google Scholar
3 Roy, S., Maganese Mineralization : Geochemistry and Mineralogy of Terrestrial and Marine Deposits (Geological Society, 1997)Google Scholar
4 Sun, Y., Ma, C., Wang, Y., Li, H., Inorg. Chem. Comm. 5, 747 (2002)Google Scholar
5 Sugantha, M., Ramakrishnan, P.A., Hermann, A.M., Warmsingh, C.P., Ginley, D.S., Int. J. Hydr. Ener. 78(6), 597 (2003)Google Scholar
6 Wang, X., Li, Y., J. Amer. Chem. Soc. 124(12), 2880 (2001)Google Scholar
7 Narita, E., Okabe, T., Bull. Chem. Soc. Jpn. 53, 525 (1980)Google Scholar
8 Sarrazin, J., Verdaguer, M., L'oxydoréduction : concepts et expériences (Ellipses, 1991), p.134 Google Scholar
9 Ciavatta, L., Palombari, R., Belli, E., J. Inorg. Nucl. Chem. 43(10), 2485 (1981)Google Scholar
10 JCPDF References: 89-4837, 88-0649, 17-0510, 81-2261, 89-4836, 15-0604Google Scholar
11 Wang, X., Li, Y., Chem. Comm. 7, 764 (2002)Google Scholar