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Morphology and Polymorph Selectivity Control in Calcium Carbonate Mineralization

Published online by Cambridge University Press:  01 February 2011

Swaminathan Sindhu ,
Parayil K. Ajikumar ,
Subbiah Jegadesan  and
Suresh Valiyaveettil
Swaminathan Sindhu
Affiliation:
NUS- Nanoscience and Nanotechnology Initiative, National University of Singapore, Singapore-117543
Parayil K. Ajikumar
Affiliation:
Singapore-MIT Alliance, National University of Singapore, Sinapore-117576
Subbiah Jegadesan
Affiliation:
Department of Chemistry, 3 Science Drive 3, National University of Singapore, Singapore – 117543
Suresh Valiyaveettil*
Affiliation:
NUS- Nanoscience and Nanotechnology Initiative, National University of Singapore, Singapore-117543 Singapore-MIT Alliance, National University of Singapore, Sinapore-117576 Department of Chemistry, 3 Science Drive 3, National University of Singapore, Singapore – 117543
*
* Email: chmsv@nus.edu.sg
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Abstract

The present paper describes the mineralization of calcium carbonate at a low temperature (4 °C) and in presence of additives. Aspartic acid immobilized polyacrylic acid (PA-Asp) induced the nucleation of spherical vaterite polymorph at 4 °C. But at room temperature, a thin film of calcite was deposited. Moreover, stable amorphous calcium carbonate was precipitated in presence of magnesium at low temperature. The observed results show that low temperature and presence of additives influence the nucleation, polymorph selectivity and morphology of the precipitated calcium carbonate.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 847: Symposium EE – Organic/Inorganic Hybrid Materials , 2004 , EE9.38
Copyright
Copyright © Materials Research Society 2005

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