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Published online by Cambridge University Press: 21 March 2011
This paper reports on attempts to fabricate transparent electrically conductive p-type ZnO by pulsed laser deposition (PLD) and sputtering using N2, N2O and NO gases. Expanding on the work of Kawai and coworkers [1,2], we used an ion source, rather than an ECR source in the PLD chamber to dissociate N2O gas, and explored the use of aluminum in addition to gallium as potential co-dopants. The most promising results have been obtained with DC reactive sputtering of gallium-doped zinc metal targets. A three to six order of magnitude reduction in n-type carrier density was observed when 2% of the argon sputtering gas was replaced with NO.