Hostname: page-component-cd9895bd7-7cvxr Total loading time: 0 Render date: 2024-12-29T12:21:08.902Z Has data issue: false hasContentIssue false
  • English
  • Français

Electrodeposited Cu-In-Ga-Se Thin Films for CIGS-based Solar Cells

Published online by Cambridge University Press:  31 January 2011

Raghu Bhattacharya
Raghu Bhattacharya*
Affiliation:
raghu.bhattacharya@nrel.gov, National Renewable Energy Laboratory, 1617 Cole Boulevard, Golden, Colorado, 80401, United States
Get access

Abstract

Cyclic voltammogram studies were performed on H2SeO3, CuSO4, In2(SO4)3, GaCl3, H2SeO3 + CuSO4 + In2(SO4)3 and H2SeO3 + CuSO4 + In2(SO4)3 + GaCl3 to understand the electrodeposition mechanism. The reduction potential from the cyclic voltammogram studies indicates that the first deposited layer is Cu from the Cu-In-Se and Cu-In-Ga-Se solution mixture. The subsequent deposition of the In and Ga layer is more favorable on the first-deposited Cu layer.

Keywords

electrodepositionCuGa
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 1165: Symposium M – Thin-Film Compound Semiconductor Photovoltaics–2009 , 2009 , 1165-M02-04
Copyright
Copyright © Materials Research Society 2009

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Bhattacharya, R. N., Batchelor, W., Hiltner, J. F., Sites, J. R., “Thin-Film CuIn1-xGaxSe2 photovoltaic cells from solution-based precursor layers,” Appl. Phys. Lett., 75, 1431, 1999.Google Scholar
2. Basol, B. M., “Low cost techniques for the preparation of Cu(In,Ga)(Se,S)2 absorber layers,” Thin Solid Films, 361-362, 514, 2000.Google Scholar
3. Kapur, V. K., Bansal, A., Le, P., Asensio, O. I., “Non-vacuum processing of CuIn1-xGaxSe2 solar cells on rigid and flexible substrates using nanoparticle precursor inks,” Thin Solid Films, 431-432, 53, 2003.Google Scholar
4. Lincot, D., “Electrodeposition of semiconductors,” Thin Solid Films, 487(1-2), 40, 2005.Google Scholar
5. Mitzi, D. B., Yuan, M., Liu, W., Kellock, A., Chey, S. J., Deline, V., Schrott, A. G., “A highefficiency solution-deposited thin-film photovoltaic device,” Advanced Materials, 20, 3657, 2008.Google Scholar