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Functional Organotin Alkynides as Precursors of Tin-Based Hybrid Materials

Published online by Cambridge University Press:  01 February 2011

Pascale Jaumier ,
Bernard Jousseaume ,
Hocine Riague ,
Thierry Toupance  and
Mohamed Lahcini
Pascale Jaumier
Affiliation:
Université Bordeaux I, Laboratoire de Chimie Organique et Organométallique, UMR 5802, 33405, Talence, France
Bernard Jousseaume
Affiliation:
Université Bordeaux I, Laboratoire de Chimie Organique et Organométallique, UMR 5802, 33405, Talence, France
Hocine Riague
Affiliation:
Université Bordeaux I, Laboratoire de Chimie Organique et Organométallique, UMR 5802, 33405, Talence, France
Thierry Toupance
Affiliation:
Université Bordeaux I, Laboratoire de Chimie Organique et Organométallique, UMR 5802, 33405, Talence, France
Mohamed Lahcini
Affiliation:
Université Cadi Ayyad, Département de Chimie, Marrakech, Morocco.
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Abstract

Functional trialkynylorganotins were obtained by alkynylation of the corresponding organotin trichlorides. When functional organotin trichlorides were not stable, a selective monoalkynylation of tetraalkynyltins by Grignard reagents was used. It was the first example of selective monoalkylation reactions of symmetrically tetrasubstituted tin compounds. Then, reactions of the functional trialkynylorganotins with alcohols, water and carboxylic acids afforded respectively the corresponding functional monoorganotin alkoxides and oxides, and monoorgano-oxotins carboxylates.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 628: Symposium CC – Hybrid Organic/Inorganic Materials , 2000 , CC1.2
Copyright
Copyright © Materials Research Society 2000

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