Hostname: page-component-cd9895bd7-fscjk Total loading time: 0 Render date: 2024-12-29T13:27:29.740Z Has data issue: false hasContentIssue false
  • English
  • Français

Geometrical Study on Change of Pore Volume of MCM-41 Functionalized with Aminopropyl Groups

Published online by Cambridge University Press:  01 February 2011

Kenji Murakami ,
Kiyoshi Fuda  and
Mikio Sugai
Kenji Murakami
Affiliation:
murakami@ipc.akita-u.ac.jp, Faculty of Engineering and Resource Science, Akita University, Department of Materials-process Engineering & Applied Chemistry for Environments, Tegatagakuencho 1-1, Akita, 0108502, Japan, +81-18-889-2433, +81-18-837-0404
Kiyoshi Fuda
Affiliation:
fudak@ipc.akita-u.ac.jp, Faculty of Engineering and Resource Science, Akita University, Department of Materials-process Engineering &Applied Chemistry for Environments, Tegatagakuencho 1-1, Akita, 0108502, Japan
Mikio Sugai
Affiliation:
sugai@ipc.akita-u.ac.jp, Faculty of Engineering and Resource Science, Akita University, Department of Materials-process Engineering &Applied Chemistry for Environments, Tegatagakuencho 1-1, Akita, 0108502, Japan
Get access

Abstract

Mesoporous silicas functionalized with aminopropyl groups were synthesized by co-condensation of tetraethoxysilane (TEOS) and 3-aminopropyl triethoxysilane (APTES) and characterized by nitrogen adsorption-desorption measurements. The pore volume drastically decreased from about 900 mm3/g for the unfunctionalized mesoporous silica to about 300 mm3/g for the aminopropyl-functionalized mesoporous silica (1.65 mmol-NH2/g). This result was explained in terms of the surface density of the aminopropyl groups in the pore.

Keywords

nanostructurecompositesurface chemistry
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 1056: Symposium HH – Nanophase and Nanocomposite Materials V , 2007 , 1056-HH08-41
Copyright
Copyright © Materials Research Society 2008

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Kresge, C. T, Leonowicz, M. E, roth, W. J, Vartuli, J. C, and Beck, J. S, Nature 359, 710 (1992).Google Scholar
2. Beck, J. S, Vartuli, J. C, Rogh, W. J, Leonowicz, M. E, Kresge, C. T, Schmitt, K. D, Chu, C. T-W., Olson, D. H, Sheppard, E. W, McCullen, S. B, Higgins, J. B, and Schlenker, J. L, J. Am. Chem. Soc. 114, 10834 (1992).Google Scholar
3. Yanagisawa, T., Shimizu, T., Kuroda, K., and Kato, C., Bull. Chem. Soc. Jpn. 63, 988 (1990).Google Scholar
4. Bois, L., Bonhomme, A., Ribes, a., Pais, B., Raffin, G., and Tessier, F., Colloid Surf. A 221, 221 (2003).Google Scholar
5. Cestari, A.R, Vieira, E.F.S., Vieira, G.S, and Almeida, L.E, J. Colloid Interface Sci. 309, 402 (2007).Google Scholar
6. Stein, A., Melde, B.J, and Schroden, R.C, Adv. Mater. 12, 1403 (2000).Google Scholar
7. Yokoi, T., Yoshitake, H., and Tatsumi, T., J. Mater. Chem. 14, 951 (2004).Google Scholar