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Published online by Cambridge University Press: 10 February 2011
Conjugated polymers and polymer blends were developed for photosensing applications. Large size photosensors fabricated in ITO/polymer/metal configuration show high photosensitivity, 0.1-0.4 A/Watt in visible and near UV, as good as that made with inorganic semiconductors. The processability of the polymeric materials allows these photosensors be made in large size, onto substrates in desire shape, or even in flexible form, hybridized or integrated with optical devices or electronic devices. Large area, full-color, digital image sensing is demonstrated using photodiode arrays made from semiconducting polymers. The photodiode arrays, fabricated by casting the semiconducting polymer from solution at room temperature, have high photosensitivity, low dark current and large dynamic range. Photo-detection with desired spectral response or multi-band selection are also demonstrated.