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High-Surface - Area Framework Zirconium Phosphates as Catalysts of Hexane Isomerization and Dehydroaromatization: Synthesis and Properties

Published online by Cambridge University Press:  15 February 2011

Vladislav A. Sadykov
Affiliation:
Boreskov Institute of Catalysis, Siberian Branch of the RAS, Lavrentieva, 5, Novosibirsk, RUSSIA; 630090, sadykov@catalysis.nsk.su
S. N. Pavlova
Affiliation:
Boreskov Institute of Catalysis, Siberian Branch of the RAS, Lavrentieva, 5, Novosibirsk, RUSSIA; 630090, sadykov@catalysis.nsk.su
G. V. Zabolotnaya
Affiliation:
Boreskov Institute of Catalysis, Siberian Branch of the RAS, Lavrentieva, 5, Novosibirsk, RUSSIA; 630090, sadykov@catalysis.nsk.su
D. I. Kochubey
Affiliation:
Boreskov Institute of Catalysis, Siberian Branch of the RAS, Lavrentieva, 5, Novosibirsk, RUSSIA; 630090, sadykov@catalysis.nsk.su
R. I. Maximovskaya
Affiliation:
Boreskov Institute of Catalysis, Siberian Branch of the RAS, Lavrentieva, 5, Novosibirsk, RUSSIA; 630090, sadykov@catalysis.nsk.su
V. I. Zaikovskii
Affiliation:
Boreskov Institute of Catalysis, Siberian Branch of the RAS, Lavrentieva, 5, Novosibirsk, RUSSIA; 630090, sadykov@catalysis.nsk.su
V. V. Kriventsov
Affiliation:
Boreskov Institute of Catalysis, Siberian Branch of the RAS, Lavrentieva, 5, Novosibirsk, RUSSIA; 630090, sadykov@catalysis.nsk.su
S. V. Tsybulya
Affiliation:
Boreskov Institute of Catalysis, Siberian Branch of the RAS, Lavrentieva, 5, Novosibirsk, RUSSIA; 630090, sadykov@catalysis.nsk.su
E. B. Burgina
Affiliation:
Boreskov Institute of Catalysis, Siberian Branch of the RAS, Lavrentieva, 5, Novosibirsk, RUSSIA; 630090, sadykov@catalysis.nsk.su
E. A. Paukshtis
Affiliation:
Boreskov Institute of Catalysis, Siberian Branch of the RAS, Lavrentieva, 5, Novosibirsk, RUSSIA; 630090, sadykov@catalysis.nsk.su
A. M. Volodin
Affiliation:
Boreskov Institute of Catalysis, Siberian Branch of the RAS, Lavrentieva, 5, Novosibirsk, RUSSIA; 630090, sadykov@catalysis.nsk.su
V. B. Fenelonov
Affiliation:
Boreskov Institute of Catalysis, Siberian Branch of the RAS, Lavrentieva, 5, Novosibirsk, RUSSIA; 630090, sadykov@catalysis.nsk.su
N. N. Kuznetsova
Affiliation:
Chemical Department, Lomonosov Moscow State Univ., Vorobyoby gory, Moscow, RUSSIA; 119899
V. V. Lunin
Affiliation:
Chemical Department, Lomonosov Moscow State Univ., Vorobyoby gory, Moscow, RUSSIA; 119899
M. V. Chaikina
Affiliation:
Institute of Solid State Chemistry, Siberian Branch of the RAS, Kutateladze, 18, Novosibirsk, RUSSIA, 630128
Dinesh Agrawal
Affiliation:
Materials Research Laboratory, The Pennsylvania State University, University Park, PA 16802
Rustum Roy
Affiliation:
Materials Research Laboratory, The Pennsylvania State University, University Park, PA 16802
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Abstract

Mechanochemical activation of solid inorganic precursors and sol-gel routes followed by hydrothermal treatment in the presence of surfactants were used to synthesize highly dispersed NZP-type complex zirconium phosphates. Genesis of samples real structure and its impact on the surface properties and catalytic performance in the reactions of hexane isomerization and dehydroaromatization have been studied.

Type
Research Article
Copyright
Copyright © Materials Research Society 1999

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References

1. Goodenough, J.B., Hong, H. J., and Kafalas, J. A., Mater. Res. Bull. 11, 173 (1976).Google Scholar
2. Komarneni, S., Int. J. High Technol. Ceram. 4, 31 (1988).Google Scholar
3. Ciesla, U., Schacht, S., Stucky, G. D., Unger, K. K., and Schtith, F., Angew. Chem. Int. Ed. Engl. 35, 541 (1996).Google Scholar
4. Chaikina, M. V.., Chemistry for Sustainable Development 6, 141 (1998) (in Russian).Google Scholar
5. Bolshov, V. A., Volodin, A. M., Zhidomirov, G. M., Shubin, A. A., and Bedilo, A. F., J. Phys. Chem. 98, 7551 (1994).Google Scholar
6. Ono, A., and Okamura, F., Bull. Chem. Soc. Jpn. 58, 1051 (1985).Google Scholar
7. Pavlova, S. N., Sadykov, V. A., Paukshtis, E. A., Burgina, E. B., Degtyarev, S. P., Kochubei, D. I., Saputina, N. F., Kalinkin, A. V., Maximovskaya, R. I., Zaikovskii, V. I., Roy, R. and Agrawal, D., Stud. Surf. Sci. Catal. 119, 759 (1998).Google Scholar