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The Hydrothermal Synthesis and Characterization of New Organically Templated Layered Vanadium Oxides by Methylamine

Published online by Cambridge University Press:  10 February 2011

Rongji Chen ,
Peter Y. Zavalij  and
M. Stanley Whittingham
Rongji Chen
Affiliation:
Chemistry Department and Materials Research Center, State University of New York at Binghamton, Binghamton, New York 13902–6016
Peter Y. Zavalij
Affiliation:
Chemistry Department and Materials Research Center, State University of New York at Binghamton, Binghamton, New York 13902–6016
M. Stanley Whittingham
Affiliation:
Chemistry Department and Materials Research Center, State University of New York at Binghamton, Binghamton, New York 13902–6016
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Abstract

The hydrothermal reaction of vanadium pentoxide with methylamine leads to a series of new layered vanadium oxides by using different acids to adjust the initial pH. The structure of these layered vanadium oxides was established by X-ray single crystal and powder diffraction. The new phases were also characterized by TGA and FTIR. The oxidation state of vanadium was determined. These materials are expected to exhibit catalytic activity and may be of interest as cathode materials for secondary lithium batteries.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 497: Symposium Z – Recent Advances in Catalytic Materials , 1997 , 173
Copyright
Copyright © Materials Research Society 1998

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