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The Influence of Nanosized Molybdenum and Tungsten Fillers on the Physico-Mechanical and Tribological Properties of Polymer-based Composite Materials

Published online by Cambridge University Press:  26 February 2011

Victor Makaryan
Victor Makaryan*
Affiliation:
makvic@freenet.am, State Engineering University of Armenia, Mechanics, Teryan 105, Yerevan 375009, Republic of Armenia, Yerevan, N/A, Armenia
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Abstract

The problems of the creation of composite polymer-based materials with the use of nanosized molybdenum and tungsten fillers with the particle size of less than 10 nm are considered. The copolymer of formaldehyde and dioxolane (CFD) and the polyphenylene sulphide (PPS) are chosen as polymeric matrixes. A comparative analysis of the tribological properties of composite materials with fine nanosized fillers (5-10 nm) and nanosized analogues (100-200) is made. It is determined that the use of nanosized isotropic structure Mo fillers leads to improved wear-resistance up to three times for CFD-based composites and up to four times for PPS-based. The highest hardness values were observed while using isotropic nanosized tungsten fillers. The nanosized crystalline fillers also give positive results, but the bigger sized fillers decrease the polymer hardness characteristics comparatively nanosize isotropic analogues.

Keywords

polymerMoW
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 977: Symposium FF – Processing-Structure-Mechanical Property Relations in Composite Materials , 2006 , 977-FF12-02
Copyright
Copyright © Materials Research Society 2007

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References

1. Makaryan, V.K. Hypothesis of Interaction of Composites Filler Particles with Polymeric Matrix. MRS Proceedings 2004 Volume 856; BB3.9Google Scholar
2. Makaryan, V.K. The peculiarities of the influence of nano-sized MoO2 filler on the tribological properties of polymer-based composite material. Scientific-technical journal “Tribology” Vol. 5. No 3, 2003. pp.40–43 Google Scholar
3. Pogosyan, A.K., Makaryan, V.K., Martirosyan, T. Device for obtaining nanosize powders. Patent of the Republic of Armenia No 1250 Bl.N1.09.06.2003 Google Scholar
4. Malkhassian, R.T., Pogosyan, A.K., Makaryan, V.K, Isajanyan, A. The Influence of Amorphous Nanosized Mo and MoO2 Fillers on the Tribological Properties of Polymerbased Composite Materials. MRS Proceedings 2003 Volume 791, Q8–12, p 255–259 Google Scholar