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Mixed Metal Phospho-Sulfates for Acid Catalysis

Published online by Cambridge University Press:  10 February 2011

S. G. Thoma ,
N. B. Jackson ,
T. M. Nenoff  and
R. S. Maxwell
S. G. Thoma
Affiliation:
Sandia National Laboratories, Albuquerque, NM 87185–0710
N. B. Jackson
Affiliation:
Sandia National Laboratories, Albuquerque, NM 87185–0710
T. M. Nenoff
Affiliation:
Sandia National Laboratories, Albuquerque, NM 87185–0710
R. S. Maxwell
Affiliation:
Lawrence Livermore National Laboratory, Livermore, CA 94551
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Abstract

Mixed Metal Phospho-Sulfates were prepared and evaluated for use as acid catalysts via 2-methyl-2-pentene isomerization and o-xylene isomerization. Particular members of this class of materials exhibit greater levels of activity than sulfated zirconia as well as lower rates and magnitudes of deactivation. 31P MAS NMR has been used to examine the role of phosphorous in contributing to the activity and deactivation behavior of these materials, while powder X-ray diffraction, BET surface area, IR, and elemental analysis were used to characterize the bulk catalysts.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 497: Symposium Z – Recent Advances in Catalytic Materials , 1997 , 191
Copyright
Copyright © Materials Research Society 1998

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References

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