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On The Influence of Nb on the Transition Temperatures of Titanium Aluminides

Published online by Cambridge University Press:  26 February 2011

Harald F. Chladil ,
Helmut Clemens ,
Masao Takeyama ,
Ernst Kozeschnik ,
Arno Bartels ,
Rainer Gerling  and
Sascha Kremmer
Harald F. Chladil
Affiliation:
harald.chladil@unileoben.ac.at, Montanuniversity Leoben, Physical Metallurgy and Materials Testing, Franz-Josef Strasse 18, Leoben, 8700, Austria, +43 3842 402 4204, +43 3842 402 4202
Helmut Clemens
Affiliation:
helmut.clemens@unileoben.ac.at, Montanuniversity Leoben, Department of Physical Metallurgy and Materials Testing, Leoben, 8700, Austria
Masao Takeyama
Affiliation:
takeyama@mtl.titech.ac.jp, Tokyo Institute of Technology, Department of Metallurgy and Ceramics Science, Tokyo, 152-8552, Japan
Ernst Kozeschnik
Affiliation:
ernst.kozeschnik@iws.tugraz.at, Graz University of Technology, Institute for Materials Science, Welding and Forming, Graz, 8010, Austria
Arno Bartels
Affiliation:
bartels@tu-harburg.de, Technical University Hamburg-Harburg, Materials Science and Technology, Hamburg, 21073, Germany
Rainer Gerling
Affiliation:
rainer.gerling@gkss.de, GKSS Research Centre, Institute for Materials Research, Geesthacht, 21502, Germany
Sascha Kremmer
Affiliation:
skremmer@bstg.buag.co.at, Bohler Schmiedetechnik GmbH&CoKG, R&D, Kapfenberg, 8605, Austria
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Abstract

Phase transformations and phase transition temperatures in several Ti-45Al and Ti-45Al-(5-10)Nb (at%) alloys were investigated experimentally and compared to thermodynamic calculation. The present study combines scanning electron microscopy, high-energy and conventional X-ray diffraction as well as differential scanning calorimetry for the characterization of the prevailing phases and phase transformations. Thermodynamic simulation based on the CALPHAD method was used to predict phase stabilities. Modifications of a commercial available database, based on the thermo-physical measurements and long-term annealing treatments, were introduced in order to achieve better agreement between calculated and experimental results.

Keywords

differential thermal analysis (DTA)scanning electron microscopy (SEM)phase transformation
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 980: Symposium II – Advanced Intermetallic-Based Alloys , 2006 , 0980-II07-03
Copyright
Copyright © Materials Research Society 2007

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