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Production, Consolidation, Sintering, and Stability of Novel Nano-Crystalline Zirconia Catalyst Support Powders

Published online by Cambridge University Press:  15 February 2011

John G. Darab ,
Gary G. Neuenschwander ,
Douglas C. Elliott ,
John G. Frye Jr.  and
Joseph T. Strauss
John G. Darab
Affiliation:
Pacific Northwest National Laboratory [1] P.O. Box 999, MS K3-59, Richland, WA 99352
Gary G. Neuenschwander
Affiliation:
Pacific Northwest National Laboratory [1] P.O. Box 999, MS K3-59, Richland, WA 99352
Douglas C. Elliott
Affiliation:
Pacific Northwest National Laboratory [1] P.O. Box 999, MS K3-59, Richland, WA 99352
John G. Frye Jr.
Affiliation:
Pacific Northwest National Laboratory [1] P.O. Box 999, MS K3-59, Richland, WA 99352
Joseph T. Strauss
Affiliation:
HJE Company 151-155 Maple St., Glens Falls, NY 12801
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Abstract

Nano-crystalline, zirconium oxide/oxyhydroxide particulates were produced using a novel, continuous, flow-through hydrothermal technology developed at the Pacific Northwest National Laboratory. Homogeneous aqueous solutions containing ZrO(NO 3)2 and urea were pumped at pressures of 6000-8000 psi through a heated stainless steel reaction tube at 340-350°C. Flow at pressure was maintained using a nozzle at the down-stream end of the reaction tube. In this process, termed Rapid Thermal Decomposition of precursors in Solution (RTDS), the formation of zirconium oxide/oxyhydroxide nano-crystals (diameters of generally less than 15-nm) occurred during the solution's brief residence time (<15 seconds) in the reaction tube, yielding aqueous slurries of agglomerated particulates. Powders were separated from these slurries, washed, then dried. RTDS powder prepared from 0.3M ZrO(NO3)2 and 0.6M urea were mixed with binder and formed into pellets using a commercial screw extruder. These extrudates were subsequently sintered at 500°C, yielding zirconia catalyst support pellets with a measured surface area of 113 m2/g. After application of 3% ruthenium metal to the sintered RTDS zirconia extrudates, the resulting catalyst was evaluated for catalytic activity using the hydrothermal hydrogenation of the sugar xylose to xylitol as a model reaction. After 3 hours at 140°C, the RTDS catalyst exhibited useful activity with 92% conversion and 66% selectivity to xylitol formation.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 549: Symposium FF – Advanced Catalytic Materials - 1998 , 1998 , 67
Copyright
Copyright © Materials Research Society 1999

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References

1. Pacific Northwest Laboratory is operated for the United States Department of Energy by the Battelle Memorial Institute under contract DE-AC06-76RLO 1830.Google Scholar
2. Clearfield, A., Serrette, G.P.D. and Khazi-Syed, A.H., Catalysis Today 20 (1994), 295.Google Scholar
3. Tani, E., Yoshimura, M. and Somiya, S., J. Am. Cer. Soc. 66 (1983), 11.Google Scholar
4. Armstrong, B.L., Materials and Manufacturing Processes 11 (1996), 999.Google Scholar
5. Matson, D.W., Linehan, J.C., Darab, J.G., Buehler, M.F., Phelps, M.R., and Neuenschwander, G.G. in Advanced Catalysts and Nanostructured Materials, ed. Moser, W.R. (Academic Press, New York, 1996), pp. 259–283.Google Scholar
6. Matson, D.W., Fulton, J.L., Linehan, J.C., Bean, R.M., Brewer, T.D., Werpy, T.A., and Darab, J.G., Catalyst Material and Method of Making, US Patent Number 5,652,192 (1997).Google Scholar
7. Darab, J.G., Buehler, M.F., Linehan, J.C. and Matson, D.W. in Better Ceramics Through Chemistry VI, eds. Sanchez, C., Brinker, C.J., Mecartney, M.L. and Cheetham, A. (Materials Research Society, Pittsburgh, 1994), pp. 499–510.Google Scholar
8. Darab, J.G. in Nanostructured Powders and Their Industrial Application, eds. Beaucage, G., Mark, J.E., Burns, G.T., and Hua, D.-W. (Materials Research Society, Pittsburgh, PA, 1998), pp. 161–166.Google Scholar