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Reactive Template-Induced Self-Assembly to Ordered Mesoporous Polymer and Carbon

Published online by Cambridge University Press:  08 August 2013

Yeru Liang ,
Ruowen Fu  and
Dingcai Wu
Yeru Liang
Affiliation:
Materials Science Institute, PCFM Lab and DSAPM Lab, School of Chemistry and Chemical Engineering, Sun Yat-sen University, Guangzhou 510275, P. R. China
Ruowen Fu
Affiliation:
Materials Science Institute, PCFM Lab and DSAPM Lab, School of Chemistry and Chemical Engineering, Sun Yat-sen University, Guangzhou 510275, P. R. China
Dingcai Wu*
Affiliation:
Materials Science Institute, PCFM Lab and DSAPM Lab, School of Chemistry and Chemical Engineering, Sun Yat-sen University, Guangzhou 510275, P. R. China
*
*Email: wudc@mail.sysu.edu.cn
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Abstract

As an important method for preparing ordered mesoporous polymer and carbon, organic template directed self-assembly is facing challenges because of the weak non-covalent interactions between the organic templates and the building blocks. Herein we developed a novel synthetic procedure based on a reactive template-induced self-assembly to construct ordered mesoporous framework. The aldehyde end-group of reactive template can react with the building blocks (i.e., resol) to form a stable covalent bond during the self-assembly process. This leads to an enhanced interaction between resol and template and thus achieves the formation of ordered mesostructure.

Keywords

self-assemblychemical synthesisnanostructure
Type
Articles
Information
MRS Online Proceedings Library (OPL) , Volume 1549: Symposium P – Carbon Functional Nanomaterials, Graphene and Related 2D-Layered Systems , 2013 , pp. 143 - 147
Copyright
Copyright © Materials Research Society 2013 

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References

REFERENCES

Wu, D.; Xu, F.; Sun, B.; Fu, R.; He, H.; Matyjaszewski, K. Design and Preparation of Porous Polymers. Chem. Rev. 2012, 112, 3959–4015.CrossRefGoogle ScholarPubMed
Choi, M.; Ryoo, R. Ordered Nanoporous Polymer-Carbon Composites. Nat. Mater. 2003, 2, 473–476.CrossRefGoogle ScholarPubMed
Liang, C. D.; Li, Z. J.; Dai, S. Mesoporous Carbon Materials: Synthesis and Modification. Angew. Chem. Int. Ed. 2008, 47, 3696–3717.CrossRefGoogle ScholarPubMed
Su, D. S.; Delgado, J. J.; Liu, X.; Wang, D.; Schloegl, R.; Wang, L.; Zhang, Z.; Shan, Z.; Xiao, F.-S. Highly Ordered Mesoporous Carbon as Catalyst for Oxidative Dehydrogenation of Ethylbenzene to Styrene. Chem. Asian J. 2009, 4, 1108–1113.CrossRefGoogle ScholarPubMed
Munoz, B.; Ramila, A.; Perez-Pariente, J.; Diaz, I.; Vallet-Regi, M. MCM-41 Organic Modification as Drug Delivery Rate Regulator. Chem. Mater. 2003, 15, 500–503.CrossRefGoogle Scholar
Wu, Z. X.; Zhao, D. Y. Ordered Mesoporous Materials as Adsorbents. Chem. Commun. 2011, 47, 3332–3338.CrossRefGoogle ScholarPubMed
Zhai, Y.; Dou, Y.; Zhao, D.; Fulvio, P. F.; Mayes, R. T.; Dai, S. Carbon Materials for Chemical Capacitive Energy Storage. Adv. Mater. 2011, 23, 4828–4850.CrossRefGoogle ScholarPubMed
Zhang, F.; Meng, Y.; Gu, D.; Yan, Y.; Chen, Z.; Tu, B.; Zhao, D. An Aqueous Cooperative Assembly Route to Synthesize Ordered Mesoporous Carbons with Controlled Structures and Morphology. Chem. Mater. 2006, 18, 5279–5288.CrossRefGoogle Scholar
Liang, C. D.; Hong, K. L.; Guiochon, G. A.; Mays, J. W.; Dai, S. Synthesis of a large-scale highly ordered porous carbon film by self-assembly of block copolymers. Angew. Chem. Int. Ed. 2004, 43, 5785–5789.CrossRefGoogle ScholarPubMed
Meng, Y.; Gu, D.; Zhang, F.; Shi, Y.; Yang, H.; Li, Z.; Yu, C.; Tu, B.; Zhao, D. Ordered mesoporous polymers and homologous carbon frameworks: amphiphilic surfactant templating and direct transformation. Angew. Chem. Int. Ed. 2005, 44, 7053–7059.CrossRefGoogle ScholarPubMed