Hostname: page-component-cd9895bd7-hc48f Total loading time: 0 Render date: 2025-01-06T04:52:45.955Z Has data issue: false hasContentIssue false
  • English
  • Français

Superconductivity in Clathrates Ba24IV100 ( IV = Si and Ge ) with Rattling Motions

Published online by Cambridge University Press:  26 February 2011

Takeshi Rachi ,
Ryotaro Kumashiro ,
Hiroshi Fukuoka ,
Syoji Yamanaka  and
Katsumi Tanigaki
Takeshi Rachi
Affiliation:
rachi@sspns.phys.tohoku.ac.jp, Tohoku University, Physics, 6-3,Aramaki Aza-Aoba,Aoba-ku, Sendai, 980-8578, Japan, 022-795-6469, 022-795-6470
Ryotaro Kumashiro
Affiliation:
rkuma@sspns.phys.tohoku.ac.jp, Graduate School of Science, Tohoku University, Department of Physics, 6-3, Aramaki Aza-Aoba, Aoba-ku, Sendai, 980-8578, Japan
Hiroshi Fukuoka
Affiliation:
hfukuoka@hiroshima-u.ac.jp, Faculty of Engineering, Hiroshima University, Department of Applied Chemistry, Higashi-Hiroshima, Hiroshima, 739-8527, Japan
Syoji Yamanaka
Affiliation:
syamana@hiroshima-u.ac.jp, Faculty of Engineering, Hiroshima University, Department of Applied Chemistry, Higashi-Hiroshima, Hiroshima, 739-8527, Japan
Katsumi Tanigaki
Affiliation:
tanigaki@sspns.phys.tohoku.ac.jp, Graduate School of Science, Tohoku University, Department of Physics, 6-3, Aramaki Aza-Aoba, Aoba-ku, Sendai, 980-8578, Japan
Get access

Abstract

Both Ba24Si100 and Ba24Ge100 with crystallographically identical structure are the superconductors whose critical temperatures are 1.45 and 0.27 K, respectively. Intriguingly, physical properties of the both compounds are extremely different. The observed differences are considered to be associated with Ba rattling motions. We have exemplified such unique motions in terms of x-ray diffraction data using MEM/Rietveld analyses. We present these exotic systems especially focusing on the relation between superconductivity and the rattling phonons.

Keywords

superconductingelectron-phonon interactionsnanostructure
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 988: Symposium QQ – Solid-State Chemistry of Inorganic Materials VI , 2006 , 0988-QQ07-02
Copyright
Copyright © Materials Research Society 2007

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Mudryk, Y., Rogl, P., Paul, C., Berger, S., Bauer, E., Hilscher, G., Godart, C., and Noël, H., J. Phys.: Condens. Matter 14 7991 (2002).Google Scholar
2. Kawaji, H., Horie, H. O., Yamanaka, S., and Ishikawa, M., Phys. Rev. Lett. 74, 1427 (1995).Google Scholar
3. Yamanaka, S., Enishi, E., Fukuoka, H., and Yasukawa, M., Inorg. Chem. 39, 56 (2000).Google Scholar
4. Herrmann, R. F. W., Tanigaki, K., Kawaguchi, T., Kuroshima, S., and Zhou, O., Phys. Rev. B 60, 13245 (1999).Google Scholar
5. Carrilo-Cabrera, W., Curda, J., von Schnering, H. G., Pachen, S., and Grin, Yu., Z. Kristallogr. 215, 207 (2000);W.Carillo-Cabrera, H.Borrmann, S.Paschen, M.Baenitz, F.Steglich, and Y.Grin, J. Solid State Chem. 178, 715 (2005).Google Scholar
6. Grosche, F. M., Yuan, H. Q., Carrillo-Cabrera, W., Paschen, S., Langhammer, C., Kromer, F., Sparn, G., Baenitz, M., Grin, Yu., and Steglich, F., Phys. Rev. Lett. 87, 247003 (2001).Google Scholar
7. Fukuoka, H., Iwai, K., Yamanaka, S., Abe, H., Yoza, K., and Haming, L., J. Solid State Chem. 151, 117 (2000).Google Scholar
8. Fukuoka, H., Ueno, K., and Yamanaka, S., J. Organomet. Chem. 611, 543 (2000).Google Scholar
9. Rachi, T., Yoshino, H., Kumashiro, R., Kitajima, M., Kobayashi, K., Yokogawa, K., Murata, K., Kimura, N., Aoki, H., Fukuoka, H., Yamanaka, S., Shimotani, H., Takenobu, T., Iwasa, Y., Sasaki, T., Kobayashi, N., Miyazaki, Y., Saito, K., Guo, F.Z., Kobayashi, K., Osaka, K., Kato, K., Takata, M., and Tanigaki, K., Phys. Rev. B 72 (2005) 144504.Google Scholar
10. Viennois, R., Toulemonde, P., Paulsen, C., and San-Miguel, A., J. Phys.: Condens. Matter 17, L311 (2005).Google Scholar
11. Tanigaki, K., Shimuzu, T., Itoh, K. M., Teraoka, J., Moritomo, Y., and Yamanaka, S., Nat.Mater. 2, 653 (2003).Google Scholar
12. Connetable, D., Timoshevskii, V., Masenelli, B., Beille, J., Marcus, J., Barbara, B., Saitta, A. M., Rignanese, G. M., Mlinon, P., Yamanaka, S., and Blase, X., Phys. Rev. Lett. 91, 247001 (2003).Google Scholar
13. Rachi, T., Tanigaki, K., Kumashiro, R., Winter, J., and Kuzmany, H., Chem. Phys. Lett. 409,48 (2005).Google Scholar
14. Nishibori, E., Takata, M., Kato, K., Sakata, M., Kubota, Y., Aoyagi, S., Kuroiwa, Y., Yamakata, M., and Ikeda, N., Nucl. Instrum. Methods Phys. Res. A 467–468, 1045 (2001).Google Scholar
15. Paschen, S., Tran, V. H., Baenitz, M., Carrillo-Cabrera, W., Grin, Y., and Steglich, F., Phys. Rev. B 65, 134435 (2002).Google Scholar
16. Shimizu, H., Kume, T., Kuroda, T., Sasaki, S., Fukuoka, H., and Yamanaka, S. Phys. Rev. B 71, 094108 (2005).Google Scholar
17. Takata, M., Nishibori, E., and Sakata, M., Z. Kristallogr. 216 71 (2001).Google Scholar
18. Tanaka, H., Takata, M.. Nishibori, E., Kato, K., Iishi, T., and Sakata, M.,J. Appl. Crystallogr. 35 282 (2002).Google Scholar