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Synthesis of Ain and AlN/SiC Ceramics from Polymeric Molecular Precursors

Published online by Cambridge University Press:  25 February 2011

Robert T. Paine ,
Jerzey FR. Janik  and
Chaitanya Narula
Robert T. Paine
Affiliation:
Department of Chemistry, University of New Mexico, Albuquerque, NM 87131
Jerzey FR. Janik
Affiliation:
Department of Chemistry, University of New Mexico, Albuquerque, NM 87131
Chaitanya Narula
Affiliation:
Department of Chemistry, University of New Mexico, Albuquerque, NM 87131
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Abstract

Reactions of (Me3Si)3 AI·Et2O with NH3 in different stoichiometric ratios have been studied in search of useful precursors to AIN. Two molecular condensation-elimination compounds and an insoluble oligomer have been obtained from these reactions, and pyrolysis of the compounds leads to the convenient formation of AlN/SiC solid solutions.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 121: Symposium H – Better Ceramics Through Chemistry III , 1988 , 461
Copyright
Copyright © Materials Research Society 1988

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References

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