Published online by Cambridge University Press: 28 February 2011
This is Part II of a tribological study of metal/ceramic pair in a sliding contact. The tribological behavior of molybdenum against a single crystal A12O3 was investigated at bulk temperatures of 23ºC and 400ºC using a sliding speed of 4 m/s and loads from nine to twenty five Newtons. The role of oxidational wear was confirmed at both temperatures. The linear dependency of wear rate on load was identified at 23ºC tests. At 400ºC, there was a rapid increase of wear rate at a load of about 25 N possibly due to the volatilization of MoO3, which is the limitation of molybdenum oxide as a solid lubricant. However, this study showed that the out-of-contact oxide formation may have prevented the catastrophic oxidation during contact at the real area of contact. It also showed that in-situ formed molybdenum oxide has good lubricating properties (≃ 0.3) and a low wear rate (≃ 10-14 m3/m). Therefore, this molybdenum can be used for a large range of sliding speeds and loads.