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Published online by Cambridge University Press: 10 February 2011
Natural fission reactors located in the uranium ore deposits of Oklo-Okélobondo and Bangombé (Gabon) are a unique case of natural nuclear waste disposal. The Reactor Zones (RZ) (up to fifteen) cores are made of 60% uranium (UO2) embedded in a clay matrix [1]. The uraninites are depleted in 235U and contain fission products. Therefore, they are considered to be good analogues for spent nuclear fuel matrix [2]. The aim of this work is to study the conditions of preservation over a long periode of time of the uraninites which have been sumitted to interraction with fluid having different oxidizing potential. For this purposes mineralogical (X-ray powder diffraction), chemical (electron microprobe) and oxygen isotopic analyses were performed on uraninites from various RZs.