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XXXII.—An Elementary Treatment of Thermal Diffusion in Gaseous and Liquid Systems

Published online by Cambridge University Press:  14 February 2012

Mowbray Ritchie
Mowbray Ritchie
Affiliation:
Chemistry Department, University of Edinburgh
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Summary

An elementary theory of thermal diffusion applicable to gaseous and liquid systems has been developed. This is based on the difference of diffusional characteristics of a molecule considered as diffusing through two different temperature regions, when the pressure is constant throughout.

For gaseous systems, the resultant expression is shown to be in general accordance with experimental variation of temperature, mass, and diameter factors, and is further developed to include isotopic separation, change of sign of separation with concentration, and general force law considerations.

A similar approach to thermal diffusion in solution, combined with the convection effect of a “cascade” system, gives an expression which is in general agreement with the results of experimental variation of mean temperature and temperature gradient for aqueous solutions of sucrose, glucose and glycerol. The simple expression does not account rigidly for the sign of separation or the effect of altered concentrations. These discrepancies are discussed in relation to the general formula; it is concluded that in addition to the diffusion diameters, the relative thermal expansions of solute and solvent are of importance in this connection.

Type
Research Article
Information
Proceedings of the Royal Society of Edinburgh Section A: Mathematics , Volume 62 , Issue 3 , 1948 , pp. 305 - 315
Copyright
Copyright © Royal Society of Edinburgh 1946

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References

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