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“Reference waters” in French laboratories involved in tritiummonitoring: how tritium-free are they?

Published online by Cambridge University Press:  21 March 2014

E. Fourré*
Affiliation:
Laboratoire des Sciences du Climat et de l’Environnement, UMR 8212 CEA-CNRS-UVSQ/IPSL, CEN Saclay, 91191 Gif-sur-Yvette, France.
P. Jean-Baptiste
Affiliation:
Laboratoire des Sciences du Climat et de l’Environnement, UMR 8212 CEA-CNRS-UVSQ/IPSL, CEN Saclay, 91191 Gif-sur-Yvette, France.
A. Dapoigny
Affiliation:
Laboratoire des Sciences du Climat et de l’Environnement, UMR 8212 CEA-CNRS-UVSQ/IPSL, CEN Saclay, 91191 Gif-sur-Yvette, France.
E. Ansoborlo
Affiliation:
CETAMA, CEA/DEN/DCRP, Marcoule, 30207 Bagnols-sur-Cèze, France.
N. Baglan
Affiliation:
CEA/DAM/DIF, 91297 Arpajon, France.
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Abstract

This paper presents a comprehensive survey of the tritium content of “reference waters”in real working conditions by French laboratories involved in environmental monitoring.Reference waters are virtually tritium-free waters used to determine blanks for theanalytical system and to check for any contamination. It is therefore crucial to be sureof the low tritium content of these waters as this can limit the sensitivity and accuracyof the measurements. Water from the commercial brand “Abatilles” is widely used in Frenchlaboratories and nine samples were analyzed in this study. Three samples from other deepaquifers were also included. The results all range from 0.004 ± 0.004 Bq/kg to 0.175 ± 0.011 Bq/kg, well below the 0.5Bq/kg advised by the French Safety Authority. The spread of the results can mainly beattributed to contamination through plastic during bottle storage. As expected, twosamples from demineralized tap water showed higher tritium activities (0.3–0.35 Bq/kg).Both waters are suitable as reference water for routine monitoring (DL of about 10 Bq/kg)but should be used with caution for activities in the Bq/kg range.

Type
Article
Copyright
© EDP Sciences, 2014

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References

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