We prove an asymptotic expansion of the second moment of the central values of the $\mathrm {GL}(n)\times \mathrm {GL}(n)$ Rankin–Selberg L-functions $L(1/2,\pi \otimes \pi _0)$ for a fixed cuspidal automorphic representation $\pi _0$ over the family of $\pi $ with analytic conductors bounded by a quantity that is tending to infinity. Our proof uses the integral representations of the L-functions, period with regularised Eisenstein series and the invariance properties of the analytic newvectors.