The Hällefors silver deposit is regarded as a volcanogenic-exhalative iron ore deposit with dispersed amounts of Ag-Pb-Zn (±Cu) which has undergone secondary remobilization leading to the concentration of sulphides and sulphosalts. Based on data from the iron oxides and sulphides, the sulphide-sulphosalt mineralization is believed to have been formed in two stages. The first is characterized by the ranges 573-473 K and 2.25–1.5 kbar, higher gradient of changes of log aS2 with temperature and mostly sulphide precipitation; the second by the ranges 473–443 K, lower gradient of changes of log aS2 and mainly sulphosalt deposition. Assuming the precipitation was from fluids and aqueous solutions, possible conditions of formation of some of the iron minerals have been determined.

A study of mine dump material from Koberg, Bergslagen, Sweden has revealed a varied mineral assemblage, including Zr-, REE-, Th- and U-bearing minerals associated with the sulphide ore deposit. Detailed descriptions and microprobe analyses are presented of the rare earth minerals yttrian zirconolite and allanite-(Ce), and the zirconium oxide baddeleyite. Yttrian zirconolite is patchily zoned in the actinide elements Th and U, and the low analytical totals suggest the presence of several weight per cent of H2O. The implications of these features with respect to synthetic zirconolite in SYNROC and to radioactive waste management are briefly discussed. Chemical zoning of individual REE in yttrian zirconolite is described and the REE distribution compared with those of zirconolites from other localities. Allanite-(Ce) is generally unzoned, but contains REE-rich rims which are considered to be sub-micron intergrowths of allanite plus a bastnäisite-type mineral phase. The MgO content of allanite-(Ce) is unusually high and appears to be a characteristic feature of allanite from other cerium and mineral occurrences of Central Sweden. The rare earth minerals at Koberg are interpretated as having been formed as a result of localized remobilization of elements including Ti and Zr with H2O- and CO2-rich fluids.

Zones of albitization 20 m wide are developed in the peraluminous, undeformed Proterozoic Bastfallshöjden granite, W. Bergslagen, central Sweden. During albitization Na, Si, Mg, Ni, Zn, and Ga are added, while Fe2+, Fe3+, Mn, K, Sc, Rb, Cs, Ba, Pb, U, and F are lost, together with the rare earth elements (REE) in decreasing amounts with increasing atomic number. Ti, Al, P, and Y were immobile. Trace element data for chlorites separated from hydrothermally altered country rocks and from a quartz-chlorite vein in the albitized granite show similar REE patterns indicating a common origin: the most altered granite has a similar REE pattern, probably resulting from interaction with the same hydrothermal fluid which produced the chlorites, in which seawater is thought to have been an important constituent.

Amphiboles of the tremolite-ferro-actinolite series from the Bergslagen district in central Sweden have between 0 and 46% of their M1-M3 sites occupied by Mn. These amphiboles are divided into two groups; (1) a group characterised by Mn (M1-M3) > (Mg or Fe) (M1-M3), and (2) a group with much lower contents of Mn (M1-M3), showing the following chemical characteristics: (a) Mn (M1-M3) never exceeds Fe (M1-M3); (b) in Mg-rich members of the group [Mg (M1-M3) > (Mn or Fe) (M1- M3)], the highest amounts of Mn (M1-M3) occur in amphiboles with about 2.20 Mg (M1-M3) per formula unit (pfu); in Fe-rich members of the group Fe [(M1-M3) > (Mg or Mn) (M1-M3)] high amounts of Mn (M1-M3) [> 0.4 Mn (MI-M3)] pfu only occur in amphiboles with >3.40 Fe (M1-M3) pfu; (d) the lowest amounts of Mn (M1-M3) occur in amphiboles with Mg (M1-M3) = Fe (M1-M3).

Mn (M4) increases with increasing amounts of Mn (M1-M3), indicating that solid solution towards the tirodite-dannemorite series is enhanced by incorporation of Mn (M1-M3).

Using type material from the Österby pegmatite in Dalarna, Sweden, the chemical composition and structural parameters of thalénite-(Y) [ideally Y3Si3O10(OH)] were examined by wavelength dispersive spectroscopy electron microprobe (WDS EMP) analysis and single-crystal X-ray diffraction. High contrast back-scatter electron images of the Österby material show at least two generations of thalénite-(Y). The formula of the primary thalénite-(Y) normalized to 11 anions is (Y2.58Dy0.11Yb0.09Gd0.06Er0.06Ho0.02Sm0.02Tb0.02Lu0.02Nd0.01Tm0.01)Σ3.00Si3.01O10F0.97OH0.03. The secondary thalénite-(Y), replacing the primary material, is weakly enhanced in Y and depleted in the lightest and the heaviest rare-earth elements, yielding the formula (Y2.63Dy0.12Yb0.06Gd0.06Er0.05Ho0.02Sm0.02Tb0.02Tm0.01Nd0.01Lu0.01)Σ3.00Si3.01O10F0.98OH0.02. Structural data for thalénite-(Y) from Österby clearly indicate the monoclinic space group P21/n, with a = 7.3464(4), b = 11.1726(5), c = 10.4180(5) Å, β = 97.318(4)°, V = 848.13(7) Å3, Z = 4, which is consistent with previous investigations. The structure was refined from single-crystal X-ray diffraction data to R1 = 0.0371 for 1503 unique observed reflections, and the final chemical composition obtained from the refinement, (Y2.64Dy0.36)Σ3.00F0.987[Si3O10], Z = 4, is in good agreement with the empirical formula resulting from electron microprobe (EMP) analysis. Both techniques reveal a strong dominance of F over OH, which means that the type material actually corresponds to the fluorine analogue. Moreover, new EMP analyses of samples of thalénite-(Y) from an additional seven localities (Åskagen and Reunavare in Sweden; White Cloud and Snow Flake in Colorado, USA; the Guy Hazel claim in Arizona, USA; Suishoyama and Souri in Japan) clearly show the prevalence of F over OH as well. Based on these observations, the Commission on New Minerals, Nomenclature and Classification of the International Mineralogical Association has recommended a redefinition of the chemical composition of thalénite-(Y) to represent the F-dominant species with the ideal formula Y3Si3O10F, as it has historical priority. Consequently, the later described fluorthalénite-(Y) has to be discredited.

The Svecofennian Domain of the Fennoscandian Shield constitutes a considerable volume of Palaeoproterozoic crustal growth, 2.1–1.86 Ga ago, in between the Archaean craton in the NE and the 1.85–1.65 Ga Transscandinavian Igneous Belt (TIB) in the south and west. The Bergslagen area is a classical ore province located in the southwestern part of the Svecofennian Domain of south-central Sweden. Its northern part is dominated by volcanic and plutonic rocks of a magmatic arc with continental affinity, while the SE part is made up by a sedimentary basin. The Bergslagen area shows a metamorphic zonation from lower to middle amphibolite facies in the north to upper amphibolite facies and locally granulite facies in the south; a small greenschist area exists in the west. Identifying the age spectra of inherited components, magmatic crystallization, as well as metamorphic episodes, provide important constraints on the geodynamic evolution of this centrally located piece of the Shield.

U–Pb zircon SIMS data presented in this paper complement the previous, regionally scattered TIMS data from this area. Magmatic zircons from two felsic metavolcanic rocks and two amphibolites (metagabbros) yield 1888±12, 1892±7 and 1887±5, 1895±5 Ma, respectively; i.e. within the 1.91–1.86 Ga range previously obtained for Early Svecofennian magmatism in Bergslagen. An augen gneiss from southern Bergslagen, assigned to the earliest TIB generation, yield an intrusive age of 1855±6 Ma. Metamorphic monazites from the same rock indicate that deformation and elevated thermal activity prevailed 1.83–1.82 Ga ago (TIMS). Metamorphic zircons in high-grade metasedimentary rocks from the south and west yield ages of 1793±5 and 1804±10 Ma, in accordance with ages for regional peak metamorphism and migmatite formation found elsewhere in the southern Svecofennian province of Sweden. More importantly, a few zircon crystals and overgrowths in rocks from the north indicate an early metamorphic episode at c. 1.87 Ga, indicating that Bergslagen has experienced two major metamorphic events. Detrital and inherited zircons span the range 2.78–1.90 Ga, with an apparent gap at 2.45–2.1 Ga, which further emphasize previous observations of a major juvenile (<2.1 Ga) and a minor Archaean provenance. This, and in particular the 1.94–1.91 Ga crystals present in the c. 1.89 Ga amphibolites, support the suggestion of a former Palaeoproterozoic pre-1.91 Ga crust in the Bergslagen area.