Submicroscopic intergrowths of K biotite, Na biotite and intermediate Na-K biotite from a schist near Málaga (Betic Cordilleras, Spain) were discovered using high-resolution transmission electron microscopy and analytical electron microscopy. The sample was also studied with X-ray diffraction, electron microprobe analysis, and scanning electron microscopy. Scanning electron microscopy revealed that the Na-enriched biotite is concentrated in albite-rich microdomains, albite being partially replaced by biotite. These images also revealed that both K and Na-K biotite grains appear locally retrograded to kaolinite. Transmission electron microscopic data indicated that K biotite, Na biotite and Na-K biotite form parallel or subparallel packets with interfaces parallel to the basal planes of biotite. Potassium biotite forms thick packets, chemically homogeneous, with a basal spacing of 10.1 Å. Sodium biotite also occurs as chemically homogeneous stacks of layers with a 9.78 Å periodicity. Sodium-K biotite shows, on the contrary, variable composition and basal spacings intermediate between K and Na biotites. Analytical electron microscopic data revealed important chemical differences between Na and K biotites, which affect both the tetrahedral and the octahedral sheets. Both electron microprobe analysis and analytical electron microscopy indicated that the trioctahedral micas show relatively low interlayer occupancy, suggesting the presence of H3O+ replacing the interlayer cations. Partial hydration of biotite explains the presence of a weak 14 Å reflection in the X-ray patterns. Both chemical and textural data suggested that these trioctahedral micas grew during a common prograde metamorphic episode, the phases with intermediate composition probably being metastable.

The effects of a subvolcanic intrusion on its host rocks in the Priego de Córdoba area (SE Spain) was studied by optical microscopy, X-ray diffraction and electron microscopy. The intrusion of a laccolith of stratiform dolerite in partially consolidated marly sediments at quite shallow depths below the ocean floor took place during the intracontinental rifting phase of the Subbetic zone of the Betic Cordilleras. In the first stage, contact metamorphism caused the crystallization of calc-silicate consisting of grossular andradite garnet, diopside, vesuvianite and titanite for which the upper temperature limit was 500°C. Phyllosilicates are found in a network of veins cross-cutting the carbonate and calc-silicate matrix, indicating their formation during a process of hydrothermal alteration superimposed on the contact aureole. In the area closest to the subvolcanic rocks, saponite is the main phyllosilicate although some dispersed chlorite is found. In the zone furthest from the contact, corrensite together with saponite and beidellitic smectites were observed. The presence of low-temperature phases (saponite) in the area closest to the laccolith reveals the evolution of the hydrothermal system toward cooler conditions. In the early stage, the circulation of a hot hydrothermal fluid caused the crystallization of chlorite in the area surrounding the subvolcanic body and corrensite in the more distal area, which might have begun even during the contact metamorphism stage. A cooling phase followed, resulting in the crystallization of saponite in the host rocks, and the crystallization of dioctahedral and trioctahedral smectites inside the subvolcanic body.

Mixed-layered phyllosilicates with composition intermediate between mica and chlorite were identified in very low-grade metaclastites from the Malàguide Complex (Betic Cordilleras, Spain), and studied by X-ray diffraction, and transmission and analytical electron microscopy. They occur both as small grains in the rock matrix, and associated with muscovitechlorite stacks. Transmission electron microscope observations revealed a transition from chlorite to ordered 1:1 interstratifications through complex 1:2 and 1:3 interstratifications. Analytical electron microscopy data indicate a composition slightly different from the sum of discrete trioctahedral chlorite and dioctahedral mica. The types of layer transitions suggest that mixed-layer formation included two main processes: (1) the replacement of a brucite sheet by a cation sheet in the chlorite structure; and (2) the precipitation of mica-like layers between the chlorite layers. The strongest diffraction lines in oriented X-ray patterns are: 12.60 Å (002), 7.98 Å (003), 4.82 Å (005) and 3.48 Å (007).

Triassic sequences from 'intermediate units' between the Alpujárride and the Malâguide complexes (Betic Cordilleras, Spain) of the westernmost part of the Cordilleras (Casares area) occur as four superimposed tectonic units; the uppermost unit shows lithological characteristics similar to those of the Malâguide complex, changing progressively at increasing depth, towards lithologies typical of the Alpujárride complex. The units studied, with a maximum thickness of ~400 m, record important variations in metamorphic pressures, according to the b parameter of white micas: from low-pressure metamorphism (in the unper unit) to high-pressure faciès series (in the deepest one). The mean b values range from 8.988 Å in the uppermost unit (Crestellina) to 9.042 Å in the lowermost one (Jubrique). The lowest metamorphic grade is represented by mineral assemblages consisting of phengite + intermediate Na-K white mica ± Fe-chlorite ± sudoite ± pyrophyllite, which record temperatures of ~300°C and pressures of 1.5—3 kbar. At increasing tectonic depth, intermediate Na-K mica and pyrophyllite disappear and the metamorphic assemblages consist of phengite ± paragonite ± margarite + Mg-chlorite ± sudoite, which record minimum pressures of ~7 kbar and temperatures in the order of 400—450°C. These mineral assemblages provide evidence of the passage from collisional to extensional geotectonic settings. The units showing different metamorphic patterns were juxtaposed tectonically, after the development of metamorphic mineral assemblages.

Clay mineral evolution in diagenetic and very low-grade metamorphic sedimentary rocks from the Maláguide Complex was studied using the following parameters: illite and chlorite crystallinity, b cell dimension of illite, chemistry of chlorite, and the occurrence and distribution of the following phyllosilicates: I-S mixed-layer minerals, kaolin polytypes, chlorite-bearing mixedlayer minerals (tosudite and mica-chlorite interstratifications), vermiculite-like minerals, paragonite and biotite. The distribution of IC values permits the subdivision of the study area into three zones: diagenetic, anchizone and epizone. On the contrary, the distribution of CC values cannot be used in the study of the metamorphic zonation. The mineralogy and b dimension of illite indicate that the Maláguide samples display a low to low-medium pressure metamorphism, also characterized by steep temperature gradients.

The correlation between IC data and distribution of other significant minerals has permitted the establishment of a zonation within the chlorite zone, which is confirmed by the appearance of some index minerals, such as paragonite, biotite, chloritoid and andalusite.

The Carboneras Fault Zone (CFZ) represents an active set of sinistral strike-slip faults in the Betic Cordilleras of southeastern Spain. It constitutes a major segment of the ‘Trans-Alboran shear zone’ during the Cenozoic, striking NE-SW. The CFZ separates the Cabo de Gata Block (Neogene volcanics) against Neogene basinal sediments and the metamorphic basement of the Alpujarride Complex.

Three sites along the CFZ were examined with Ground Penetrating Radar techniques. Radar surveying was complemented by structural studies. Shallow-depth high-resolution imaging of Tyrrhenian beach terraces exhibited both vertical and minor horizontal offsets in the Rambla Morales site in the south. A sinistral strike-slip fault associated with minor thrust faults in a positive flower structure was detected in the middle segment along the La Serrata ridge, sealed by a caliche of late Pleistocene age (> 10 ka). The Playa de Bolmayor section yielded sub-surface evidence for several faults probably related to recent activity of individual fault strands. Our results suggest a distributed tectonic activity of the CFZ during the Late Quaternary.

The hot emplacement of the Ronda peridotites (Betic Cordilleras) developed a dynamothermal aureole and partial melts that led to the intrusion of granite dykes in the peridotites. Previous geochronological data place rather broad limits for this event between 22 and 19 Ma. Analyses of neocrystalline zircon rims from large zircon populations yield a U–Pb SHRIMP age of 22.3±0.7 Ma for the dynamothermal aureole formation, and intrusion ages of granite dykes between 22.6±1.8 and 21.5±3.8 support that conclusion. Therefore, these new ages provide a more robust constraint on the hot emplacement of the Ronda peridotites at middle crustal levels.

Approximately 10-15 vol% of the Neogene Hoyazo dacite consists of Al-rich restite rock inclusions (A12O3 = 20–45%) and monocrystal inclusions derived therefrom. Restite material and dacitic melt were formed syngenetically from a (semi-)pelitic rock sequence by means of anatexis. Restite rock fragments and dacite show similar high δ18O values (13–16‰) corresponding to those found for sedimentary material. Striking monocrystal restite inclusions in the dacite rock are graphite crystals measuring a few hundred μm, 0.5–10 mm blue cordierite crystals and 2–10 mm ruby red crystals of almandine-rich garnet (1.1 ± 0.2 vol%). Although the almandine crystals are perfectly euhedral, they are identical in every respect to the crystals found in the Al-rich restite rock inclusions and cannot be crystallisation products of the magmatic melt. The dacite also contains many inclusions of quartz gabbroic and basaltoid material which contains inclusions identical to the restite material found in the dacitic glass base. Many basaltoid inclusions show well-developed chilled borders. These inclusions may represent a more mafic magma of deeper origin which mixed with some dacite magma before mingling into it.