The increased detection of pharmaceuticals in finished drinking water has become a growing cause of concern in recent years. The removal of atenolol, ranitidine, and carbamazepine by sepiolite, following functionalization of its surface by organosilane grafting, constituted the subject of this investigation. Silylated surfaces include octyl, γ-aminopropyl, 3-chloropropyl, and triphenyl moieties. The sorption of atenolol and ranitidine was higher on sepiolite functionalized with 3-chloropropyl, while carbamazepine showed a higher sorption on sepiolite with triphenyl groups. Filtration experiments of both ranitidine and carbamazepine on octyl- and triphenyl-sepiolite, respectively, showed a higher retention of ranitidine in comparison to carbamazepine, in spite of the fact that the number of sorption sites was lower due to its higher binding rate.

Drinking-water supply remains a significant challenge in tropical areas; to help meet this challenge, the purpose of the present study was to manufacture low-thermal conductivity ceramic membranes suitable for the retention/removal of particles found in non-potable water. These membranes with significant chemical and mechanical resistances were developed from Cameroonian clays, cassava starch, and bovine bone ash. Up to 30% of Cassava starch and bovine bone ash were added to the membrane as porogens (materials used to make pores in membranes). Membranes were manufactured by uniaxial pressing, drying at 105°C, and sintering at 1150°C for 2 h. The effects of various types of porogen on the thermal behavior, microstructure, flexural strength, porosity, and permeability of ceramic membranes were investigated to determine possible applications of those membranes for water filtration in the tropics. The thermal conductivity of membranes produced without a pore-forming agent (SM0) was greater (0.54 Wm–1K–1) than those produced with starch (SM1 and SM3) (0.45–0.40 Wm–1K–1) or bovine bone ash (SM2) (0.49 Wm–1K–1). The total porosity of SM0s (30.72%) was less than those of starch and bovine bone membranes (37.87–45.99%). The average pore size (0.04 μm) of SM2 membranes was the smallest: SM0 (0.09 μm), SM1 (0.10 μm), and SM3 (0.07 μm). The maximum pore size was 0.37 μm, indicating that membranes contain mesopores and macropores. The flexural strengths of SM1 and SM3 membranes (8.85 and 6.97 MPa, respectively) were less than those of SM2 (10.53 MPa) and SM0 (10.28 MPa), and water permeability from 108 L/h·m2 bar to 2198 L/h·m2 bar. Filtered water properties showed that pH values were upgraded from 5.9 to 7, the turbidity reduction rates and levels were >94% and <0.65 NTU. Particle-size distributions moved from 1150–39,000 nm in polluted water to <2 nm in filtered water. Judging by the sizes of particles present in filtered waters, these membranes may be suitable for elimination of viruses, pigments, proteins, colloids, and bacteria.

A clay from the Mediterranean area classified as natural bleaching earth was comprehensively characterized and the quantitative phase content was determined. Morphology and surface characteristics were determined by environmental scanning electron microscopy (ESEM) and nitrogen adsorption. The BET surface area was >200 m2 g–1 and the average mesopore diameter was >10 nm. Thus the clay is suitable for bioseparation of larger proteins. X-ray diffraction (XRD), X-ray fluorescence (XRF), cation exchange capacity (CEC), layer charge measurement and simultaneous thermal analysis (STA) were used for mineralogical characterization. Determination of the phase content by Rietveld analysis was possible only after Sr2+ saturation, while Rietveld analysis of XRD patterns from Na+-saturated clay resulted in a strong overestimation of the amorphous content and masking of the sepiolite. The clay consists of sepiolite, dioctahedral smectite with high layer charge and low stack height, X-ray amorphous matter (probably mainly SiO2) and accessory feldspars.

The rheological and filtration properties of a Tunisian clay are presented and compared with those of Wyoming bentonite. The study was part of an evauation of Tunisian mining resources in general, and of the bentonitic deposits in particular. Qualitatively, the two clays exhibit the same rheological and filtration behaviour but quantitatively the properties of purified Wyoming bentonite are distinctly better at the same concentration. The difference can be related to the mineralogical structure and the presence of 13% illite in the Tunisian clay. Standard tests show that the rheological behaviour of the purified Tunisian clay is close to that of the raw Wyoming bentonite and conform to the American Petroluem Institute (A.P.I.) standards for medium-depth drilling formulations.

This work examines possible new applications for common, clay-based formulations. We processed spray-dried grains of a common clay (ZA-4) and collected fines/rejects from the production of lightweight aggregates (LWA), which were used as filtration beds for removal of Pb2+ and Ni2+ from aqueous solutions. Experiments were performed at different contaminant concentrations and by testing several operational conditions. The removal performance of both tested materials is strongly dependent on the particle-size distribution of the batch, being better for beds made of smaller grain size, since packing density and specific contact area for removal are greater. In general, the efficiency for removal of Pb2+ was greater than for Ni2+. When compared with granular activated carbon, clay-based beds performed well. In particular, finer fractions of LWA show stable behaviour, without saturation after consecutive runs. Saturated beds can potentially be reused, in appropriate amounts, for production of new lightweight aggregates or common ceramic items (e.g. bricks), since retained contaminants will be fixed by firing in the clay matrix. Calcination of pressed pellets made of contaminated filter grains created consolidated ceramic components and sorbed metallic species became inert.

Let ${{\Theta }^{[j]}}$ be an analogue of the Ramanujan theta operator for Siegel modular forms. For a given prime $p$ , we give the weights of elements of mod $p$ kernel of ${{\Theta }^{[j]}}$ , where the mod $p$ kernel of ${{\Theta }^{[j]}}$ is the set of all Siegel modular forms $F$ such that ${{\Theta }^{[j]}}(F)$ is congruent to zero modulo $p$ . In order to construct examples of the mod $p$ kernel of ${{\Theta }^{[j]}}$ from any Siegel modular forms, we introduce new operators ${{A}^{(j)}}(M)$ and show the modularity of $F|{{A}^{\left( j \right)}}\left( M \right)$ when $F$ is a Siegel modular form. Finally, we give some examples of the mod $p$ kernel of ${{\Theta }^{[j]}}$ and the filtrations of some of them.

This is a case study concerning the rate at which probabilistic coupling occurs for nilpotent diffusions. We focus on the simplest case of Kolmogorov diffusion (Brownian motion together with its time integral or, more generally, together with a finite number of iterated time integrals). We show that in this case there can be no Markovian maximal coupling. Indeed, there can be no efficient Markovian coupling strategy (efficient for all pairs of distinct starting values), where the notion of efficiency extends the terminology of Burdzy and Kendall (2000). Finally, at least in the classical case of a single time integral, it is not possible to choose a Markovian coupling that is optimal in the sense of simultaneously minimizing the probability of failing to couple by time t for all positive t. In recompense for all these negative results, we exhibit a simple efficient non-Markovian coupling strategy.

We introduce stable canonical rules and prove that each normal modal multi-conclusion consequence relation is axiomatizable by stable canonical rules. We apply these results to construct finite refutation patterns for modal formulas, and prove that each normal modal logic is axiomatizable by stable canonical rules. We also define stable multi-conclusion consequence relations and stable logics and prove that these systems have the finite model property. We conclude the paper with a number of examples of stable and nonstable systems, and show how to axiomatize them.

L'étude de la maturation et de la ponte de l'huître creuse Crassostrea gigas, s'intègre dans une large problématique visant à comprendre les causes de mortalité qui surviennent épisodiquement dans le bassin de Marennes-Oléron au printemps et en été. Un conditionnement thermique et alimentaire des élevages permet d'obtenir simultanément des huîtres à tous les stades de maturité sexuelle. Le calcul des taux de filtration, consommation, absorption et respiration permet d'estimer le potentiel de croissance, et donne le bilan énergétique des huîtres aux différents stades sexuels. Les réponses physiologiques sont semblables pour des huîtres mâles ou femelles. La filtration de 2,4 à 2,6 1.h−1, passe à 1,8 1.h−1 à un stade de maturation avancée. La prise de poids liée au développement des gonades ne semble pas avoir d'effet sur le taux de filtration. Les huîtres de 2,5 ans présentent un bilan énergétique déficitaire (–15 J.h−1) à un stade de maturation avancée. Ce déficit est confirmé (–90 J.h−1) sur des huîtres de 1,5 ans au même stade de maturation. En revanche, les huîtres immatures, en début de maturation ou en post-ponte, ont un potentiel de croissance compris entre 110 et 170 J.h−1 . Le déficit énergétique observé au stade de maturation avancée relève essentiellement de la fonction d'absorption qui chute de façon importante en période de forte gamétogenèse. L'étude de la respiration permet de définir une allométrie particulière à la croissance gonadique avec un coefficient d'allométrie de 0,574. La faiblesse physiologique des huîtres, observée à un stade de maturation avancée, doit être prise en compte dans la recherche des facteurs responsables des mortalités printanières et estivales affectant les cheptels en élevage dans le bassin de Marennes-Oléron.

The uptake and release of material by oysters (Crassostrea gigas) and mussels (Mytilus edulis) in Marennes-Oléron Bay (SW France) were measured in situ using benthic ecosystem tunnels (BEST). There was a large variation in seston concentrations, owing to high sedimentation/erosion dynamics. Organic matter was diluted by resuspended sediment, but had a low C/N ratio, i.e. a high quality, owing to resuspension of microphytobenthos. In many cases a significant decrease of chlorophyll concentrations was observed in tunnels with oysters and mussels. Average clearance rates per tidal cycle ranged from 4 to 7, and from 0.9 to 2.7 1.g−1AFDW.h−1 throughout the season, for oysters and mussels respectively. Calculation of the filtration pressure (the fraction of the primary production filtered per day), indicated that bivalves in the bay were able to filter much more than the daily pelagic primary production. It seemed obvious that the bivalve stocks depended not only on phytoplankton but also on microphytobenthos. Significant regeneration of nitrogen could be demonstrated from musselbeds on the sediment, at higher rates than direct excretion of ammonium. No significant release of nutrients was observed for the oysters or mussels, when they were put on tables, as practised by the oyster farmers. lt seemed likely that biodeposits were flushed away from the tunnels in this case, and mineralization occurred elsewhere. It was concluded that the carrying capacity of the bay for herbivores is extensively exploited by the shellfish. Mineralization of bivalve biodeposits represent a large potential for nitrogen regeneration.