The subject of this chapter is the quantum mechanical analysis of the interaction of electromagnetic radiation with atomic transitions. The analysis is based on the Schrödinger wave equation, and in the first section, the gauge-invariant form of the external electromagnetic field is introduced. The electric dipole interaction and the long-wavelength approximation for the analysis of this interaction are discussed. The perturbative analysis of both single-photon and two-photon electric dipole interactions is presented, and density matrix analysis is introduced. The interaction of radiation with the resonances of atomic hydrogen is then discussed. The analysis is performed for both coupled and uncoupled representations. In the last section of the chapter, the radiative interactions for multielectron atoms are discussed. The Wigner–Eckart theorem and selection rules for transitions between levels characterized by coupling are developed. The effect of hyperfine splitting on radiative transitions is also briefly discussed.

This chapter introduces how we can use the quantum fields introduced in the previous chapter to access amplitudes and, thus, measurable quantities, such as the cross sections and the particle lifetime. More specifically, an educational tour of quantum electrodynamics (QED), which describes the interaction of electrons (or any charged particles) with photons, is proposed. Although this chapter uses concepts from quantum field theory, it is not a course on that topic. Rather, the aim here is to expose the concepts and prepare the reader to be able to do simple calculations of processes at the lowest order. The notions of gauge invariance and the S-matrix are, however, explained. Many examples of Feynman diagrams and the calculation of the corresponding amplitudes are detailed. Summation and spin averaging techniques are also presented. Finally, the delicate concept of renormalisation is explained, leading to the notion of the running coupling constant.

Chapter 5 described quantum mechanics in the context of particles moving in a potential. This application of quantum mechanics led to great advances in the 1920s and 1930s in our understanding of atoms, molecules, and much else. But, starting around 1930 and increasingly since then, theoretical physicists have become aware of a deeper description of matter, in terms of fields. Just as Einstein and others had much earlier recognized that the energy and momentum of the electromagnetic field is packaged in bundles, the particles later called photons, so also there is an electron field whose energy and momentum is packaged in particles, observed as electrons, and likewise for every other sort of elementary particle. Indeed, in practice this is what we now mean by an elementary particle: it is the quantum of some field that appears as an ingredient in whatever seem to be the fundamental equations of physics at any stage in our progress.

In this chapter the linearized Riemann tensor correlator on a de Sitter background including one-loop corrections from conformal fields is derived. The Riemann tensor correlation function exhibits interesting features: it is gauge-invariant even when including contributions from loops of matter fields, but excluding graviton loops as it is implemented in the 1/N expansion, it is compatible with de Sitter invariance, and provides a complete characterization of the local geometry. The two-point correlator function of the Riemann tensor is computed by taking suitable derivatives of the metric correlator function found in the previous chapter, and the result is written in a manifestly de Sitter-invariant form. Moreover, given the decomposition of the Riemann tensor in terms of Weyl and Ricci tensors, we write the explicit results for the Weyl and Ricci tensors correlators as well as the Weyl–Ricci tensors correlator and study both their subhorizon and superhorizon behavior. These results are extended to general conformal field theories. We also derive the Riemann tensor correlator in Minkowski spacetime in a manifestly Lorentz-invariant form by carefully taking the flat-space limit of our result in de Sitter.