The response of the photographic grain to light is a non-deterministic process which is as yet not completely understood. This response, as measured by the photographic density, is usually taken to be a function of the product of incident light intensity and exposure time interval duration, but at extreme values of either of these two quantities, this is no longer true. This latter effect is called reciprocity-law failure.
This paper discusses a probabilistic model, similar to a multiserver queue, for high-intensity reciprocity failure.