The production of highly charged ions in a CO2
laser-generated plasma is compared for different laser pulse-time
structures. The work was performed at the CERN Laser Ion Source,
which has the aim of developing a high current, high charge-state
ion source for the Large Hadron Collider (LHC). When an intense
laser pulse is focused onto a high-Z metal target,
the ions expanding in the plasma plume are suitable for extraction
from the plasma and matching into a synchrotron. For the first
time, a comparison is made between free-running pulses with
randomly fluctuating intensity, and mode-locked pulse trains
with a reproducible structure and the same energy. Despite the
lower power density with respect to the mode-locked pulse train,
the free-running pulse provides higher charge states and higher
yield.