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Crystal structure determination of K2Zn(PO3)4
L. N. Ji, Y. Q. Chen, J. B. Li, J. Luo, J. K. Liang, G. H. Rao
Journal:

Powder Diffraction / Volume 24 / Issue 1 / March 2009

Published online by Cambridge University Press:

29 February 2012, pp. 4-7
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The crystal structure of K2Zn(PO3)4 was determined and refined using the Rietveld method based on the isostructure model of K2Cu(PO3)4. This compound belongs to the monoclinic system with space group Cc and lattice parameters of a=11.0941(2) Å, b=12.5215(3) Å, c=7.6597(2) Å, and β=102.47(2)°. The chemical formula unit per unit cell is Z=4 and the calculated density is 2.938(3) g∕cm3. Zigzag [PO3]∞ chains formed along the a axis, and their period contains eight PO4 tetrahedrons.

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Crystal structure determination of K2Zn(PO3)4