Conodonts are an important biostratigraphic tool for many Phanerozoic stages. Along with graptolites, they define all global Ordovician Stage boundaries. Within the Upper Ordovician interval, a known species of Amorphognathus tvaerensis (Bergström) is present in both Sandbian and Katian stratotype sections. Study of changes in the succession of A. tvaerensis revealed that elements in the upper part of its range differ morphologically quite distinctly from those in its lower part. Here, they are described as a new conodont species, A. viirae sp. nov. This new species is recognized in several Estonian and Swedish sections, with apparent occurrence also in Mójcza Quarry, Holy Cross Mountains, Poland and Black Knob Ridge, Oklahoma, USA. Detailed analysis of early Amorphognathus elements from Estonian and Swedish sections revealed the absence of A. inaequalis (Rhodes) in both regions, although a conodont subzone based on this species was identified earlier by some authors. Both the absence of A. inaequalis (Rhodes) and recognition of the new species A. viirae sp. nov. resulted in the revision of the conodont zonation, and a new version of it is proposed for the Sandbian Stage in the Atlantic Realm. The new zonation includes (from below) Pygodus anserinus, Baltoniodus variabilis, A. tvaerensis, B. gerdae, A. viirae and B. alobatus Conodont zones.

The Katian (Upper Ordovician) Shiyanhe Formation at the Sigang section, Neixiang area, Henan Province, central China, has been investigated for carbon isotope (δ13Ccarb) chemostratigraphy. The carbon isotopic data document signal between the two major Ordovician positive shifts in δ13C, the early Katian Guttenberg and the Hirnantian excursions. The Kope (Ka1/2), Fairview (Ka2/3), Waynesville (Ka3/4), Whitewater (Ka4) excursions and a doubtful Elkhorn (Ka4) excursion are identified herein. The continuous and well-defined conodont zonal succession of the Sigang section provides a secure biostratigraphic framework for the mid-late Katian carbon isotope chemostratigraphy in China. Correlation between carbon-isotope data curve and the relative sea-level changes shows no clear correspondence, and hence the sea-level change is probably not the main driver of δ13C excursions during the Katian. Intercontinentally, the mid–late Katian carbon isotope excursions, identified mainly in the North American and Baltoscandian successions, are useful for improving long-distance stratigraphic correlations. This further suggests that these excursions represent global perturbations in the carbon cycle.

Latest Sandbian to early Katian sequences across Laurentia's epicontinental sea exhibit a transition from lithologies characterized as ‘warm-water’ carbonates to those characterized as ‘cool-water'carbonates. This shift occurs across the regionally recognized M4/M5 sequence stratigraphic boundary and has been attributed to climatic cooling and glaciation, basin reorganization and upwelling of open ocean water, and/or increased water turbidity and terrigenous input associated with the Taconic tectophase. Documentation of oxygen isotopic trends across the M4/M5 and through bracketing strata provides a potential means of distinguishing among these alternative scenarios; however, oxygen isotopic records generated to date have failed to settle the debate. This lack of resolution is because δ18O records are open to multiple interpretations and potentially confounding factors related to local environmental conditions have not been tested by examining the critical interval in multiple areas and different depositional settings. To begin to address this shortcoming, we present new species-specific and mixed assemblage conodont δ18O values in samples spanning the M4/M5 boundary from the Upper Mississippi Valley, Alabama, and Virginia. The new results are combined with previous studies, providing a record of δ18O variability across SE Laurentia. The combined dataset allows us to test for regional trends at a resolution not previously available. Our results document a ~1.5‰ decrease in values across Laurentia instead of increasing δ18O values across the M4/M5 as predicted in various ‘cool-water’ scenarios. In short, these results do not support a shift to ‘cool-water’ conditions as an explanation for changes in early Katian carbonates across the M4/M5.

Two trilobite faunas of Late Ordovician (Katian) age are described from the Mayatas Formation in the Stepnyak region of north-central Kazakhstan. The older, oligotaxic fauna derives from flanks of a carbonate build-up, and is dominated by numerous Sphaerexochus specimens. Amphilichas is also relatively common, with Pliomerina and indeterminate asaphids present as rare components. The overlying unit of siliceous argillites contains a different assemblage, representing the raphiophorid biofacies and comprising seven genera. The poorly preserved fauna is dominated by blind trilobites (a new genus of trinucleid, the three-segmented raphiophorid Pseudampyxina, Malongullia?, Lonchodomas and Arthrorhachis) and at least two species of large-eyed Telephina, suggesting that they occupied the disphotic zone in deep water offshore. A single cranidium of the odontopleurid Primaspis is also present. The trinucleid, Iputaspis stepnyakensis gen. et sp. nov., has an unusual pit arrangement, with E1 and E2 aligned in sulci and all I arcs irregularly arranged. The Atansor area is located within the Stepnyak tectonostratigraphical unit, which probably represented an Ordovician active margin of the Kalmykkol–Kokchetav Microplate. Some of the genera represented in the faunas have affinities with Australia and South China and, also, there is a possible link to European peri-Gondwana.

Altered volcanic ash interbeds (bentonites) in the upper Katian of Baltoscandia indicate significant volcanic activity in neighbouring tectonically active areas. Katian bentonites in the East Baltic can be reliably correlated using sanidine phenocryst composition. Ratios of immobile trace elements TiO2, Nb, Zr and Th to Al2O3 enable extension of the correlations to Scandinavia, where late diagenetic alterations could have caused recrystallization of sanidine phenocrysts. At least seven volcanic eruptions were recognized in Baltoscandian sections. Several bentonites found in deep-sea sediments are absent in shallow-sea sediments, indicating extensive breaks in sedimentation and erosion during late Katian and Hirnantian times. The areal distribution pattern of Katian bentonites in Baltoscandia indicates a volcanic source from the north or northwest (present-day orientation) from the margins of the Iapetus Palaeo-Ocean. Signatures of ultra-high-pressure metamorphism in the Seve Nappe (Central Sweden) and intrusions in the Helgeland Nappe Complex in Central Norway have been proposed as potential sources of the magmas that generated the volcanic ashes deposited in the East Baltic in Katian times. Geochemical similarities between Baltoscandian and Dob's Linn bentonites from southern Scotland suggest a common volcanic source in Katian times.

Brachiopods are among the most common components of the Late Ordovician benthic faunal assemblages recorded in the Faraghan Mountains, Zagros Ranges, Iran. A total of 19 species referable to 16 genera are identified, including seven new species; namely Drabovia elegans, Hibernodonta bonehensis, Hedstroemina zakeenensis, Jezercia faraghani, Protomendacella multicostata, Tafilaltia dargazensis and Tafilaltia seyahouensis. Reported brachiopod assemblages are oligotaxic (2–3 species per assemblage) to monotaxic. The only exception is the medium diversity Aegiromena-Hedstroemina Association, with up to ten species, which occurs at the lower part of the A. nigerica Zone. Low diversity patterns were probably controlled by the palaeogeographical position of the region in high southern latitudes throughout the Ordovician. Paterula sp. and Iranospirifer sp. are the only brachiopods documented from the Silurian (Llandovery) Sarchahan Formation. This paper gives the first detailed report of shelly fossils from the Llandovery ‘hot shale’ of the Arabian margin of Gondwana. Most of the Katian genera, and many of their species, are shared with neighbouring high- to mid-latitude peri-Gondwanan margins, including Morocco, Spain, France, Sardinia and Bohemia.

The generic assignments of some 200 Ordovician brachiopod species in the Barr and Lower Ardmillan (upper Darriwilian–lower Katian) succession, Girvan are reviewed and, where necessary, modified. This key database on the distribution and occurrence of a Laurentian-marginal brachiopod assemblage has featured in many analyses of global biogeography for the period and has confirmed the position of Girvan at relatively low latitudes. Revision of these taxonomic assignments within a modified stratigraphical framework permits closer comparisons with coeval faunas elsewhere around the palaeocontinent of Laurentia and beyond and allows the definition of a variety of brachiopod biofacies on a fault-controlled basin founded on a dismembered ophiolite.

The trilobite fauna of the upper Ordovician (middle Katian) Pyle Mountain Argillite comprises a mixture of abundant mesopelagic cyclopygids and other pelagic taxa and a benthic fauna dominated by trilobites lacking eyes. Such faunas were widespread in deep water environments around Gondwana and terranes derived from that continent throughout Ordovician time but this is the only known record of such a fauna from North America and thus from Laurentia. It probably reflects a major sea level rise (the ‘Linearis drowning events’) as does the development of coeval cyclopygid-dominated deep water trilobite faunas in terranes that were marginal to Laurentia and are now preserved in Ireland and Scotland. The Pyle Mountain Argillite trilobite fauna occurs with a deep water Foliomena brachiopod fauna and comprises 22 species. Pelagic trilobites (mostly cyclopygids) constitute 36% of the preserved sclerites, and 45% of the fauna is the remains of trilobites lacking eyes, including one new species, Dindymene whittingtoni sp. nov. Three species of cyclopygid are present, belonging in Cyclopyge, Symphysops and Microparia (Heterocyclopyge). Cyclopygids are widely thought to have been stratified in the water column in life and thus their taxonomic diversity reflects the relative depths of the sea-beds on which their remains accumulated. A tabulation of middle and upper Katian cyclopygid-bearing faunas from several palaeoplates and terranes arranged on the basis of increasing numbers of cyclopygid genera allows an assessment of the relative depth ranges of the associated benthic taxa. The Pyle Mountain Argillite fauna lies towards the deeper end of this depth spectrum.

Two trilobite faunas of late Ordovician (Sandbian and Katian) age are described from the siliciclastic Karagach Formation, western Tarbagatai Range, eastern Kazakhstan. They comprise 15 families and 24 genera and include the new taxa Agerina acutilimbata sp. nov., Birmanites akchiensis sp. nov., Dulanaspis karagachensis sp. nov. and Kimakaspis kovalevskyi gen. et sp. nov. Most of the Karagach Formation yields graptolites characteristic of the Diplograptus foliaceus [multidens] Biozone, which are associated with the older trilobite fauna; the uppermost part, which is the source of the younger trilobite fauna, contains Orthograptus quadrimucronatus and Dicranograptus hians which suggest a younger age, equating with the lowermost Ensigraptus caudatus Biozone, and the base of the Katian Stage. Most of the trilobite genera in both faunas have a wide geographical distribution in the late Ordovician, although Dulanaspis and Sinocybele are characteristic of low latitude eastern peri-Gondwanan faunas.