A theoretical model is developed to describe self-similar plasma expansion into vacuum with two different electron temperature distribution functions. The cold electrons are modeled with a Maxwellian distribution while the hot ones are supposed to be non-thermal obeying a kappa distribution function. It is shown that ion density and velocity profiles depend only on cold electron distribution in early stage of expansion whereas ion acceleration is mainly governed by the hot electrons at the ion front and is strongly enhanced with the proportion of kappa distributed electrons. It is also found that when the kappa index is decreasing, the critical value of temperature ratio Teh/Tec, limiting the application of quasi-neutrality, becomes larger than the $5 + \sqrt {24} \approx 9.9$ value obtained in the two-electron Maxwellian Bezzerides model [Bezzerides, B., Forslund, D. W. & Lindman, E. L. (1978). Phys. Fluids21, 2179–2185].